Dissolved inorganic nitrogen (DIN) enrichment accompanied by silicate deficiency in seawater can promote dinoflagellate growth over diatom growth and induce further negative ecological consequences. Here, we propose an easily exercisable method for silicate fertilization as a remedy of eutrophication. In the laboratory, rice husk ash (RHA) released silicate and phosphate in an atomic ratio range of 38–113 without a significant influence on DIN. During incubations of silicate-limited waters, low-dose fertilization increased the diatom/dinoflagellate ratio by 1–5 times. With the high-dose fertilizer addition, DIN, with an initial concentration of 7.63 ± 0.95 μmol l⁻¹, was exhausted in three days, and the diatom abundance increased by 19 times on the 5th day. The silicate fertilization method presented here can be applied independently in eutrophicated waters for dinoflagellate suppression and dissolved nitrogen removal; this method could also work as a supplementary measure to existing nutrient (N, P) reduction and biomanipulation efforts.

Great Barrier Reef (GBR) catchment management has been constrained by knowledge gaps regarding streambank erosion processes in grazing lands. To help reduce these uncertainties a remote sensing study using high-resolution imagery estimated sediment contributions from cattle traffic on streambanks of a GBR river basin. Results suggest cattle ramps and ramp trails may contribute up to 50% of the modelled streambank sediment supply. Once a suitable delivery ratio is applied, this estimated supply may contribute up to 30% of the modelled fine sediment exported from the Fitzroy River Basin. These findings may also offer a plausible explanation for the first-flush of high sediment concentration observed early in flood hydrographs. Overall, the results could help identify what proportion of currently modelled subsoil erosion is generated by riparian cattle traffic. Future studies applying similar methods could provide useful initial estimates of streambank ramp erosion from grazing land use in other GBR river basins.

We investigated the distribution of microplastics in the water column along a large remote estuarine system located between the Northern and Southern Patagonian Ice Fields in Chilean Patagonia, and connected with the Pacific Ocean through the Gulf of Penas. Microplastic particles were found in all samples, with abundances ranging from 0.1 to 7 particles/m³. Polymers identified were principally acrylics, PET, and cellophane. The average abundance of microplastics in surface waters was similar along the whole estuary (0.4 ± 0.3 particles/m³) with acrylics and epoxy resins being more abundant near Caleta Tortel, the only small village in the area. The observed higher abundance of microplastics in the deeper waters towards the Gulf of Penas points to intrusions of subsurface waters transporting plastic particles from the ocean into the channel system. This underlines the potential of ocean currents in transporting plastic pollution into pristine fjords and channels in Chilean Patagonia.

Nitrogen mineralization is a critical biogeochemical process that transfers organic nitrogen into inorganic forms using heterotrophic microorganisms. However, few studies have focused on this potential nutrient supplier. In this study, the composition of sediment organic nitrogen (SON) was studied, and nitrogen mineralization flux entering the water column was quantified. The results indicate that acid-hydrolyzable nitrogen (AHN) accounts for more than 40% of the SON, especially in the riverine input and marine aquaculture areas, which had significantly higher concentrations than the bay mouth area. Similar results were found for the ammonium nitrogen (AN), amino-sugar nitrogen (ASN), the total hydrolyzable amino acid (THAA), and unidentified hydrolyzable nitrogen (HUN). The mineralization rate in the marine aquaculture area was as high as 9.03 ± 1.33 mg·kg⁻¹·d⁻¹, while those of the riverine input (4.77 ± 1.55 mg·kg⁻¹·d⁻¹) and bay mouth (5.12 ± 1.42 mg·kg⁻¹·d⁻¹) areas were lower. The SON fractions, including the AHN, AN, ASN, and AAN, could obviously affect the mineralization of the SON. However, the extracellular enzymes, including proteinase and urease, are the predominant factors controlling the SON mineralization process. Anthropogenic activities, including riverine input and marine aquaculture, exert significant influences on the fractions and mineralization of the SON, and thus, they may increase the amount of dissolved inorganic nitrogen in the bottom of the water column in Daya Bay.

Given a large quantity of epiphytes and other material attached on eelgrass leaf blades, we explored the relationship between eelgrass sheaths and different-aged leaf blades (1st, 2nd, 3rd, and 4th leaf blade) on nutrient content and their ratios (C, N, P, C/N, C/P, and N/P) to identify whether eelgrass sheaths could be used to instead of leaf blades in terms of nutrient content. In addition, we explored the relationship between eelgrass sheath length and shoot length. Results showed that there were significant relationships between the sheath and leaf blades in terms of N and P content and their ratios. For length analysis, there was a significant relationship between sheath length and shoot length, and shoot length was approximately four to five times (mean 4.4659) longer than sheath length, such that shoot length can be estimated by sheath length. These significant relationships suggest that eelgrass sheath could be used as a suitable predictor of leaf blade in length and nutrient stoichiometry, thus eelgrass sheath could be used as an indicator for further eelgrass nutrient monitoring and research.

Demersal trawls provide an index of seafloor macrolitter abundance, but there are no published data from sub-Saharan Africa. We collected litter items from 235 trawls conducted to assess fish abundance off South Africa. Only 17% of trawls contained litter (3.4 items·km⁻², 2.1 kg·km⁻² but only 0.2 kg·km⁻² excluding four megalitter items). Plastic items predominated (88%), of which 77% floated once cleaned of epibionts. One LDPE bag manufactured three months before being caught carried pelagic goose barnacles Lepas anserifera, confirming that biofouling leads to rapid sinking of floating plastics. Fishery/shipping wastes comprised 22% of litter items (98% by mass; 73% excluding megalitter items); the remainder was general waste – mostly packaging or other single-use items – that could come from land- or ship-based sources. Litter was more abundant in deep water close to Cape Town. The annual demersal trawl survey is a useful way to monitor seafloor litter off South Africa.

The concentrations of total mercury (THg) and methylmercury (MeHg) were assessed in water, sediment and biota (54 species) samples from the coast of Laizhou Bay, to evaluate MeHg biomagnification in Laizhou Bay food web. The trophic web structure was determined with stable isotope ratios. The MeHg concentrations were highly variable among species ranged from 4.8 ng g⁻¹ in primary producers to 411.2 ng g⁻¹ in spotted sea bass. Weight and ecotype were the principal parameters related to the mercury concentrations for most species. The trophic magnification factors (TMFs) for MeHg and THg were 2.09 and 1.69, respectively, indicating that mercury biomagnification is occurring in this marine food web. The estimated weekly intake (EWI) and target hazard quotient (THQ) values demonstrated that consuming predatory fishes from the bay could cause potential health risks to humans.

The southern Yellow Sea (SYS) is a significant repository of sedimentary organic matter (SOM) and has been impacted by green tides since 2007; however, data on the distribution and quantitative contributions of different SOM sources has been scarce. TOC, TN and their δ¹³C and δ¹⁵N values were determined in 38 surface sediments. TOC and TN were high in central mud area and low in sand area. TOC was positively correlated with the abundance of fine-grained sediments, indicating that controlling factors of SOM were the sediment types and circulation system. The SOM included marine and terrestrial organic matter and anthropogenic nutrient inputs according to TOC/TN (5.8–14.3), δ¹³C (−25.1‰ to −21.0‰) and δ¹⁵N (2.6‰–6.4‰). High terrestrial contributions in northern and western parts of SYS, were influenced by terrestrial materials and eroded substances of the abandoned Yellow River delta, respectively. In the central mud area of SYS, marine organic matter was dominant.

The microplastics removal and its effects on membrane fouling in membrane bioreactor (MBR) for treating polluted surface water in drinking purpose was investigated in this study. Typical microplastics polyvinylchloride (PVC) with concentration 10 particles/L was added in the feed water. MBR was effective in treating organic matters and ammonia with removal rate over 80% and 95%, respectively. The removal performance was immediately inhibited with the microplastics PVC added into the MBR system, and recovered after operated for few days. The membrane fouling and cleaning results indicated that microplastics contamination could led to higher membrane fouling, and also the irreversible membrane fouling. The main contributor of rejection is the membrane module and the adsorption onto bio-carrier. The microbial community of the system before and after PVC addition did not show obvious difference. MBR has the potential to be used as effective technology in treating microplastics contaminated polluted surface water.

The main environmental variables of bottom seawater and macrobenthic invertebrates were investigated from February 2015 to January 2016 to evaluate the benthic ecological status in adjacent areas of the Yangtze River Estuary, China. Diverse ecological assessment results were given by the AZTI Marine Biotic Index (AMBI), multivariate-AMBI (M-AMBI) and benthic opportunistic polychaetes amphipods (BOPA) index, showing that the M-AMBI was the most suitable in the study area. A clear spatial distribution pattern related to the distance from the estuary and the coasts was found both for the benthic ecological status and the eutrophication-related bottom seawater environmental variables, indicating that the study area was under eutrophication pressure. Two major disturbed regions (one was east of the Yangtze River Estuary, and the other was east of Zhejiang Province) were discovered, which was probably mainly caused by the Changjiang Diluted Water (CDW). No significant seasonal changes were found in the ecological status.