Cellulose acetate (CA) is one of widely used polymers for chemical and medical applications due to its versatile physico-chemical functionalities. Although its recycle is available after a deacetylation process, the recycle process releases a huge amount of wastewater. Thus, this study investigated a direct disposal process of CA with its valorization to syngas (H₂ and CO) through pyrolysis. To construct more environmentally benign process, CO₂ was used as a co-feedstock with CA to simultaneously convert them into syngas. Pyrolysis of CA in N₂ was performed as a reference study to examine the effectiveness of CO₂ on valorization of CA. Acetic acid and methyl acetate were main volatile pyrolysates (VPs) from CA pyrolysis, and the further thermal cracking of VPs resulted in syngas and CH₄ formations under both N₂ and CO₂ conditions. To expedite syngas formations, multi-stage pyrolysis (two-stage pyrolysis) and catalytic pyrolysis were employed. With the increased thermal energy through two-stage pyrolysis, four times more production of syngas was shown, comparing to the result of a single-stage pyrolysis. With Ni catalysts, the syngas formation was the two orders of magnitude higher than the single-stage pyrolysis, and the significant enhancement of CO formation was shown in the presence of CO₂ due to combined effects of CO₂ and the Ni-based catalysts. This CO enhancement resulted from catalytically expedited gas phase reactions between CO₂ and VPs evolved from CA. In addition, the CO₂ contributed to the suppression of coke deposition on the catalyst, thereby suggesting more technical and environmental benefits of CO₂ as a reactive co-feedstock of pyrolysis in reference to N₂. Therefore, this study proved the direct and versatile technical platform to convert CA and CO₂ into syngas.

The installation of marine renewable energy devices (MREDs, wind turbines and converters of wave, tidal and ocean thermal energy) has increased quickly in the last decade. There is a lack of knowledge concerning the effects of MREDs on benthic invertebrates that live in contact with the seabed. The European common cuttlefish (Sepia officinalis) is the most abundant cephalopod in the Northeast Atlantic and one of the three most valuable resources for English Channel fisheries. A project to build an offshore wind farm in the French bay of Saint-Brieuc, near the English Channel, raised concern about the possible acoustic impact on local cuttlefish communities. In this study, consisting of six exposure experiments, three types of noise were considered: 3 levels of pile-driving and 3 levels of drilling. The objectives were to assess possible associated changes in hatching and larva survival, and behavioural and ultrastructural effects on sensory organs of all life stages of S. officinalis populations. After exposure, damage was observed in the statocyst sensory epithelia (hair cell extrusion) in adults compared to controls, and no anti-predator reaction was observed. The exposed larvae showed a decreased survival rate with an increasing received sound level when they were exposed to maximum pile-driving and drilling sound levels (170 dB re 1 μPa² and 167 dB re 1 μPa², respectively). However, sound pressure levels's lower than 163 dB re 1 μPa² were not found to elicit severe damage. Simulating a scenario of immobile organisms, eggs were exposed to a combination of both pile driving and drilling as they would be exposed to all operations without a chance to escape. In this scenario a decrease of hatching success was observed with increasing received sound levels.

Insulation materials are essential components in construction, and their main objective is to increase the efficiency of thermal energy by minimizing internal and external thermal exchange. Accordingly, research and development studies are being actively conducted to increase the thermal resistance of insulation materials, and high-performance insulation materials that use organic chemicals have been developed after industrialization. However, thermal insulation comprising chemicals poses a potential risk of pollutant emissions and can cause health problems. In this study, five types of insulation materials and the contaminants generated from the building materials used in insulation construction were quantitatively analyzed. In addition, an empirical study on the discharge of pollutants was conducted using a test bed, and the effects of the pollutants discharged from the insulation material on the indoor environment were examined by analyzing the pollutant concentration for 90 days. In addition, we analyzed the effect of an insulation material on an indoor environment through the standard specifications. Moreover, the necessity of legal management of the emission of contaminants from insulation materials was proposed based on the empirical research results.

The intermittent nature of solar radiation requires a thermal energy storage (TES) system for reducing the mismatch between energy demand and supply. Solar water heating (SWH) systems can help save up to 90% of the utilized energy for water heating. In this study, a compound parabolic concentrator (CPC) solar collector has been coupled to three different configurations of TES system. A comprehensive analysis on the effects of PCMs arrangements in TES systems viz three PCMs (case 1) and five PCMs (case 2) on the energy efficiency, exergy efficiency, and overall loss coefficient of the solar collector and TES system has been made and compared with sensible TES system. An experimental data showed an augmented energy storage of 12% and 41% in “case 1” and “case 2” over sensible TES system as a result of reduction in heat losses with the cascaded arrangement of PCMs. The collector paired with case 2 configuration clearly exhibited a higher exergy efficiency due to supply of heat transfer fluid at relatively lower temperature while compared to other TES configurations. The outcomes of this study reveal the key role of cascaded arrangement of PCMs for enhancing energy and exergy efficiencies of solar collector.

The present research work aims to investigate the energy saving aspects in cool thermal energy storage system (CTES) by improving the thermophysical properties of deionized (DI) water. The influence of phase change enthalpy, specific heat, thermal conductivity, and cooling rate of the DI water for the dispersion of chemically functionalized multi-walled carbon nanotubes (f-MWCNT) is studied experimentally. The covalent functionalization method is used to modify the surface of the multi-walled carbon nanotubes (MWCNT) with the use of concentrated nitric acid. The nanofluid phase change materials (PCMs) in different mass concentrations (0.25%, 0.50%, and 0.75%) were prepared by dispersions of the f-MWCNT in DI water. The minimum reduction in enthalpy (4.01%) was recorded for the nano-PCM with 0.75% f-MWCNT as compared to the base PCM with 0.5% of sodium dodecyl benzene-sulfonate (10%). The thermal conductivity enhancement of 53.15% and 28.2% was recorded in both states for the nano-PCM (with 0.75%) at the temperature of − 10 °C and 5 °C respectively. Also, the enhancement of 30% and 23% in cooling rate is recorded for the dispersion of maximum concentration of f-MWCNT at the HTF temperatures of − 8 °C and − 6 °C, respectively. It is proven from the above findings that the dispersion of f-MWCNT reduces the subcooling and facilitates the running of the CTES system at a higher operating temperature.

The investigation of a solar collector is based on the thermal behaviour of a carrier fluid and the degradation of energy across a flat plate collector. The exergy analysis of a thermal system includes the change in the exergy function of a carrier fluid while transferring solar radiation across an air gap. The cell cast acrylic glass was used to transmit the incident solar radiation to the absorber plate, and to safeguard the absorber plate from the outside environment. With the help of the steady flow energy equation, the enthalpy of the carrier fluid (moist air) was calculated. The specific humidity of the incoming air was calculated at an average dry bulb temperature of 299.4 K. The stagnation temperature at a limiting condition was also estimated to find out the maximum permissible limit for a given thermal design. The mass flow rate of air was assumed to be 5.2 g-s⁻¹. The efficiency of the solar collector was found to vary from 40 to 42%, whereas the thermal energy available for drying was 15–59% of the exergy of the carrier fluid. The net entropy generation rate due to the collector plate was calculated to be 0.12 W-K⁻¹.

Although the solar distillers are one of the economic solutions for addressing the freshwater shortage problem around the world, these devices suffer from low productivity. In this paper, a simple and inexpensive modification was made in the tubular solar still (TSS) to improve its productivity. The adjustment is to tilt the glass cylinder, something to help the droplets move down and collect them as a distillate. The modified inclined TSS was abbreviated by ITSS. Then, three different inclination angles were investigated (2°, 4°, and 6°), and the performance of ITSS with these inclination angles was compared with that of TSS without inclination angle (0°). Moreover, to obtain additional productivity for ITSS, the basin was painted with a mixture of matte black paint with nanomaterials. Three types of nanomaterials were studied (copper oxide nanoparticles, titanium oxide nanoparticles, and silver nanoparticles). For further improvement in ITSS productivity, Ag nanoparticles mixed with phase change material (PCM) were employed beneath the ITSS base to work as thermal energy storage material. Experimental results revealed that the highest average daily productivity rise for ITSS over TSS was observed when tilting ITSS by 6°, where the daily productivity rise and thermal efficiency reached 24% and 37.6%, respectively. Besides, the average increase in daily distillate of ITSS was 34%, 30%, and 28.5% when using Ag, CuO, and TiO₂, respectively, compared to that of TSS. Moreover, ITSS with Ag provided the best thermal efficiency compared to the other operating cases, where it was 39.1%. In addition, ITSS-PCM-Ag showed a daily productivity of 62.5% more than that of TSS and a thermal efficiency of 43.5%.

Solar energy has been a vital renewable energy source for humanity for decades. Researchers have proposed many strategies to harness the same but solar photovoltaic (PV) is the only technology which has reached commercial scale and highly successful in meeting renewable energy goals of many countries. The major drawback of PV systems is that increase in the temperature of solar cell of the PV module beyond the threshold limit brings down its electrical efficiency (EE). Hence, this review paper discusses the different cooling techniques responsible for reducing the cell temperature, which in turn increases not only its EE, but also collection of the thermal energy that is otherwise considered to dampen the performance of the PV system. A brief study on PV with air cooling, photovoltaic thermal (PVT) with water cooling, PVT/PCM with and without fins, PVT integrated with nanofluids has been done in this review paper. PVT hybrid systems are the need of hour to get the optimum efficiency. Amongst the PVT systems, the performance analysis of PV integrated with the nanofluid is discussed and it is found to give the maximum cell temperature reduction. Since reduction in the cell temperature directly relates to better efficiency, PVT system using nanofluid as a cooling medium gives the best overall efficiency (OE) followed by PVT system incorporating water and air respectively. This review paper also gives spotlight to the real-time usages of PCM and nanofluids for the effective cooling ability especially in the case of PV module.

Slurry fuels based on wood and coal processing and petroleum refinery waste are an environmentally friendly and economically feasible alternative to the conventional solid fuel-coal. As part of this experimental research, we compared a set of fuels (coal and coal-water slurries with and without petrochemicals) by normalizing and calculating the specific concentrations of pollutants from their combustion. The pollutant concentrations were normalized with respect to the mass of burnt fuel, the thermal energy released by combustion, specific mass emissions per unit time, specific maximum mass emissions, and specific mass emissions per 1 kg of fuel equivalent or 1 MJ of thermal energy. The key objective of this research was to develop a method for comparing composite fuels in terms of their relative environmental friendliness. As part of the research, coal combustion was notable for the peak emissions of gaseous pollutants irrespective of the fuel mass and combustion chamber temperature. When slurries were burnt, CO₂, SO₂, and NOₓ concentrations were 12–90% lower as compared to coal. The research findings established that the most promising fuel of all the slurries under study is the one based on coal slime and sawdust due to its high environmental indicators.

This experimental study analyzed the use of solar photovoltaic energy for operating a novel twin-circuit DC milk chiller without batteries using water-based cold thermal energy storage for different seasons in Chennai, India. HFC-134a and HC-600a were used as refrigerants in the two individual circuits. For each season, the test was conducted continuously for 18 days to analyze the quantity of generated ice that could be utilized to chill 10 L of milk in the morning and in the evening. The average quantity of ice formed per day in the ice bank during monsoon, winter, and summer seasons was found to be 3.61, 19.75, and 27.97 kg, respectively. Thus, it is evident that the use of solar energy with thermal energy storage is effective for operating the milk chilling unit for two seasons, namely winter and summer. However, the system requires an additional power source for continuous operation during the monsoon season. It is noteworthy to mention that the use of a solar milk chiller instead of a conventional milk chiller resulted in 91.15% lesser CO₂ emission with 27.6% less LCC. In this study, solar photovoltaic power was observed to be a good choice for chilling milk in the context of global warming and energy consumption. The use of thermal energy storage also allows the initial cost to be reduced.