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Emission characteristics and associated assessment of volatile organic compounds from process units in a refinery
2020
Feng, Yunxia | Xiao, Anshan | Jia, Runzhong | Zhu, Shengjie | Gao, Victor | Li, Bo | Shi, Ning | Zou, Bing
The accuracy and reliability of volatile organic compound (VOC) emission data are essential for assessing emission characteristics and their potential impact on air quality and human health. This paper describes a new method for determining VOC emission data by multipoint sampling from various process units inside a large-scale refinery. We found that the emission characteristics of various production units were related to the raw materials, products, and production processes. Saturated alkanes accounted for the largest fraction in the continuous catalytic reforming and wastewater treatment units (48.0% and 59.2%, respectively). In the propene recovery unit and catalytic cracking unit, alkenes were the most dominant compounds, and propene provided the largest contributions (57.8% and 23.0%, respectively). In addition, n-decane (12.6%), m,p-xylene (12.4%), and n-nonane (8.9%) were the main species in the normal production process of the delayed coking unit. Assessments of photochemical reactivity and carcinogenic risk were carried out, and the results indicate that VOC emissions from the propene recovery unit and catalytic cracking unit should be controlled to reduce the ozone formation potential; in addition, alkenes are precedent-controlled pollutants. The cancer risk assessments reveal that 1,2-dibromoethane, benzene, 1,2-dichloroethane, and chloroform were the dominant risk contributors, and their values were much higher than the standard threshold value of 1.0 × 10⁻⁶ but lower than the significant risk value defined by the US Supreme Court. Based on the VOC composition and a classification algorithm, the samples were classified into eight main groups that corresponded to different process units in the petroleum refinery. In conclusion, this work provides valuable data for investigating process-specific emission characteristics of VOCs and performing associated assessments of photochemical reactivity and carcinogenic risk in petrochemical refineries.
Mostrar más [+] Menos [-]Public awareness and attitudes towards naval sonar mitigation for cetacean conservation: A preliminary case study in Fairfax County, Virginia (the DC Metro area)
2011
Zirbel, K. | Balint, P. | Parsons, E.C.M.
The potential impacts of naval sonar on cetaceans has led to a series of court cases and statements of concern by international organizations. However, there has been no research conducted on attitudes of the general public with respect to this issue. To investigate this, a preliminary public survey was conducted in Fairfax, Virginia (the Washington, DC Metro region). The majority of the public sampled believed that naval sonar impacted marine mammals (51.3%), that the US Navy should not be exempt from environmental regulations in time of peace (75.2%), and that sonar use should be moderated if it impacts cetaceans (75.8%). Individuals who were conservative, Republican, and have served in the military were more likely to believe the Navy should be exempt from marine mammal protection regulations. In addition, expert interviews were conducted to gain opinions on the potential ramifications of the recent US Supreme Court case on naval sonar mitigation.
Mostrar más [+] Menos [-]Navy sonar, cetaceans and the US Supreme Court: A review of cetacean mitigation and litigation in the US
2011
Zirbel, K. | Balint, P. | Parsons, E.C.M.
One source of anthropogenic noise in the oceans which has attracted much concern is naval sonar. As a result of possible impacts of such sonar, several environmental NGOs have pursued legal cases in the United States criticizing environmental assessments conducted prior to exercises and proposed mitigation measures. Cases have been brought using the US National Environmental Protection Act, Marine Mammal Protection Act, Endangered Species Act, Coastal Zone Management Act and other statutes. This paper reviews the chronology and results of these various cases. During the G.W. Bush presidential administration, the legal battle went to the US Supreme Court in the case Winter vs. Natural Resources Defense Council. This case however, did not address the potential impacts of sonar on cetaceans or the effectiveness of mitigation measures. During the Obama administration, mitigation measures for naval exercises have been revised, and working groups planned, in an attempt to resolve conflict between parties.
Mostrar más [+] Menos [-]Evaluation of the environmental noise problems in holiday villages: a case study from Antalya, Turkey
2019
Gürsoy, Özge | Yüğrük Akdağ, Neşe
Not only the appeal of the sun, natural, and historical beauties but also architectural features and business advantages of the accommodation facilities emerge as important factors in tourism development. Holiday villages differ from other types of accommodation facilities in terms of their functions and services. It is important to provide tourists acceptable levels of comfort in holiday villages offering various functions. One of these comfort conditions is acoustic comfort, which involves noise control. Noise emitted from various indoor and outdoor facilities is the main component impacting acoustic comfort in holiday villages. In this study, a holiday village in Antalya, Turkey with an open area of 120,000 m² was examined to identify noise exposure conditions of outdoor areas. Pools, restaurants, animation areas, playgrounds, and courts are the main outdoor noise sources in this holiday village. The noise emitted by these sources during daytime (Ld) and evening time (Le) are shown in noise maps. The open areas affected by 65 LAₑq noise level extend to an area of 55,500 and 21,000 m² during Ld and Le, respectively. With the noise barriers around the main noise sources, impacted open areas are reduced by 13% in Ld and 12% in Le. The results of this study clearly reveals the importance of resolving the issue of environmental noise in the most efficient and cost-effective way in terms of settlement and planning, especially in areas with dominant noise sources like holiday villages.
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