Owing to the habit of most of Yugoslavs to prepare coffee without filtering, the large part of used coffee comes to recipients. In this paper, the influence of coffee deposits reaching recipients in Yugoslavia is analyzed. Results of laboratory examination of the biodegradability and kinetic of biodegradability of coffee deposits are also presented.

Nowadays, microplastics represent emergent pollutants in terrestrial ecosystems that exert impacts on soil properties, affecting key soil ecological functions. In agroecosystems, plastic mulching is one of the main sources of plastic residues in soils. The present research aimed to evaluate the effects of two types of plastic sheets (un-biodegradable and biodegradable) on soil abiotic (pH, water content, concentrations of organic and total carbon, and total nitrogen) and biotic (respiration, and activities of hydrolase, dehydrogenase, β-glucosidase and urease) properties, and on phytotoxicity (germination index of Sorghum saccharatum L. and Lepidium sativum L.). Results revealed that soil properties were mostly affected by exposure time to plastics rather than the kind (un-biodegradable and biodegradable) of plastics. After six months since mesocosm setting up, the presence of un-biodegradable plastic sheets significantly decreased soil pH, respiration and dehydrogenase activity and increased total and organic carbon concentrations, and toxicity highlighted by S. saccharatum L. Instead, the presence of biodegradable plastic sheets significantly decreased dehydrogenase activity and increased organic carbon concentrations. An overall temporal improvement of the investigated properties in soils covered by biodegradable plastic sheets occurred.

Biodegradable plastic mulch film (BDM) is an environmentally friendly alternative to conventional polyethylene mulch, and has been growingly used in agriculture. However, practical degradation performance of BDM, especially the widely used type of blended polylactic acid (PLA)/polybutylene adipate (PBAT) in different ratios, and microbial alteration in soil environments, remain largely unrevealed. In this study, four types of BDM blended with 40–80% PLA and 20–60% PBAT were comparatively investigated through microcosm soil incubation experiments for 105 days, and combined with conditions of different soil moisture or pH. Microbiome within film-surrounding soil were assayed using 16 S rRNA high-throughput sequencing. Results showed a trend of increasing degradation efficiency with the increase of PLA proportion, and 70% PLA and 30% PBAT group presented the highest weight loss rate, i.e., 60.16 ± 5.86%. In addition, degradation and aging of PLA/PBAT varied among different soil moisture and pH values. A moderate moisture, i.e., 60% and a neutral pH7.0 caused significantly high degradation efficiency compared to other moisture or pH conditions. Moreover, bacterial abundance and community structure in the surrounding soil were related to soil moisture and pH. PLA/PBAT incubation treatment induced a remarkable increase in abundance of degradation-related species Pseudomonas and Sphingomonas. Bacterial richness and diversity in soil correspondingly respond to ratio-different PLA/PBAT's degradation under moisture/pH-different conditions through a redundancy analysis. Altogether, these findings indicate that practical degradation of PLA/PBAT film is closely related to soil environments and bacterial community. It is significant for the application of biodegradable plastics in agriculture on the perspective of soil sustainability.

Although microplastic pollution in the soil environment is currently an important research topic, few studies have focused on farmland soil in arid regions. This study investigated the abundances, sizes, polymer compositions, and forms of microplastics across nine agricultural plots cultivated with maize, sunflower, and potato (three of each crop) plants to determine the influences of different cropping characteristics and agricultural practices. The study area was within the arid region of the Ulungur River basin in Qinghe County, Altay, Xinjiang, China. The main forms of microplastics were fragments and fibers, and polyethylene was the dominant polymer (91.6%). The microplastic abundance ranged from 11 347 items/kgdw to 78 061 items/kgdw (mean of 52 081.7 items/kgdw). The abundance and proportion of microplastics with a diameter of <0.2 mm were significantly higher in the sunflower and maize plots (i.e., tall crops) than in the potato plots (i.e., short crops) (p < 0.05). This is due to straw residues affecting the migration and recovery of the mulch. The abundance and fragmentation of microplastics were significantly higher in the sunflower and maize plots where plastic mulch was extensively used because these tall crops anchored the mulch near their stem–root systems. The mulch was then slowly aged (e.g., via wind erosion) before being fragmented due to agricultural practices (e.g., mechanical plowing and residue retention). Although microplastics sourced from mulch are probably immobilized by straw residues in the short term, fragile and easily broken pieces of mulch are eventually released into the soil due to agricultural practices. The findings suggest that different cropping characteristics can affect the abundance and fragmentation of microplastics in agricultural soils, even within the same region, and thus the level and type of microplastic pollution. Traditional plastic mulch should be replaced with biodegradable mulch to reduce microplastic pollution in agricultural fields.

A biological treatment method was tested in laboratory conditions for the removal of hydrocarbons contained in a waste disposal soil sample consisting of excavated sandy soil from a former fueling station. Two fractions of hydrocarbons were quantified by GC-FID: diesel (C₁₀–C₂₁) and lubricant oil (C₂₂–C₄₀). Meat and bone meal (MBM, 1% w/w) was used as a bio-stimulant agent for soil organisms. Cyclodextrin, an oligosaccharide produced from starch by enzymatic conversion, was also used to assess its ability to improve the bioavailability/biodegradability of hydrocarbons in the soil. Parameters such as temperature, pH, water content and aeration (O₂ availability) were monitored and optimized to favor degradation processes. Two different experimental tests were prepared: one to measure the degradation of hydrocarbons; the other to monitor the mobility of some elements in the soil and in the leachate produced by watering with tap water. Soil samples treated with MBM and cyclodextrin showed, over time, a greater removal of the more persistent hydrocarbon fraction (lubricant oil). MBM-treated soils underwent a faster hydrocarbon removal kinetic, especially in the first treatment period. However, the final hydrocarbon concentrations are comparable in all treatments, including control. Over time, the effect of cyclodextrin on hydrocarbon degradation seemed to be relevant. MBM-treated soils sequestered lead in the very first weeks. These results highlight the intrinsic capacity of soil, and its indigenous microbial communities, to degrade petroleum hydrocarbons and suggest that MBM-induced bioremediation is a promising, environmentally friendly technology which should be considered when dealing with hydrocarbon/heavy metal co-contaminated soils.

Soil contamination is perhaps the most hazardous issue all over the world; these emerging pollutants ought to be treated to confirm the safety of our living environment. Fast industrialization and anthropogenic exercises have resulted in different ecological contamination and caused serious dangerous health effects to humans and animals. Agro wastes are exceptionally directed because of their high biodegradability. Effluents from the agro-industry are a possibly high environmental risk that requires suitable, low-cost, and extensive treatment. Soil treatment using a bioremediation method is considered an eco-accommodating and reasonable strategy for removing toxic pollutants from agricultural fields. The present review was led to survey bioremediation treatability of agro soil by microbes, decide functional consequences for microbial performance and assess potential systems to diminish over potentials. The presence of hazardous pollutants in agricultural soil and sources, and toxic health effects on humans has been addressed in this review. The present review emphasizes an outline of bioremediation for the effective removal of toxic contaminants in the agro field. In addition, factors influencing recent advancements in the bioremediation process have been discussed. The review further highlights the roles and mechanisms of micro-organisms in the bioremediation of agricultural fields.

India struggles with frequent exceedances of the ambient air quality standard for particulate matter and benzene. In the past two decades, India has made considerable progress in tackling indoor air pollution, by phasing out kerosene lamps, and pushing biofuel using households towards Liquefied Petroleum Gas (LPG) usage. In this study, we use updated emission inventories and trends in residential fuel consumption, to explore changes in the contribution of different sectors towards India's largest air pollution problem. We find that residential fuel usage is still the largest air pollution source, and that the <10% households using cow dung as cooking fuel contribute ∼50% of the residential PM₂.₅ emissions. However, if current trends persist, residential biofuel usage in India is likely to be phased out by 2035. India's renewable energy policies are likely to reduce emissions in the heat and electricity sector, and manufacturing industries, in the mid-term. PM₂.₅ emissions from open waste burning, on the other hand, hardly changed in the decade from 2010 to 2020. We conclude that without strong policies to promote recycling and upcycling of non-biodegradable waste, and the conversion of biodegradable waste to biogas, open waste burning is likely to become India's largest source of air pollution by 2035. While our study is limited to India, our findings are of relevance for other countries in the global South suffering from similar waste management challenges.

Plastic residues have become a serious environmental problem in areas where agricultural plastic film are used intensively. Although numerous of studies have been done to assess its impacts on soil quality and crop yields, the understanding of meso-plastic particles effects on plant is still limited. In this study, low density polyethylene (PE) and biodegradable plastic (Bio) mulch film were selected to study the effects of meso-plastic debris on soybean germination and plant growth with the accumulation levels of 0%, 0.1%, 0.5% and 1% in soil (w: w, size ranging 0.5–2 cm) by a pot experiment under field condition. Results showed that the germination viability of soybean seeds was reduced to 82.39%, 39.44% and 26.06% in the treatments with 0.1%, 0.5% and 1% added plastic debris compared to the control (CK), respectively, suggesting that plastic residues in soil inhibit the viability of soybean seed germination. The plastic debris had a significant negative effect on plant height and culm diameter during the entire growth stage of soybean. Similarly, the leaf area at harvest was reduced by 1.97%, 6.86% and 11.53% compared to the CK in the treatments with 0.1%, 0.5% and 1% plastic debris addition, respectively. In addition, the total plant biomass under plastic addition was reduced in both the flowering and harvesting stages, compared to the CK. For the different type of plastic residues, plant height, leaf area and root/shoot ratio at group PE were significantly lower than those of groups treated by Bio. In conclusion, PE debris had a greater negative effects on plant height, culm diameter, leaf area and root/shoot ratio while Bio debris mainly showed the adverse effects on germination viability and root biomass especially at the flowering stage. Therefore, further research is required to elaborate plastic particles’ effects on different stages of crops and soil quality.

Ionic liquids (ILs), also known as green solvents, are widely acknowledged in several fields, such as chemical separation, synthesis, and electrochemistry, owing to their excellent physiochemical properties. However, their poor biodegradability may lead to environmental and health risks, posing a severe threat to humans, thus requiring further research. In this study, the biotoxicities of the imidazolium-based ILs were evaluated in Tetrahymena pyriformis. Moreover, IL detoxification was investigated by addition of glutathione (GSH), cysteine, and nicotinamide adenine dinucleotide (NADH). Reactive oxygen species (ROS) initiated by different IL types caused damage to Tetrahymena, while glutathione, cysteine, and NADH eliminated ROS, achieving the detoxification purposes. Detoxification results showed that NADH exhibited the best detoxification ability, followed by glutathione and cysteine. Finally, RT-PCR results suggested that metallothionein might have participated in IL detoxification.

The plastic mulch films used in agriculture are considered to be a major source of the plastic residues found in soil. Mulching with low-density polyethylene (LDPE) is widely practiced and the resulting macro- and microscopic plastic residues in agricultural soil have aroused concerns for years. Over the past decades, a variety of biodegradable (Bio) plastics have been developed in the hope of reducing plastic contamination of the terrestrial ecosystem. However, the impact of these Bio plastics in agroecosystems have not been sufficiently studied. Therefore, we investigated the impact of macro (around 5 mm) and micro (<1 mm) sized plastic debris from LDPE and one type of starch-based Bio mulch film on soil physicochemical and hydrological properties. We used environmentally relevant concentrations of plastics, ranging from 0 to 2% (w/w), identified by field studies and literature review. We studied the effects of the plastic residue on a sandy soil for one month in a laboratory experiment. The bulk density, porosity, saturated hydraulic conductivity, field capacity and soil water repellency were altered significantly in the presence of the four kinds of plastic debris, while pH, electrical conductivity and aggregate stability were not substantially affected. Overall, our research provides clear experimental evidence that microplastics affect soil properties. The type, size and content of plastic debris as well as the interactions between these three factors played complex roles in the variations of the measured soil parameters. Living in a plastic era, it is crucial to conduct further interdisciplinary studies in order to have a comprehensive understanding of plastic debris in soil and agroecosystems.