Biobased epoxides from unsaturated plant fatty acids by a new fungal peroxygenase and its heme-channel variants

Carro, Juan; González-Benjumea, Alejandro; Linde, Dolores; Renau-Mínguez, Chantal; Fernández-Fueyo, Elena; Gutiérrez Suárez, Ana; Martínez, Ángel T.; Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]

Biobased epoxides from unsaturated plant fatty acids by a new fungal peroxygenase and its heme-channel variants

2022

4 páginas.- 1 figura.- 1 tabla.- 15 referencias.- Comunicación oral presentada en el 16th European Workshop on Lignocellulosics and Pulp (EWLP) Gothenburg, Sweden, June 28 – July 1, 2022

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Enzyme-driven oxygenation reactions are in the spotlight for organic synthesis, and production of reactive bio-based compounds. The oxirane ring of epoxides has been termed the "Lord of chemical rings" because of its high reactivity and interest in chemical syntheses. A heme-thiolate unspecific peroxygenase (UPO) from the fungus Collariella virescens has recently proven to be a suitable catalyst for the selective production of fatty acid (di)epoxides. Here, lipid epoxidation is investigated in the frame of the SusBind EU project (https://susbind.eu) whose objective is the production of sustainable binders for wood-based panels.

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Funding from the Bio Based Industries Joint Undertaking under the EU’s Horizon 2020 research and innovation programme under Grant Agreement No 792063 (https://susbind.eu).

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