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Assessment of groundwater and surface water pollution by hazardous metals, using multivariate analysis and metal pollution index around the old Sidi Kamber mine, NE Algeria
2022
khelfaoui, malika | Benaissa, Amina | Kherraf, Sihem | Madjram, Mohamed Salah | Bouras, Ibtissem | Mehri, karima
In order to evaluate the impact on water quality of the abandoned Sidi Kamber mine in Skikda, NE Algeria, Pb, Zn, Cd, Fe, Cu, Mn and Ni metals were collected at surface water and groundwater, from twenty eight sites located near the mine. Conventional hydrochemical methods, heavy metal pollution index (HPI) and multivariate statistical analysis techniques: correlation matrix (CM), principal component analysis (PCA) and hierarchical cluster analysis (HCA) were used. Surface water results show that El-Souk River has a high level of pollution, but Guenitra dam water is less contaminated. Regarding the groundwater results, the wells and springs are not suitable for drinking. The overall quality estimated by HPI values of surface and groundwater are poor; they may pose a potential health risk to the local population. The PCA and HCA suggest that surface water and groundwater are contaminated by two sources: anthropogenic and natural. According to the obtained results, surface water and groundwater pollution state of this area raises serious concerns about health and environment.
Mostrar más [+] Menos [-]Assessment of Groundwater Based Public Drinking Water Supply System of Kamrup District, Assam, India using a Modified Water Quality Index
2021
Goswami, Jayanta | Bhattacharjya, Rajib Kumar
This work aims to assess the Water Quality Index (WQI) of the groundwater-based public drinking water supply system of Kamrup District (Rural) of Assam, India. For assessing WQI, water samples have been collected, both raw water and treated water, from seventy-eight public drinking water supply projects over the district for comprehensive physicochemical analysis. The WQI was calculated based on the weightage derived from the literature survey and based on the doctors’ weightage. The derived WQI showed that the water quality falls from poor to very poor quality. However, the concentration of the water quality parameters except Iron, Fluoride, and Manganese are within the permissible limit in all the water supply projects. It shows that the WQI calculated based on the weightage derived, as stated above, is not displaying the actual water quality of the supplied water. As such, a modified method is proposed to calculate the WQI of the supplied water considering the permissible limit of the parameters in deriving the weightage for the parameters. The WQI values calculated using the modified method falls in the range of good water quality to poor water quality and shows the true water quality of the supplied water. The statistical analysis of the water quality parameters and WQI shows that the WQI has a very high correlation with Manganese with a coefficient of correlation value of 0.86, followed by 0.4 with Chloride and 0.34 with Fluoride.
Mostrar más [+] Menos [-]Assessment of Heavy Metals and Microbial Load of Groundwater Samples from Ibadan Metropolis Nigeria
2018
Salaudeen, I.A. | Ogunbamowo, Paul | Rasheed-Adeleke, A.A. | Olaniyi, A.A.
The present study investigates groundwater quality in terms of heavy metals level and microbial contamination as well as the impact of bleaching powder on microbial load of groundwater samples in close proximity to a surface water body inside selected areas of Ibadan Nigeria. To do so, it collects nine water samples from three boreholes and six hand-dug wells from six locations, namely Eleyele, Wofun-Olodo, Oluyole Industrial Estate, Ogunpa, Olorunsogo, and Ojoo, keeping them in 750 mL plastic bottles. The samples are then divided by two, giving a total amount of 18 samples, with 3 and 6 duplicates apiece being treated with bleaching powder and the rest remaining untreated. Both sample sets have been analysed for water quality parameters such as pH, biochemical oxygen demand, and chemical oxygen demand, assessed using standard methods. The coliform count has been determined, using the pour plate method while heavy metal has been set by means of Atomic Absorption Spectrophotometer (AAS) after nitric acid digestion. Results show that the pH ranges within 6.0-6.5, BOD within 1.67-4.33mg of O2/L, and COD within 2.93-9.43, while heavy metal concentration is from 0.013 to 0.047 mg/L for lead, ND to 0.023 mg/L for chromium, and ND to 0.010 for cadmium. What is more, the coliform count in the samples is between 0.00 and 913.33 CFU/mL. Most of the samples exceed the WHO limits for heavy metals in drinking water, having significant levels of microbial contamination. Bleaching powder treatment alleviated the level of pollution to varying degrees; therefore, constant monitoring of groundwater source and treatment before drinking is of utmost importance.
Mostrar más [+] Menos [-]Groundwater quality determination regarding major anions and cations (Case study of an aquifer in the Lut Desert, Iran)
2015
Nasrabadi, Touraj | Baghvand, Akbar | Vosoogh, Ali
Groundwater quality regarding major anions and cations in the Birjand Plain located in the largest desert in Eastern Iran was monitored in this study. Fifteen boreholes were considered as sampling stations and the parameters pH, TDS, EC and major anions and cations were measured in groundwater samples. The dominant groundwater types can be introduced as sodium-chloride and magnesium-sulphate. The majority of samples were within the not-suitable category for drinking uses. Regarding agricultural use, around 80 and 50 per cent of samples indicated a very high salinity hazard and a very high sodium alkali hazard, respectively. Spatial distribution of salinity was also monitored within the study area. If the study area was considered to be a semicircle, the centre appeared to be the least polluted area, while towards the peripheral surroundings, an increasing behaviour was observed. Intrusion of salt water from eastern and western parts of the study area caused severe groundwater degradation. The relatively better quality of groundwater in southern areas may be attributed to a chain of mountains located along south of the study area. The prevention of uncontrolled groundwater withdrawal must be regarded to cease the salinization trend and to prepare the required infrastructure for implementing the artificial recharge projects.
Mostrar más [+] Menos [-]Spectrophotometer-based student education program on health hazard assessment due to Cr(VI) and Pb contamination in surface and groundwaters of Hyderabad City, India
2015
Das Sharma, Mala | Juyal, Archana | Karuna, Mantha | Das Sharma, Subrata
A student-centric research education program with the active participation of undergraduate students is initiated. The aim is to imbibe ―responsible citizenship behavior‖ in them so that each member becomes conscious and well trained to take up environmental-related issues and challenges for long-term sustainability of the ecosystem. In this work, we report spectrophotometer-based estimation of hexavalent chromium (57-268 gL-1) and lead (34–158 gL-1) concentrations in different surface waters and groundwater samples in and around the city of Hyderabad, India. Our results indicate that the studied surface water bodies and aquifers are contaminated to variable degrees and pose a serious threat to the ecosystem. In view of low geochemical baseline values for chromium and lead, the origin of heavy metal pollution is inferred to be anthropogenic, mainly originating from industrial effluents. The toxicological data are integrated with health data for risk assessment and impending health hazard. Finally, the novelty of this student-centric research program is highlighted.
Mostrar más [+] Menos [-]Perfluorooctane Sulfonic Acid (PFOS) in River Water and Groundwater along Bharathapuzha River Basin, India
2023
Kanjiyangat, Vivek
Perfluorinated chemicals (PFCs) are widely used in industrial and commercial applications, leading to their release into the environment. The rapid industrialization and growing population in India make it a suitable case study to investigate PFOS contamination in environmental matrices. The purpose of this study is to investigate PFOS concentrations in river water and groundwater from several locations along the Bharathapuzha river basin and estimate PFOS intakes through drinking water. The highest PFOS level detected in the surface water is 1.3 ng/L and groundwater is 1.0 ng/L, which is significantly lower than the level of PFOS detected in major rivers of many developed countries. It is possible to attribute the low PFOS concentration to factors such as high annual precipitation, reduced industrial and municipal wastewater discharge, and relatively low emissions per capita in a region where agriculture is a major part of the economy. In addition, the daily intake of PFOS through drinking water in all age groups was below the safety threshold for cancer risk.
Mostrar más [+] Menos [-]Uranium in Groundwater: Distribution and Plausible Chemo-Radiological Health Risks Owing to the Long-term Consumption of Groundwater of Panchkula, Haryana, India
2023
Tanwer, Naresh | Anand, Poonam | Batra, Neha | Kant, Krishan | Gautam, Yogender | Sahoo, Sunil
A comprehensive investigation was engaged to determine the spatial distribution of Uranium (U) and the consequential chemical and radiological health risk associated due to the consumption of groundwater containing U, in Panchkula district. A well-accepted technique of fluorescence of U estimation in an aqueous medium was employed having a detection limit of 0.50 µgL-1. The chemo-radiological health risk and water quality index was computed using a standard equation of concerned agencies to determine the suitability for human health. The concentration of U was observed to vary from 1.70 – 12.28 µgL-1 with the mean value of 5.89 µgL-1 The concentration of U was far below the standard prescribed limits as per World Health Organisation, Atomic Energy Regulatory Board, and United Nation Environmental Protection Agency. Except nitrate and total alkalinity in few samples, all water quality paramters were within the recommended limit of BIS. The annual effective dose (AED), excess cancer risk (ECR), and lifetime average daily dose (LADD) indicated no potential health issue due to the consumption of groundwater of studied locations. The correlation was computed between U and various macro-anions and cations present in water samples. U was observed to have a significant weak positive correlation with total dissolved solids (TDS), electrical conductivity (EC), and salinity.
Mostrar más [+] Menos [-]Analytical Solutions for Solute Transport from two-point Sources along Porous Media Flow with Spatial Dispersity involving Flexible Boundary Inputs, initial Distributions and Zero-order Productions
2022
Tjock-Mbaga, Thomas | Ele Abiama, Patrice | Ema'a Ema'a, Jean Marie | Ben-Bolie, Germain Hubert
This study derives an analytical solution of a one-dimensional (1-D) Advection-Dispersion Equation (ADE) for solute transport with two contaminant sources incorporating the source term. Groundwater velocity is considered as a linear function of space while the dispersion as a nth power of velocity and analytical solutions are obtained for , and . The solution is derived using the Generalized Integral Transform Technique (GITT) with a new regular Sturm-Liouville Problem (SLP). Analytical solutions are compared with numerical solutions obtained in MATLAB pedpe solver and are found to be in good agreement. The obtained solutions are illustrated for linear combination of exponential input distribution and its particular cases. The dispersion coefficient and temporal variation of the source term on the solute distribution are demonstrated graphically for the set of input data based on similar data available in the literature. As an illustration, model predictions are used to estimate the time histories of the radiological doses of uranium at different distances from the sources boundary in order to understand the potential radiological impact on the general public for such problem.
Mostrar más [+] Menos [-]Carcinogenic and Non-carcinogenic Health Risk Assessment of Heavy Metals in Ground Drinking Water Wells of Bandar Abbas
2021
Farimani Raad, Hamidreza | Pardakhti, Alireza | Kalarestaghi, Hamidreza
This research evaluates the carcinogenic and non-carcinogenic risks from cadmium, lead, and zinc in Bandar Abbas groundwater sources. The samples from 25 wells were analyzed for cadmium, lead and zinc. Total lifetime cancer risk and non-cancer risk assessment from exposure to these pollutants in drinking water (ingestion, inhalation and skin routes) were conducted for people living in these villages. In these regions most of the drinking water supplied, are from these wells which shows the importance of analyzing the quality of them in order to prevent diseases and cancer risks. The highest risk from cadmium seems to be in village Dehno Paein and also this amount for lead occurs in Tifakan Tal-e Gerdu. The highest hazard index (HI) based on human health risk assessment (HHRA) model for cadmium, lead, and zinc through oral, inhalation and dermal pathways were computed as 0.005, 1.63 and 0.043 which are in Dehno Paein, Tifakan Tal-e Gerdu and Faryab. Results show that lead can lead to more cancer cases in these villages that cadmium. The total expected cancer cases from exposure to cadmium in different routes are lower than lead.
Mostrar más [+] Menos [-]Investigation of Spatial Structure of Groundwater Quality Using Geostatistical Approach in Mehran Plain, Iran
2016
Khosravi, Hassan | Karimi, Kamran | Nakhaee nejadfard, Sara | Mesbahzadeh, Tayebeh
Groundwater is a major source of water for domestic, industrial, and agricultural sectors in many countries. The main objective of this research was to provide an overview of present groundwater quality using parameters such as calcium, magnesium, sodium, chloride, sulfate, pH, and electrical conductivity (EC) in the Mehran plain, Ilam province using GIS and geostatistical techniques. A total of 23 deep and semi-profound wells were selected based on the classified randomized sampling method. The sampling locations were obtained by GPS. Plastic containers were used for the collection of water samples. These samples were transferred to the laboratory for analyzing water quality parameters. Statistical characteristics, qualitative data interpolation, and zoning were investigated using SPSS 20 ،GS+5.3 and ArcGIS10.1. Kolmogorov–Smirnov test were used to test data normality. In order to normalize parameters, logarithm, and 1/x were used for sulfate, EC, cation, and anion. Then the variogram analysis was performed to select the appropriate model. Results showed that co-kriging is the best method for cation and anion, whereas local polynomial interpolation is suitable for sulfate. The results of the interpolation of groundwater quality factors showed that there is approximately good adaption among groundwater factors and geomorphology and topology of the region. Because of inappropriate irrigation system, the highest concentration is in the northwest and western parts of the region, where there is the minimum height and maximum agricultural land. Growth of arable land and agricultural activities has caused increasing concentrations of studied elements, especially EC.
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