The paper presents one of the methods for calculation of temperature of a water course, downstream of the relase of a thermo-electric power-plant, taking into consideration the well-known temperatures and discharge values of the tributaries under different meteorological conditions. In view of the importance of temperature regime for the water eco-system, understanding the influence of the power plants on thermic capacity of the water course, is essential in design and use of the power plant. The author's intention is to help towards improving computer models for the computation of a water course thermic capacity. To this end a model developed at the Institute for Meteorology and Water Management in Poland and applied in many coutries has been presented.

Vertical profiles of Tl, Pb and Zn concentrations and Tl and Pb isotopic ratios in a contaminated peatland/fen (Wolbrom, Poland) were studied to address questions regarding (i) potential long-term immobility of Tl in a peat profile, and (ii) a possible link in Tl isotopic signatures between a Tl source and a peat sample. Both prerequisites are required for using peatlands as archives of atmospheric Tl deposition and Tl isotopic ratios as a source proxy. We demonstrate that Tl is an immobile element in peat with a conservative pattern synonymous to that of Pb, and in contrast to Zn. However, the peat Tl record was more affected by geogenic source(s), as inferred from the calculated element enrichments. The finding further implies that Tl was largely absent from the pre-industrial emissions (>~250 years BP). The measured variations in Tl isotopic ratios in respective peat samples suggest a consistency with anthropogenic Tl (ε²⁰⁵Tl between ~ -3 and −4), as well as with background Tl isotopic values in the study area (ε²⁰⁵Tl between ~0 and −1), in line with detected ²⁰⁶Pb/²⁰⁷Pb ratios (1.16–1.19). Therefore, we propose that peatlands can be used for monitoring trends in Tl deposition and that Tl isotopic ratios can serve to distinguish its origin(s). However, given that the studied fen has a particularly complicated geochemistry (attributed to significant environmental changes in its history), it seems that ombrotrophic peatlands could be better suited for this type of Tl research.

Air pollution constitutes the greatest environmental threat to human health in the European Union. In Poland, the emission of particulate matter and harmful gases originating from local coal based boiler plants and the combustion of fuels in residential heating appliances is a considerable source of air pollution. The combustion of fuel in home furnaces is inefficient due to the use of cheap fuels of low heating parameters and the frequent addition of waste. For the purpose of the research, deciduous tree wood pellets were selected as the basic fuel with the admixture of plastic waste, rubber, waste paper, wood residues, diapers, textile waste, multi-material packaging, construction waste, biomass and alternative fuel (RDF). Examining ash samples to confirm the practices of combusting or co-combusting waste materials in heating appliances is considered to be one of the most reliable detection methods; however, the results of direct research require further data processing. The application of hierarchical clustering analysis to the obtained results arranged into a matrix enabled in a simple way to demonstrate the similarities between the examined samples of fuel and the samples of fuel mixed with waste materials in the parameters space as well as to analyze the similarities among the measured parameters (the content of particular elements in ash) in the space of the examined samples. The application of chemometric methods for the purpose of identifying the combusted fuels, and, in particular the co-combusted waste complements the currently used monitoring tools which control the use of low quality fuels or the combustion of waste of different origin.

Piscivorous avian species may be affected by mercury (Hg) which tends to accumulate in aquatic environments and biomagnifies across the food webs. One of such species is the black stork, whose population increase recently slowed down due to unknown reasons. At the same time Hg contamination and its effects were almost unaudited for this species, so it may have exerted deleterious effects on the population and an evaluation is necessary. This is the first study of this species concerning Hg contamination. Thus, Hg concentrations were investigated in the down of black stork chicks (N = 90) from breeding locations in central and southern Poland (Europe) between 2015 and 2017. As well as Hg levels, morphometric parameters and age were evaluated. Mean Hg concentrations reached 0.7 μg/g d.w. and differed significantly between years, from the lowest value noted in 2017 (mean 0.5 μg/g), through 2016 (0.7 μg/g), to the highest one in 2015 (0.9 μg/g), and between nest locations where higher Hg levels were generally found in northern parts of the study area. Hg concentrations were also unrelated to morphometric parameters. Contrarily, morphometric parameters revealed high correlations between themselves, which was confirmed by the cluster analysis (revealing only two clusters) and principal component analysis (the first PC explained 96.8% of the variance). Hg levels in the down of black storks were rather low with the fluctuation between years and nest locations probably caused by parental exposure during wintering, migration, pre-breeding season and recent exposure through food provided by parents. Such low Hg concentrations seemed not to affect the population from the region studied.

Cadmium (Cd) and its forms has recently been a focus of attention due to its toxic effects on human health and the environment. We evaluated the atmospheric deposition of Cd during three consecutive winter seasons (2009–2011) at 10 mountain-top locations in the Czech Republic along the borders with Poland, Germany, Austria and Slovakia. Cadmium concentrations of soluble and insoluble forms in both horizontal (rime) and vertical (snow) deposition were determined using sector-field ICP-MS. Across the sites, 94% of the total winter Cd deposition occurred in the soluble (environmentally available) Cd form. Mean concentrations of soluble Cd in rime were six times higher than in snow (398 vs. 66 ng L⁻¹). Vertical deposition contributed as much as 41% to the total winter Cd input. Between-site variability in Cd deposition was large, ranging between 13 and 108 μg m⁻² winter⁻¹. Overall, Cd concentrations in winter deposition did not reach the drinking water limits and did not pose a direct threat for human health. Long-term trends (1996–2017) in winter Cd deposition were evaluated at six GEOMON sites (a monitoring network of small forested catchments). Since 1996, Cd input in winter atmospheric deposition decreased by 73–93%. Simultaneously, we found declines in between-site variability in winter Cd inputs. The highest recent winter Cd inputs were found at sites located in the northeast of the country. A north-south pollution gradient, which has frequently been mentioned in the literature, was not observed, with both northwestern sites and southern sites being among those with the lowest Cd pollution. Backward trajectories of the HYSPLIT model for fresh snow samples identified Poland and Germany as major transboundary Cd pollution sources for the Czech Republic.

The current air pollution by SO₂ due to anthropogenic pressure in Poland was assessed based on sulfur concentrations in pine needles (Pinus sylvestris L.). On 308 monitoring sample plots located in pine stands distributed across Poland, measurements were conducted in mineral soil layers (0–10 cm, 10–40 cm, 40–100 cm) and in the soil organic layer (+5–0 cm). Samples of Scots pine foliage (current-year needles) were then collected, and the sulfur concentration in these needles was determined. Based on these data, a map of the spatial variability of sulfur concentrations in pine needles was drawn. The mean sulfur concentration in the pine needles was 854.8 mg kg⁻¹ in dry mass. Higher SO₂ emissions were noted in regions influenced by industry, such as the Upper Silesia and regions under strong urban pressure. Sulfur concentrations in Scots pine needles were related to the stands' degrees of defoliation. A comparison of the current sulfur concentrations in pine needles from biomonitoring in 2015–2016 with those from previous biomonitoring (in 1983–1985, by Dmuchowski and Bytnerowicz (1995) showed that air quality has improved and SO₂ emissions have decreased.

The occurrence and concentrations of a wide range of organic phosphates (OPEs) in vehicle's exhaust (VPM), ambient air particulate matter (APM), and soil of various urban environments were researched. VPM comes from passenger cars, commercial vehicles, marine and bus engines emitted in New European Driving Cycle tests whereas APM was sampled in several sites of the Upper Silesia region (Poland). APM and VPM collected on filters and soil from the same locations as APM sampling sites were extracted with dichloromethane and extracts analyzed by gas chromatography-mass spectrometry. The OPEs found include aryl phosphates such as triphenyl phosphate (TPhP) and tricresyl phosphate (TCP), alkyl phosphates - triethyl phosphate (TEP), tripropyl phosphate (TPP), tributyl phosphate (TBP) and tri(butoxyethyl)phosphate (TBEP), and alkylchlorinated phosphates including tris-(2-chloroisopropyl) phosphate (TCiPP) and tris(2-chloroethyl) phosphate (TCEP). Occurrence and concentrations of these compounds in the PM investigated are highly variable. It was found that total concentrations in APM are directly related to traffic density in particular sites of the urban environment and a style of a vehicle driving. The highest emission of OPEs was found at a crossroad and city center sites where traffic is the densest and vehicles stops and starts are frequent. Village and residential areas were less exposed to OPEs emission. Since OPEs concentrations show exponential correlations to each other also human exposure to these compounds increases exponentially with increasing traffic density. High TEP and TBP level is tentatively proposed as an indicator of emission from petrol-fueled cars. Concentrations of OPEs in some soil are related to their emission to the air and resistance to degradation of a particular compound since only the most resistant TCiPP and TPhP were identified in soil extracts.

The Wiśniówka rock strip mining area (south-central Poland) with quartzite quarries, acid water bodies and tailings piles is one of the most unique acid mine drainage (AMD) sites throughout the world. This is due to the occurrence of enormous amounts of pyrite unknown in sedimentary formations worldwide. Of the two mineralization zones, one that is the most abundant in arsenical pyrite occurs in the lowermost Upper Cambrian formation of the Podwiśniówka quarry. The As-rich pyritiferous clastic rocks are exposed as a result of deep quartzite extraction during 2013–2014. In addition, the clayey-silty shale interbeds are enriched in rare earth element (REE) minerals. The mining operation left an acidic lake with a pH of about 2.4–2.6 and increased contents of sulfates, metal(loid)s and REE. The Podwiśniówka pyrite-rich waste material was stacked up in many places of the mining area giving rise to strongly acidic spills that jeopardized the neighboring environment. One of these unexplored tailings piles was a source of extremely sulfate- and metal(loid)-rich pools with unusual enrichments in As (up to 1548 mg L⁻¹) and REE (up to 24.84 mg L⁻¹). These distinctly exceeded those previously reported in the Wiśniówka area. A broad scope of geochemical, mineralogical and petrographic methods was used to document these specific textural and mineralogical properties of pyrite facilitating its rapid oxidation. The pyrite oxidation products reacted with REE-bearing minerals releasing these elements into acid water bodies. Statistical methods were employed to connect the obtained tailings pool hydrogeochemical data with those derived from this and the previous studies of the Podwiśniówka and Wiśniówka Duża acid pit lakes. In contrast to metal(loid) profiles, the characteristic shale-normalized REE concentration patterns turned out to be more suitable for solving different AMD issues including provenance of mine waste material in the tailings pile examined.

The increased bioeconomy targets for the biomass share of renewable energy production across Europe should be met using land unsuitable for food production. Miscanthus breeding programs targeted the production of plants with a diverse range of traits allowing a wider utilization of land resources for biofuel production without competing with arable crops. These traits include increasing tolerances to drought, chilling, and to metal(loid)s excess. Two novel Miscanthus hybrids, GNT41 and GNT34, were compared against Miscanthus x giganteus (Mxg) on metal-contaminated arable land in Poland. This study aimed at evaluating their yield, biomass quality and quantifying seasonal differences in photosynthetic and transpiration parameters. A secondary objective was to identify key physiological mechanisms underlying differences in metal accumulation between the investigated plants. The new hybrids produced a similar yield to Mxg (13–15 t ha−1 yr−1), had shorter shoots, higher Leaf Area Index and stem number. Based on gas exchange measurements, GNT34 exhibited isohydric (water-conserving) behavior. The stomatal response to light of the new hybrids was at least twice as fast as that of Mxg, a trait that is often associated with increased seasonal water use efficiency. This contributed to the almost 40% reduction in shoot Pb and Cd concentrations for the new hybrids as compared to Mxg. This suggested that promoting stomatal regulation in conjunction with improved water conservation may be a target for improving plants for wider use on metals contaminated land.