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Household Dust from a City in Morocco: Characterization by Scanning Electron Microscopy
2022
Bouchriti, Youssef | Kabbachi, Belkacem | Ait Haddou, Mohamed | Achbani, Abderrahmane | Amiha, Rachid | Gougueni, Hicham
Exposure to household dust is a common occurrence in all countries and causes various diseases. This study provided information on the number, shape, size distribution, and elemental composition of household dust particles collected in urban homes in Agadir city in Morocco. Moreover, a potential human health risk of exposure has been identified based on current research. Samples were analyzed using computer-controlled scanning electron microscopy and ImageJ image processing program. A total of 3296 particles were analyzed for their size, and 76 particles were classified according to their size and elemental composition. Household dust particles were classified in six types: micro-aggregates (31.6%), biogenic (5.3%), spherical (17.1%), subrounded (7.9%), subangular (11.8%), and angular (26.3%). These particles were determined to have originated from a distant source (Trask classification index between 1 and 2.5). They were large (Skewness asymmetry coefficient > 1), and ranged from 0.2 to 363 µm with an average value of 22.8 ± 0.6 µm in diameter. Dust particles with diameters of 5-10 µm and 10-20 µm were the most abundant, while dust diameters of 10-20 µm, 20-30 µm, and > 100 µm were the highest in volume. The domestic dust deposition rate was 19.8 ± 7.4 g/m2 per year. Household dust is one of the major sources of PM10 in the residential environment (44.6% of the total number of particles), and the studied properties of house dust are highly related to human health. Household dust is a critical element to be considered in the occurrence of respiratory and cardiovascular infections.
Mostrar más [+] Menos [-]Size-dependent in vitro inhalation bioaccessibility of PAHs and O/N PAHs - Implications to inhalation risk assessment
2022
Besis, Athanasios | Gallou, Domniki | Avgenikou, Anna | Serafeim, Eleni | Samara, Constantini
Size segregated samples (<0.49, 0.49–0.95, 0.95–1.5, 1.5–3.0, 3.0–7.2 and > 7.2 μm) of atmospheric particulate matter (APM) were collected at a traffic site in the urban agglomeration of Thessaloniki, northern Greece, during the cold and the warm period of 2020. The solvent-extractable organic matter was analyzed for selected organic contaminants including polycyclic aromatic hydrocarbons (PAHs), and their nitro- and oxy-derivarives (NPAHs and OPAHs, respectively). Mean concentrations of ∑₁₆PAHs, ∑₆NPAHs and ∑₁₀OPAHs associated to total suspended particles (TSP) were 18 ng m⁻³, 0.2 ng m⁻³ and 0.9 ng m⁻³, respectively, in the cold period exhibiting significant decrease (6.4, 0.2 and 0.09 ng m⁻³, respectively) in the warm period. The major amount of all compounds was found to be associated with the alveolar particle size fraction <0.49 μm. The inhalation bioaccessibility of PAHs and O/N PAHs was measured in vitro using two simulated lung fluids (SLFs), the Gamble's solution (GS) and the artificial lysosomal fluid (ALF). With both SLFs, the derived bioaccessible fractions (BAFs) followed the order PAHs > OPAHs > NPAHs. Although no clear dependence of bioaccessibility on particle size was obtained, increased bioaccessibility of PAHs and PAH derivatives in coarse particles (>7.2 μm) was evident. Bioaccessibility was found to be strongly related to the logKOW and the water solubility of individual compounds hindering limited mobilization of the most hydrophobic and less water-soluble compounds from APM to SLFs. The lifetime cancer risk due to inhalation exposure to bioaccessible PAHs, NPAHs and OPAHs was estimated and compared to those calculated from the particulate concentrations of organic contaminants.
Mostrar más [+] Menos [-]Seasonal variation of dissolved bioaccessibility for potentially toxic elements in size-resolved PM: Impacts of bioaccessibility on inhalable risk and uncertainty
2022
Jia, Bin | Tian, Yingze | Dai, Yuqing | Chen, Rui | Zhao, Peng | Chu, Jingjing | Feng, Xin | Feng, Yinchang
The health effects of potentially toxic elements (PTEs) in airborne particulate matter (PM) are strongly dependent on their size distribution and dissolution. This study examined PTEs within nine distinct sizes of PM in a Chinese megacity, with a focus on their deposited and dissolved bioaccessibility in the human pulmonary region. A Multiple Path Particle Dosimetry (MPPD) model was used to estimate the deposited bioaccessibility, and an in-vitro experiment with simulated lung fluid was conducted for dissolved bioaccessibility. During the non-heating season, the dissolved bioaccessible fraction (DBF) of As, Cd, Co, Cr, Mn, Pb and V were greater in fine PM (aerodynamics less than 2.1 μm) than in coarse PM (aerodynamics between 2.1 and 10 μm), and vice versa for Ni. With the increased demand of heating, the DBF of Pb and As decreased in fine particle sizes, probably due to the presence of oxide/silicate compounds from coal combustion. Inhalation health risks based on the bioaccessible concentrations of PTEs displayed the peaks in <0.43 μm and 2.1–3.3 μm particulate sizes. The non-cancer risk was at an acceptable level (95th percentiles of hazard index (HI) was 0.49), but the cancer risk exceeded the threshold value (95th percentiles of total incremental lifetime cancer risk (TCR) was 8.91 × 10⁻⁵). Based on the results of uncertainty analysis, except for the exposure frequency, the total concentrations and DBF of As and Cr in <0.43 μm particle size segment have a greater influence on the uncertainty of probabilistic risk.
Mostrar más [+] Menos [-]How small is the big problem? Small microplastics <300 μm abundant in marine surface waters of the Great Barrier Reef Marine Park
2022
Carbery, Maddison | Herb, Frithjof | Reynes, Julien | Pham, Christopher K. | Fong, Wye-Khay | Lehner, Roman
Particle size plays an important role in determining the behaviour, fate and effects of microplastics (MPs), yet little is known about MPs <300 μm in aquatic environments. Therefore, we performed the first assessment of MPs in marine surface waters around the Whitsunday Islands region of the Great Barrier Reef Marine Park, Australia, to test for the presence of small MPs (50–300 μm) in-situ. Using a modified manta net, we demonstrate that MPs were present in all marine surface water samples, with a mean sea surface concentration of 0.23 ± 0.03 particles m⁻³. Microplastics were mainly blue, clear and black fibres and fragments, consisting of polyethylene terephthalate, high-density polyethylene and polypropylene plastic polymers. Tourism and marine recreation were considered the major contributing sources of MPs to surface waters around the Whitsunday Islands. Between 10 and 124 times the number of MPs exist in the 50 μm–300 μm size class, compared with the 1 mm–5 mm size range. This finding indicates that the global abundance of small MPs in marine surface waters is grossly underestimated and warrants further investigation. Research into the occurrence, characteristics and environmental fate of MPs <300 μm is needed to improve our understanding of the cumulative threats facing valuable ecosystems due to this smaller, potentially more hazardous size class.
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