The current work reports on the degradation of glycerol aqueous solution via photocatalytic-Fenton technique. The CuFe₂O₄ photocatalyst was synthesized via sol-gel method and its physicochemical properties were characterized. The as-synthesized photocatalyst possessed Brunauer-Emmett-Teller (BET)-specific surface area of 104 m²/g. The large BET-specific surface area was also corroborated by the field-emission scanning electron microscopy (FESEM) images which showed porous morphology. In addition, the XRD pattern showed that the visible light-active component, CuFe₂O₄, was successfully formed with band gap energy of 1.58 eV determined from the UV-Vis diffuse reflectance spectroscopy. Significantly, it was determined from the blank run study that the visible light was an integral part of the photoreaction. Without the visible light irradiation, glycerol degradation was low (<4.0 %). In contrast, when visible light was present, the glycerol degradation improved markedly to attain 17.7 % after 4 h of visible light irradiation, even in the absence of CuFe₂O₄ photocatalyst. This can be attributed to splitting of H₂O₂ into hydroxyl (●OH) radical. In the presence of CuFe₂O₄ photocatalyst, the photocatalytic Fenton degradation of glycerol has further enhanced to record nearly 40.0 % degradation at a catalyst loading of 5.0 g/l. This has demonstrated that the CuFe₂O₄ was capable of generating additional hydroxyl radicals to attack the glycerol molecule. Moreover, this degradation kinetics can be captured by Langmuir-Hinshelwood model from which it was found that the adsorption constant related to H₂O₂ was significantly weaker compared to the adsorption constant of glycerol.

Calcium nitrate and a lanthanum-modified bentonite (Phoslock®) were investigated for their ability to control the release of phosphorus from contaminated sediment. Their effectiveness and mode of action were assessed using microcosm experiments by monitoring the variation of physiochemical parameters and phosphorus and nitrogen species over time following the treatment for 66 days. Phoslock® was more effective reducing phosphorus in overlaying water and controlling its release from sediment. Calcium nitrate improved redox condition at the sediment-water interface and temporally reduce phosphorus in overlaying water but phosphorus level returned back in a long run. Phosphorus fractionation suggested that Phoslock® converted mobile phosphorus to more stable species while calcium nitrate increased the fractions of mobile phosphorus species. Phoslock® generally showed no effect on nitrogen species. Whereas calcium nitrate temporally increased nitrate, nitrite, and ammonium concentrations but their concentrations quickly reduced likely due to the denitrification process. Results suggested that Phoslock® can be more effective in controlling the release of phosphorus from sediment than calcium nitrate. However, calcium nitrate can improve the redox condition at the sediment-water interface, which may provide other benefits such as stimulating biodegradation.

The dust removal performance of two types of modified electrode electrostatic precipitator systems was evaluated and compared with that of a conventional aluminum plate electrode using laboratory-scale experiments. In the novel electrode systems, the electrode surface was coated with activated carbon using a mixed slurry containing carbon black, polyvinyl acetate, and methanol. The modification of the electrode surface improved dust precipitation by increasing the specific capacitance of the electrode. The modification also lowered the electrode’s resistance and increased its specific surface area. The optimum electrode spacing and electric voltage supply were determined using batch-type tests. In addition, dielectric insulators were applied as a partition between the oppositely charged electrodes equipped with the modified electrode plates. Multi-layered office paper cut to the same size as the electrodes was used as an insulating material. The addition of the insulator resulted in excellent improvement in the dust removal performance by minimizing the back-corona discharge phenomenon as well as doubling the dust collecting surface. Continuous dust removal tests with the three electrode systems revealed that whereas the conventional aluminum electrode exhibited 54 % dust removal, the activated carbon (AC)-coated system showed 85 % and AC-coated + insulator system showed 90 % and higher dust removal efficiency.

Natural zeolitic tuff was modified with FeCl₃solution for the removal of fluoride, and the effect of chloride, nitrate, and sulfate ions was examined on fluoride sorption from solutions and drinking water. The unmodified zeolitic tuff (Z) and the iron-modified zeolitic tuff (Fe(III)-Z) were characterized by scanning electron microscopy and X-ray diffraction analysis. The elemental composition, the specific surface area, and the point of zero charge of the zeolitic material were also determined. The fluoride adsorption was carried out in a batch system considering the effect of contact time, the initial concentration of fluoride ions, and the effect of other anions naturally present in the drinking water. The kinetic and isotherm results were adjusted to the pseudo-second-order and Freundlich models, respectively, which indicated that the sorption mechanism was chemisorption on a heterogeneous material. The fluoride sorption capacity was higher in solutions (2.7 mg/g) than in drinking water (0.41 mg/g), and this could be attributed to the presence of other anions. Overall, the presence of chloride ions significantly diminished the fluoride adsorption capacity, while the presence of nitrate and sulfate ions did not show any significant effect; the anion removal efficiency by Fe(III)-Z followed the order F⁻ > > Cl⁻ > NO₃⁻ > SO₄²⁻.

Grape stalks, a low-cost agro-industrial by-product, were used for the first time as a biosorbent for the removal of uranium from aquatic systems. Basic operating conditions (effect of pH, biosorbent dose, uranium initial concentration, and kinetics) were investigated, and the sorption mechanism was explored. The proposed biosorbent’s efficiency to sequester uranium from different profile aquatic systems was assessed, as well as the potential uranium recovery. Biosoprtion performance increased progressively from pH 1.5 to 4.5, and uranium uptake was a rapid process, where film diffusion was the determining step. Maximum uptake ranged from 90 to 115 mg U(VI) g⁻¹at 15–33 °C, respectively. None of the commonly used adsorption models (Langmuir, Freundlich, Dubinin-Radushkevich) was able to describe the experimental isotherms, whereas the linear model seems to provide the best fit. Kinetic and thermodynamic data implied that both physical and chemical sorption are involved in the process. Species calculation experiments showed that only positively charged and uncharged uranium species can be retained on the biomass. Quantitative uranium recovery was achieved by mild desorbing agents at concentrations as low as 0.1 M. Therefore, grape stalks seem to be a promising biosorbent due to their high sequestration capacity even under high salinity and acidity conditions, low cost, and easy regeneration.

To test the hypothesis that lead (Pb) content of rice grain may be related to its transport and subcellular distribution in rice plant, the present study was conducted with six rice cultivars of different types under different soil Pb levels. The results showed that grain Pb concentrations were correlated positively and significantly (P < 0.05 or 0.01) with distribution ratios (DRs) of Pb from shoots to ears/grains, but insignificantly (P > 0.05) with the DR from roots to shoots. The DR from shoots to ears/grains was correlated positively and significantly (P < 0.05 or 0.01) with subcellular distribution ratios (SDRs) of Pb in soluble fraction of shoots, but negatively and significantly (P < 0.05 or 0.01) with the SDR in cell wall fraction of shoots. In conclusion, Pb transportation from the shoot to the grain is the key factor in determining Pb content of rice grain. The Pb distributed in soluble fraction of shoot tissue is the key source of Pb for transferring into the grain. The Pb precipitated in cell wall fraction is the key sink of Pb in shoot tissue that restricts the transport of Pb from the shoot to the grain.

Peatlands are often regarded as metal repositories, but under drought conditions may switch from sinks to sources of metals and contaminate downstream ecosystems. To evaluate whether the release of metals into soil solution in peatlands is predictable using simple, widely available soil parameters, six peatlands, with varying levels of metal contamination, including a previously limed peatland, were sampled around the Sudbury, Ontario, region, and were subjected to simulated drought. The simulated drought lowered soil water pH and dissolved organic carbon (DOC) concentrations, which is consistent with field observations. Metal partitioning (K d) values for Co, Mn, Ni, and Zn, with just one exception at one peatland, could be significantly predicted by just the pH of the soil water, although the strength of the relationship varied considerably among sites. The metal speciation model WHAM VII predicted that the free metal ion concentration of all metals tested, including Cu and Al, increased significantly with decreasing pH. At the same time, DOC-bound metal concentrations were predicted to decrease as DOC levels were lower, which for metals with strong organic matter affinities (Cu and Al) offset the increase in free metal ion concentration in soil solution following summer drought. Climate change forecasts for more frequent and sustained droughts may promote metal release from peatlands and increased mobilization to surface waters, and importantly, for some metals, the potential toxicity of the metals released from peatlands may increase to a greater extent than expected from increases in total metal concentrations because of decreased DOC following drought.

The effluent of the ornamental rock industry is characterized by presenting great concentrations of total solids, high contents of iron, and elevated pH, all responsible for the contamination of the superficial and ground waters, destruction of the soil, the vegetation, and the silting of the rivers. The purpose of this study is to assess the cytotoxic and genotoxic effects and the anatomical changes caused by the effluents arising from the ornamental rock polishing industry in root apex cells of Allium cepa L. (Amaryllidaceae). The samples of the effluent were collected in a polishing industry located in Nova Venécia, State of Espírito Santo, and were analyzed by mass spectrometry and atomic emission. Bulbs of A. cepa were exposed to the effluent at 12.5, 25, 37.5, 50, 75, and 100 % concentrations (residue in raw form) (v/v) for a period of 20 days. For the positive control, metilmethanesulfonate (MMS) at 4 × 10⁻⁴-M concentration was used, and distilled water was used for the negative control. The experiment was assessed taking into consideration the following parameters: mitotic index, frequency of chromosomal and nuclear abnormalities in the root apical meristem, and root anatomy. The mitotic index suffered a decrease proportional to the increase in the concentration of effluent. All the concentrations of the effluent led to chromosomal and nuclear abnormalities being stickiness and nuclear shoots the most frequent. The root apex evidenced changes that reflected on the decrease of the percentage area of the protoderm and the fundamental meristem and the increase in the areas of the cap and quiescent center. The symptoms of toxicity are related to the high frequency of cell in cellular death process observed in the roots exposed to the higher concentrations and to the decrease in the mitotic index of the apical root meristem.

Rhizoctonia zeae SOL3 fungus was isolated from contaminated soil based on its ability to decolorize remazol brilliant blue R in solid medium. This fungus has been used to degrade pyrene a four-ring polycyclic aromatic hydrocarbon. R. zeae SOL3 could biodegrade pyrene as a sole source of carbon and energy. Different parameters were investigated to study their effect on the biodegradation rate. The highest biodegradation rate reached at 28 °C, non-agitated culture, 20 g/L glucose, 24 g/L NaCl, and 20 mg/L pyrene. The metabolites of pyrene were detected by thin layer chromatography (TLC) and confirmed by gas chromatography–mass spectrometry (GC-MS), which were identified as benzoic acid, 4-hydroxybenzoic acid and botanic acid.

In the present study, facile and competent homogeneous liquid–liquid microextraction via flotation assistance (HLLME-FA) method combined with flow injection flame atomic absorption spectrometry (FI-FAAS) was proposed for simultaneous separation/preconcentration and determination of trace amounts of cadmium and copper in water samples. The efficient 2-(3,4-dihydroxyphenyl)-1,3-dithiolane (DHPDTO) with thiol groups was used as chelating reagent. The predominant parameters influencing the HLLME-FA, such as solution pH, concentration of DHPDTO, extraction and homogeneous solvent types and volumes, ionic strength, and extraction time were studied. Applying all the optimum conditions in the process, the detection limits of 0.008 and 0.01 μg L⁻¹, linear ranges of 0.08–40 and 0.1–45 μg L⁻¹, and the precision (RSD%, n = 7) of 3.4 and 3.9 % were obtained, respectively, for cadmium and copper. The proposed procedure showed satisfactory results for analysis of tap water, river water, well water, and seawater.