Measuring loads of bioavailable metals is important for environmental assessment near mines and other industrial sources. In this study, a setup of monitoring buoys was tested to assess loads of bioavailable metals near a former Pb–Zn mine in West Greenland using transplanted seaweed, mussels and sea snails. In addition, passive DGT samplers were installed. After a 9-day deployment period, concentrations of especially Pb, Zn and Fe in the species were all markedly elevated at the monitoring sites closest to the mine. Lead concentrations in all three species and the DGT-Pb results showed a significant linear correlation. Zinc and Fe concentrations were less correlated indicating that the mechanisms for Zn and Fe accumulation in the three species are more complex. The results show that there is still a significant load of metals from the mine and that such buoys can be an adequate method to assess present loads of bioavailable metals.

Mercury (Hg) is a toxic element distributed globally through atmospheric transport. Agattu Island, located in the western Aleutian Islands, Alaska, has no history of point-sources of Hg contamination. We provide baseline levels of total mercury (THg) concentrations in breast feathers of three birds that breed on the island. Geometric mean THg concentrations in feathers of fork-tailed storm-petrels (Oceanodroma furcata; 6703±1635, ng/g fresh weight [fw]) were higher than all other species, including snowy owl (Bubo scandiacus; 2105±1631, ng/g fw), a raptor with a diet composed largely of storm-petrels at Agattu Island. There were no significant differences in mean THg concentrations of breast feathers among adult Kittlitz’s murrelet (Brachyramphus brevirostris; 1658±1276, ng/gfw) and chicks (1475±671, ng/gfw) and snowy owls. The observed THg concentrations in fork-tailed storm-petrel feathers emphasizes the need for further study of Hg pollution in the western Aleutian Islands.

This study describes the changes in hydrology, zooplankton communities and abundance in the Senegal River Estuary (SRE) before and after the breaching of the sandbar in October 2003. Samples were taken in 2003 at 3 stations located upstream (DI), in mid estuary (HY) and downstream (RM), and in 2005 at the same stations (RM becoming Old River Mouth: ORM), plus the new river mouth (NRM) resulting from the morphological evolution of the SRE.The study showed marked seasonal variations that affected the structure and distribution of zooplankton as well as major changes caused by the sandbar opening:–increased marine influence throughout the whole SRE,–changes in the horizontal gradients,–arrival of euryhaline species and increase in meroplankton, in particular decapod larvae,–transformation of the ORM area into a slackwater area with limited exchanges and the highest zooplankton numbers during high waters.

Invasive coral species of the genus Tubastraea have been increasingly recorded in Southwestern Atlantic waters since the 1980s. Their invasion and infestation are mainly related to port and oil exploration activities. For the first time the presence of Tubastraea tagusensis colonies is reported in Espírito Santo State, colonizing a port shore area, and incrusting oil/gas platform structures situated in the southern Abrolhos Bank, which is part of the most important coral reef system of the South Atlantic Ocean. Tubastraea colonies exhibit fast growth and high recruitment rates, and colonized 40% of the analyzed structures in just four years. The projection of port and oil/gas industry growth for the Espírito Santo State (more than 300%) highlights an alert to the dispersal of this alien species to natural areas.

The North Atlantic right whale (Eubalaena glacialis) faces increasing pressure from commercial shipping traffic and proposed marine renewable energy developments. Drawing upon the successful Stellwagen Bank National Marine Sanctuary model, we propose a multi-stakeholder marine spatial planning process that considers both appropriate positioning of offshore wind farms and redefining commercial shipping lanes relative to whale migration routes: placement of wind turbines within certain right whale habitats may prove beneficial for the species. To that end, it may be advisable to initially relocate the shipping lanes for the benefit of the whales prior to selecting wind energy areas. The optimal end-state is the commercial viability of renewable energy, as well as a safe shipping infrastructure, with minimal risk of collision and exposure to shipping noise for the whales. This opportunity to manage impacts on right whales could serve as a model for other problematic interactions between marine life and commercial activities.

This study focuses on the coastal monitoring network established in the scope of WFD implementation. The objective of this network was to provide an ecological assessment of Valencian coastal waters. After three years, sufficient data had been collected to enable us to analyse and explore ways to increase the network’s efficiency.A methodology was developed to select the best subset of sampling stations to be surveyed. This method was approached from the perspective of an inter-observer variability problem. In order to compare the concordance between the k-observers and the reference observer, two measures were considered: euclidean distance, and interclass correlation coefficient.The obtained results confirm that the current network can be reduced by over 50% and still guarantee accurate results. This methodology (not limited by indicators, geographically, or by type of water body) could be applied to different environmental monitoring networks and could significantly decrease the efforts and costs required by the WFD.

Results from a comprehensive oil weathering and dispersant effectiveness study of the MC252 crude oil have been used to predict changes in oil properties due to weathering on the sea surface and to estimate the effective “time window” for dispersant application under various sea conditions. MC252 oil is a light paraffinic crude oil, for which approximately 55wt.% will evaporate within 3–5days when drifting on the sea. An unstable and low-viscosity water-in-oil (w/o) emulsion are formed during the first few days at the sea surface. This allows a high degree of natural dispersion when exposed to breaking wave conditions. Under calm sea conditions, a more stable and light-brown/orange colored water-in-oil (w/o) emulsion may start to form after several days, and viscosities of 10,000–15,000mPas can be achieved after 1–2weeks. The “time window” for effective use of dispersants was estimated to be more than 1week weathering at sea.

Anthropogenic perturbations exert important impacts on sulfur geochemistry in marine sediments. In the study, chemical extraction was used to quantify four sulfur pools, i.e., pyrite, humic-acid sulfur (HA-S), fulvic-acid sulfur (FA-S), and residual organic sulfur (ROS), in surface sediments of eutrophic Jiaozhou Bay. Results show that riverine inputs are the main control on organic matter (OM) distribution in the sediments. OM enrichment in the eastern coast is mainly due to discharges of anthropogenic wastes. Spatial coupling of pyrite and FA-S vs. TOC points to the impacts of OM enrichment on formation and preservation of pyrite and FA-S. Poor spatial coupling of HA-S vs. TOC is due to low fractions of diagenetic OS in the pool. ROS is mainly from riverine inputs and anthropogenic OS has been superimposed on this pool. Spatial coupling among TOC, pyrite-S and FA-S is a sensitive indicator of anthropogenic impacts on benthic processes of the bay.

The suitability of a rootless Bromeliad species (Tillandsia usneoides) as biomonitor of airborne trace elements in urban areas of the Mediterranean basin was evaluated. The study was performed at five sites of the city of Pisa (Tuscany, Central Italy) differing for land use, anthropogenic activities and/or proximity to emission sources. The elements investigated were Al, As, B, Ba, Bi, Ca, Cd, Co, Cr, Cs, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Sb, Sr, V and Zn. Unwashed and washed samples, collected after 36 days of exposure (May–June 2011), were analyzed by ICP–MS. Results showed significant differences among sampling sites for several elements. Concentrations of Al, Ba, Bi, Cd, Co, Cu, Pb, Sb and Zn were the highest in urban/traffic and/or suburban/traffic areas. Some of these elements e.g. Ba, Cu, Sb and Zn are commonly considered as traffic–related elements. In the industrial site, the main elements found were Mg, Sr and Zn. Iron, Mn, Na and V concentrations were much higher in rural/remote areas. Enrichment factors highlighted that T. usneoides showed: high resistance/tolerance to heavy metal toxicity, specificity, capability to well–definitely represent a sampling site, quantitative response to pollutant exposure. The results indicated that T. usneoides reflects the intrinsic characteristics of each sampling area and allows tracing back differences related to the various emission sources by factor analysis.

This study examined trends in contaminants measured during three decades of “Mussel Watch” monitoring on the California coast. Chlorinated organic contaminants and butyltins declined the most rapidly, with tissue concentrations in 2010 that were up to 75% lower than during the 1980s. Silver and lead declined at about half of the stations statewide, but generally exhibited slower rates of decline relative to the organic compounds. In contrast, copper increased at many stations, and PAHs showed little evidence for declines. Mussels from San Francisco Bay and the Southern California Bight were historically the most contaminated and have had the steepest declines. Overall, these data show that the “Mussel Watch” approach to monitoring contaminants in California has provided some of the best evidence of the effectiveness of actions to improve water quality over the past 30years. These datasets also highlight challenges that remain in managing PAHs and copper.