Anthropogenic activities have altered the geomorphological and ecological conditions of the Nakdong River Estuary (NRE) dramatically over the last century. The objectives of this study were to classify NRE sub-environments and to identify their unique ecological functions. The first step in classification was the establishment of 14 a priori sub-environmental groups based on landscape factors. Surface sediments obtained for these groups were analyzed for factors related to grain size and organic matter. Based on the results, the NRE was divided into two primary estuarine environment divisions: (1) a mixed marine and terrestrial environment influenced primarily by land; and (2) a principally marine environment influenced primarily by the ocean. Using multivariate analysis, we subdivided these primary estuarine divisions into six sub-environments, including Sub-1 and -2 in the former and Sub-3, -4, -5, and -6 in the latter.

Microplastics (MP) are detected in aquatic environments worldwide, yet detection is often limited to larger sized MP. To address this data gap, the abundance of MP 3–500 μm was assessed in the Los Angeles River, the San Gabriel River, and the Long Beach Harbor (CA, USA), three areas with highly urbanized surroundings. Whole surface water samples were taken, subjected to a hydrogen peroxide digestion and MP counts were compared between unstained visual examination and Nile Red staining identification techniques. The largest concentration of MP was found in the Los Angeles River, where 13,622 MP m−3 were found using unstained visual examination and 641,292 MP m−3 were found utilizing Nile Red staining. The protocol used to detect smaller sized MP is low cost, time efficient, and reproducible. This work highlights the need for more extensive sampling of smaller sized MP globally and universal testing and reporting standards for MP detection.

Using a laboratory simulation experiment, we studied the trend of change in methylmercury (MeHg) content of sediments in response to the changing salinity of flooding water (deionized water, 0.5%, 1.0%, 1.5%, and 2.0%) and sulfate-reducing bacteria (SRB) content for both the surface layer (0–10 cm) and the bottom layer (10–20 cm) of Suaeda heteroptera wetland sediments in the Liaohe estuary under anaerobic and aerobic conditions, respectively. The results showed that under AAC (anaerobic conditions), the MeHg content in the surface and bottom sediment layers increased first and then decreased over time and was highest at the 14th day. In contrast, under AC (aerobic conditions), the MeHg content in sediments of both layers increased slowly with increasing test time. The MeHg content in sediments increased first and then decreased with rising salinity and was highest at a salinity of 1.0%. Among the samples collected at different experimental stages, the SRB content in the sediments showed a decreasing trend with rising flooding salinity under AAC and AC. The MeHg and SRB contents were higher under anaerobic conditions than under aerobic conditions. Linear fitting results showed that there was no linear correlation between MeHg contents and SRB quantities in surface and bottom sediments under AAC and AC (R² < 0.1). Collectively, these results suggest an important role for flooding salinity and anaerobic-aerobic conditions in the production of MeHg in S. heteroptera wetlands of the Liaohe estuary, and may predict the ecological risk of methylmercury according to the change of salinity.

Knowledge of key species sensitivity for oil spill response (OSR) options is needed to support decision-making and mitigate impact on sensitive life stages of keystone species. Here, Northern shrimp (Pandalus borealis) larvae were exposed for 24 h to a gradient (H-High, M-Medium: 10 times dilution and L-Low: 100 times dilution) of mechanically- (MDO) (H < 6 mg/L total hydrocarbon content) and chemically- (CDO) dispersed oil (Slickgone NS, H < 20 mg/L total hydrocarbon content), followed by a recovery period. Larval mortality, feeding rate and development were evaluated.Overall, the results show that 24 h exposure to field-realistic concentrations of CDO lead to lower survival, reduced feeding rate and slower larval development in P. borealis larvae compared to MDO. These effects persisted during recovery, indicating a higher vulnerability with dispersant use and the need for longer observation periods post-exposure to fully evaluate the consequences for sensitive life-stages from OSR.

This study focused on the determination of seven volatile methylsiloxanes (VMSs) and eleven UV-filters (UVFs) in beach sand from the Oporto's region (Portugal). A QuEChERS methodology (“Quick, Easy, Cheap, Effective, Rugged, and Safe”) was used to extract VMSs from the sand, which has never been employed before. To extract the UVFs, a solid-phase microextraction (SPME) was used. The analyses were performed by gas chromatography–mass spectrometry (GC–MS). Twenty-three beach sand samples were analysed, from two campaigns – summer/winter. VMSs were found in all the samples with concentrations ranging from 0.007 ± 0.001 to 17.8 ± 0.9 ng g−1dw, while UVFs in summer samples from 0.030 ± 0.001 to 373 ± 17 ng g−1dw. Cyclic VMSs and octocrylene (OC) were detected in higher concentrations. In general, higher levels were detected in summer than winter. Hazard quotients were determined and 3-(4′-methylbenzylidene) camphor (4-MBC), 2-ethylhexyl 4-methoxycinnamate (EMC) and benzophenone-3 (BP3) presented values >1, which may indicate that they may pose an ecotoxicological risk.

The main objectives of the present study were to measure the concentration of mercury in Alosa spp. muscle tissue and to assess the health risk to consumers. For this purpose, fish samples were collected from four regions of the southern coast of the Caspian Sea. Mean concentrations of mercury in the regions of Bandar Torkaman, Feridonkenar, Chalos and Bandar Anzali were 264.10, 73.74, 161.90, and 183.80 μg g−1 dw, respectively. The mercury averages obtained in all four regions were below the standards recommended by the World Health Organization (WHO), the Food and Agriculture Organization (FAO), the Standardization Administration of China (SAC) and the Joint FAO/WHO Expert Committee on Food Additives (JECFA). The values of hazard quotient also showed no potential health risk for consumer. However, the assessment of other contaminants is recommended for more accurate conclusions about the health risks of consumers through the consumption of the fish.

The mechanism of fish kill events is not thoroughly understood in Kuwait Bay (KB). However, it is obvious that fish kill events have a close relationship with hypoxia due to some biogeochemical processes. Hydrodynamics controls the dissolved oxygen (DO) concentration that occurs within various spatial and temporal scales. The current study utilizes a previously validated hydrodynamic model to drive a three-dimensional water quality model for KB. The water quality model was validated using comprehensive field measurements during the summer of 2018. Reasonable model computations were achieved to represent the general patterns of the DO in KB. The model computations reproduced the formation of hypoxic water parcels. Some minor fish kill events that occurred during summer 2018 correlated well with predicted hypoxic parcels. The hydro-environmental controls over the extent of the hypoxic parcels and interplaying forces shall be addressed in a separate article by the same authors.

Vessels, specifically ballast water and hull fouling, are a major vector for the introduction of non-indigenous species (NIS) in European seas. The Mediterranean is one of the world's marine regions where their invasion is heaviest. The shallow Adriatic basin is a highly sensitive area that is already experiencing its consequences. The secondary spread of NIS over a wider area through natural dispersion is a complex process that depends on a wide range of oceanographic factors. This work analysed the dataset of the BALMAS project, in whose framework twelve ports in the Adriatic Sea were subjected to a Port Baseline Survey (PBS), to estimate the natural spread of NIS organisms from their port of arrival to the wider Adriatic basin. Its findings indicate that the prevailing water circulation patterns facilitate the natural dispersal of harmful aquatic organisms and pathogens (HAOP).

Sources of organic matter in a polluted coastal embayment (Lake Sihwa) indicated that δ¹³C and δ¹⁵N of suspended particulate matter (SPM) and sediments could be distinguished by land-use type and surrounding activities. Specifically, low δ¹⁵N occurred in inland creeks near industrial complex, where severe contamination by persistent toxic substances (PTSs) is evidenced. To identify the sources of ¹⁵N-depleted organic matter and PTSs, the SPM and/or sediments were collected along ~8 km of the Singil Creek and in stormwater drainage pipes that carried pollutants to the creeks from upland areas. Results indicated that stormwater originating in industrial areas was the main source of low δ¹⁵N and elevated PTSs, which appeared to flow into stormwater drains with rainwater and eventually into the creeks at stormwater outfalls. To improve the water quality of inland creeks, it will be necessary to reduce the amount of untreated stormwater entering stormwater drainage system from industrial complex.

A molecularly imprinted polymer (MIP) anchored on the surface of CdTe quantum dots (QDs) was fabricated and used as a fluorescent probe for sulfadiazine (SDZ) detection in seawater. CdTe QDs was used as photoluminescent material, SDZ as the template, 3-aminopropyltriethoxysilane (APTES) as the functional monomer and tetraethyl orthosilicate (TEOS) as the cross-linking agent. Characterizations of MIP-QDs were analyzed by Fourier transform infrared (FT-IR), Transmission electron microscopy (TEM) and Scanning electron microscope (SEM). The conditions were optimized for the detection of MIP-QDs to SDZ. The mechanism of fluorescence quenching was studied by UV–Vis absorption spectroscopy and fluorescence spectroscopy. Under optimal conditions, the fluorescence intensity of MIP-QDs decreased linearly between 4‐ and 20 μM SDZ with a good correlation coefficient of 0.995. The limit of detection is 0.67 μM and the recovery is between 91.8 and 109.4% with RSD lower than 3.9%. These results indicated that MIP-QDs for SDZ detection in seawater was developed successfully.