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Resultados 1-5 de 5
Temporal changes in some chlorinated hydrocarbon residue levels of Canadian breast milk and infant exposure
1994
Mes, J. (Food Research Division, Bureau of Chemical Safety, Food Directorate, Health Protection Branch, Health and Welfare Canada, Tunney's Pasture, Ottawa K1A 0L2 (Canada))
Chlorinated hydrocarbons and shell thinning in eggs of (Accipiter) hawks in Ontario, 1986-1989
1994
Elliott, J.E. | Martin, P.A. (Canadian Wildlife Service, National Wildlife Research Centre, Ottawa, Ontario K1A 0H3 (Canada))
A study of the influence of sewage sludge fertilization on the concentrations of PCDD/F and PCB in soil and milk
1994
McLachlan, M.S. | Hinkel, M. | Reissinger, M. | Hippelein, M. | Kaupp, H. (Ecological Chemistry, University of Bayreuth, 95440 Bayreuth (Germany))
Levels of selected individual polychlorinated biphenyls in different tissues of harbour seals (Phoca vitulina) from the southern coast of Norway
1994
Bernhoft, A. | Skaare, J.U. (Norwegian College of Veterinary Medicine, PO Box 8146 Dep., 0033 Oslo (Norway))
Surfactant solubilization of hydrophobic compounds in soil and water. 1. Dodecylsulphate monomer and micellar partition coefficients for 28 polychlorinated biphenyls (PCBs) (41)
1994
Rahman, M.S. (Bangladesh Atomic Energy Commission, Dhaka (Bangladesh). Inst. of Food and Radiation Biology) | Paya-Perez, A.B. | Skejo-Andresen, H. | Larsen, B.R.
Reductions in the apparent soil-water partition coefficients (K(d)* ) for 28 polychlorinated biphenyls (PCBs) caused by the surfactant sodium dodecylsulphate (SDS) in the aqueous phase were studied. Above the critical micelle concentration (CMC) of the surfactant, K(d)* was reduced by 2-3 orders of magnitude, but even far below CMC at environmentally relevant surfacant concentrations significant reductions in Kd3 were observed. The plot of the soil-water partition coefficient (K(d)) divided by K(d)* versus the concentration of SDS allowed for the calculation of monomer (K(mn)(oc)) and micellar (K(mc)(oc)) surfactant-water parrition coefficients normalized to organic carbon for each PCB congener. K(mn)(oc) values were comparable with published values for the partition of PCBs between natural dissolved organic matter and lake water. K(mc)(oc) values were up to 30 times higher than K(mn)(oc) values and comparable with published octanol-water distribution coefficients. The findings of the present study underline the potential of surfactants at concentrations below their CMC to mobilize otherwise strongly bound hydrophobic compounds in soil-water systems.
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