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Resultados 2021-2030 de 4,936
Quantitative evaluation of n-alkanes, PAHs, and petroleum biomarker accumulation in beach-stranded tar balls and coastal surface sediments in the Bushehr Province, Persian Gulf (Iran) Texto completo
2019
Dashtbozorg, Mehdi | Riyahi Bakhtiari, Alireza | Shushizadeh, Mohammad Reza | Taghavi, Lobat
Coastal areas within the Bushehr Province (BP), Persian Gulf, Iran, face great challenges due to the heavy organic contamination caused by rapid industrialization, and the presence of numerous oil fields. In addition, in 2014, a significant number of tar balls are found along the coasts of BP. A total of 96 samples (48 coastal sediments and 48 tar balls) were taken from eight sampling points at the BP coast during the summer of 2014. These samples were analyzed to identify the sources and characteristics of their organic matter using diagnostic ratios and fingerprint analysis based on the distribution of the source-specific biomarkers of n-alkanes, PAHs,¹1Polycyclic Aromatic Hydrocarbons hopanes and steranes. Mean concentration of n-alkanes (μg g⁻¹ dw) and PAHs (ng g⁻¹ dw) varied respectively from 405 to 220,626, and 267 to 23,568 in coastal sediments, while ranged respectively from 664 to 145,285 and 390 to 46,426 in tar balls. In addition, mean concentration of hopanes and steranes (ng g⁻¹ dw) were between 18.17 and 3349 and 184.66 to 1578 in coastal sediments, whereas in tar balls were 235–1899 and 520–1504, respectively. Pri/Phy²2Pristane/Phytane ratio was 0.25 to 1.51 (0.65) and 0.36 to 1 (0.63) in coastal sediment and tar ball samples, respectively, and the occurrence of UCM³3Unresolved Complex Mixture in both matrices, reflecting the petrogenic OM⁴4Organic Matter inputs and chronic oil contamination, respectively. The C₃₀ and C₂₉ homologues followed Gammacerane were detected in both matrices, in particular those collected from intensive industrial activities, suggesting petrogenic sources of OM. The coastal sediment PAHs profiles were significantly dominated by HMW⁵5Higher Molecular Weight-PAHs in the Bahregan Beach (BAB) (78% of total PAHs), Bandare-Genaveh (GP) (66%), and Bandare-Bushehr (BUB) (61%) stations, while the Bashi Beach (BSB) (40%), Bandare-Kangan (KP) (57%), and Bandare-Asaluyeh (AP) (51%) stations exhibited higher proportion of LMW⁶6Lower Molecular Weight-PAHs. PCA⁷7Principal Component Analysis indicated that the tar ball and coastal sediment samples deposited along the Southwest of the BP beaches are most likely originated from the Abuzar oil. Based on the intensity of the anthropogenic activities, NPMDS⁸8Non-Parametric Multi-Dimensional Scaling analysis revealed that the GP, BAB, NNP, AP, and KP sampling sites had a high concentration of detected organic pollutants. To the best of our knowledge, this is the first study that investigates oil pollution in costal sediments and tar balls in the BP, providing insights in to the fate of oil in the coastal areas of the Persian Gulf, Iran.
Mostrar más [+] Menos [-]Occurrence and identification of microplastics along a beach in the Biosphere Reserve of Lanzarote Texto completo
2019
Edo, Carlos | Tamayo-Belda, Miguel | Martínez-Campos, Sergio | Martín-Betancor, Keila | González-Pleiter, Miguel | Pulido-Reyes, Gerardo | García-Ruiz, Carmen | Zapata, Félix | Leganés, Francisco | Fernández-Piñas, Francisca | Rossal S., J. Roberto (Julio Roberto Rossal Salazar)
This work studied the accumulation of plastic debris in a remote beach located in La Graciosa island (Chinijo archipelago, Canary Islands). Microplastics were sampled in the 1–5 mm mesh opening range. An average plastic density of 36.3 g/m2 was obtained with a large variability along the 90 m of the beach (from 8.5 g/m2 to 103.4 g/m2). Microplastic particles preferentially accumulated in the part of the beach protected by rocks. A total number of 9149 plastic particles were collected, recorded and measured, 87% of which corresponded to fragments. Clear colours and microscopic evidence of weathering corresponded to aged plastics wind-driven by the surface Canary Current. The chemical composition of plastics particles corresponded to PE (63%), PP (32%) and PS (3%). Higher PE/PP ratios were recorded in the more protected parts of the beach, suggesting preferential accumulation of more aged fragments.
Mostrar más [+] Menos [-]Sea surface pCO2 in an urbanized coastal system (Jiaozhou Bay, China) during summer Texto completo
2019
Liu, Xiang-Yu | Yang, Xu-Feng | Li, Yun-Xiao | Zhang, Long-Jun
Various biogeochemical processes complicate carbon dioxide (CO₂) behaviour in coastal oceans. Through eight summer surveys, detailed variations in CO₂ mechanisms in the urbanized Jiaozhou Bay, China, were analysed. During the rainless period, respiration and dissolved inorganic carbon input from treated wastewater made the northeastern region a strong CO₂ source, while the western region with cleaner seawater was a weak source because calcium carbonate (CaCO₃) precipitation exceeded primary production. Rainfall events with different intensities and locations caused significantly different effects. When rainfall occurred over the sea, enhanced primary production caused a CO₂ sink; when rainfall induced little terrestrial pollutant input, CaCO₃ precipitation exceeded net primary production, leading to a CO₂ source. When heavy rain caused bulk runoff, the northeastern region was a strong CO₂ source because rivers flowing through downtown regions inputted considerable organic matter, while in the western region, runoff through suburbs and wetlands led to a strong sink.
Mostrar más [+] Menos [-]Fatty acids and elemental composition as biomarkers of Octopus vulgaris populations: Does origin matter? Texto completo
2019
Arechavala-Lopez, P. | Capó, X. | Oliver-Codorniú, M. | Sillero-Rios, J. | Busquets-Cortés, C. | Sanchez-Jerez, P. | Sureda, A.
Fatty acids and elemental composition as biomarkers of Octopus vulgaris populations: Does origin matter? Texto completo
2019
Arechavala-Lopez, P. | Capó, X. | Oliver-Codorniú, M. | Sillero-Rios, J. | Busquets-Cortés, C. | Sanchez-Jerez, P. | Sureda, A.
The present study describes the novel use of fatty acids (FAs) and element profiles of Octopus vulgaris inhabiting three coastal areas in the W-Mediterranean Sea. These populations are exposed to different anthropogenic activities, and were compared at different geographical scales. The FA composition in the mantle of O. vulgaris exhibited significant differences in 22:6 n−3 (DHA) and 22:5 n−3 (EPA) among the sampled populations. The essential microelements Fe, Cu, Zn and Ni, and the non-essential microelements As, Sr, Al and Cd were the main contributors of variability among sampled octopus populations, with some notable differences among tissues. The variations in the FAs and elemental composition in octopus tissues were detected with other populations throughout the species distribution range, which might reflect differences in natural habitats and foraging strategies. Therefore, these may be considered biomarkers as a proxy to distinguish the origin of octopus specimens at different scales.
Mostrar más [+] Menos [-]Fatty acids and elemental composition as biomarkers of Octopus vulgaris populations: Does origin matter? Texto completo
2019
Arechavala-Lopez, Pablo | Capó, Xavier | Oliver-Codorniú, Marc | Sillero-Rios, Joana | Busquets-Cortés, Carla | Sanchez-Jerez, Pablo | Sureda, Antoni | Universidad de Alicante. Departamento de Ciencias del Mar y Biología Aplicada | Biología Marina
The present study describes the novel use of fatty acids (FAs) and element profiles of Octopus vulgaris inhabiting three coastal areas in the W-Mediterranean Sea. These populations are exposed to different anthropogenic activities, and were compared at different geographical scales. The FA composition in the mantle of O. vulgaris exhibited significant differences in 22:6 n−3 (DHA) and 22:5 n−3 (EPA) among the sampled populations. The essential microelements Fe, Cu, Zn and Ni, and the non-essential microelements As, Sr, Al and Cd were the main contributors of variability among sampled octopus populations, with some notable differences among tissues. The variations in the FAs and elemental composition in octopus tissues were detected with other populations throughout the species distribution range, which might reflect differences in natural habitats and foraging strategies. Therefore, these may be considered biomarkers as a proxy to distinguish the origin of octopus specimens at different scales. | This work was partially funded by the Ministry of Economy, Industry and Competitiveness (ref. IJCI-2015-25595), by the Institute of Health Carlos III (Project CIBEROBN CB12/03/30038) and by Govern de les Illes Balears (AAEE001/2017). We would like to thank the “Conselleria de Medi Ambient, Agricultura i Pesca” of the “Govern de las Illes Balears” for supporting this project.
Mostrar más [+] Menos [-]Occurrence of polycyclic aromatic hydrocarbons (PAHs) in coral reef fish from the South China Sea Texto completo
2019
Li, Yali | Wang, Chenglong | Zou, Xinqing | Feng, Ziyue | Yao, Yulong | Wang, Teng | Zhang, Chuchu
Little data are available on the bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) in coral reef fish from the South China Sea (SCS). In this study, we collected 21 coral reef fish species from the Xisha and Nansha Islands in the SCS to investigate the occurrence of 16 US-EPA PAHs. The total PAH concentrations (ΣPAH) in the collected fish ranged from 12.79 to 409.28 ng/g dry weight (dw, Xisha Islands) and from 32.71 to 139.09 ng/g dw (Nansha Islands), respectively. The ΣPAH concentration of Scarus niger collected from the Xisha Islands (237.13 ng/g dw) was about twofold higher than that of Scarus niger collected from the Nansha Islands (139.09 ng/g dw). The dominant compounds were found to be 2-ring and 3-ring PAHs. Based on qualitative and quantitative analyses, the main PAH sources were found to be coal and biomass combustion (50.43%), petroleum sources (25.86%), and vehicular emissions (16.10%).
Mostrar más [+] Menos [-]Micro(nano)plastics: Unignorable vectors for organisms Texto completo
2019
Shen, Maocai | Zhu, Yuan | Zhang, Yaxin | Zeng, Guangming | Wen, Xiaofeng | I-Huan, | Ye, Shujing | Ren, Xiaoya | Song, Biao
Micro(nano)plastics, as emerging contaminants, have attracted worldwide attention. Nowadays, the environmental distribution, sources, and analysis methods and technologies of micro(nano)plastics have been well studied and recognized. Nevertheless, the role of micro(nano)plastic particles as vectors for attaching organisms is not fully understood. In this paper, the role of micro(nano)plastics as vectors, and their potential effects on the ecology are introduced. Micro(nano)plastics could 1) accelerate the diffusion of organisms in the environment, which may result in biological invasion; 2) increase the gene exchange between attached biofilm communities, causing the transfer of pathogenic and antibiotic resistance genes; 3) enhance the rate of energy, material and information flow in the environment. Accordingly, the role of microplastics as vectors for organisms should be further evaluated in the future research.
Mostrar más [+] Menos [-]Presence of plastic debris and retained fishing hooks in oceanic sharks Texto completo
2019
Mucientes, Gonzalo | Queiroz, Nuno
In a context where the problem of plastic pollution is globally increasing, more studies are needed to assess the real impact in oceanic megafauna. Here, we reported on the incidence of plastic and also retained hooks in two species of commercially exploited pelagic sharks in two ocean basins, the North Atlantic and South Pacific. In the South Pacific, 1.18% of caught blue sharks were observed with plastic debris on their body and 4.82% and with retained hooks, while 0.00% of shortfin makos had plastic debris and 1.76% were recorded with retained hooks. In the North Atlantic, 0.21% of blue sharks had plastic debris and 0.37% of blue, and 0.78% of shortfin makos were observed with retained hooks.
Mostrar más [+] Menos [-]Evaluation of bioconcentration and metabolism of diclofenac in mussels Mytilus trossulus - laboratory study Texto completo
2019
Świacka, Klaudia | Szaniawska, Anna | Caban, Magda
Interest in the presence of pharmaceutically active compounds in the aquatic environment has been growing for over 20 years, yet very few studies deal with the metabolism of pharmaceuticals in marine organisms. In this study, the bioaccumulation under short-term conditions and metabolism of diclofenac were investigated. Mytilus trossulus was used as a representative of the Baltic benthic fauna. The mussels were exposed to diclofenac at a concentration of 133.33 μg/L for five days, following a five-day depuration phase. The highest concentration of diclofenac (7.79 μg/g dw) in tissues was determined on day 3. Subsequently, the concentration of diclofenac in tissues decreased rapidly to 0.86 μg/g dw on day 5. After five days of depuration, the concentration of diclofenac was 0.21 μg/g dw. Hydroxylated diclofenac metabolites were found both in tissues of mussels and water. This study shows that M. trossulus has the potential to accumulate diclofenac and metabolize it to 4-OH and 5-OH diclofenac.
Mostrar más [+] Menos [-]Heavy metal concentrations in commercial marine organisms from Xiangshan Bay, China, and the potential health risks Texto completo
2019
Liu, Qiang | Xu, Xiaoqun | Zeng, Jiangning | Shi, Xiaolai | Liao, Yibo | Du, Ping | Tang, Yanbin | Huang, Wei | Chen, Quanzhen | Shou, Lu
Commercial marine organisms were collected from the coast of Xiangshan Bay to investigate the concentrations of eight heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) and evaluate the potential health risks. The results indicated considerable variations in the heavy metal concentrations among six species groups, of them mollusks (seasnail, benthic bivalve, and oyster) generally contained relative high levels of most metals, followed by crustaceans (crab and shrimp), by contrast, fish had low concentrations of all metals, except Hg. Three heavy metal groups were identified to interpret the accumulative characteristics in the marine organisms. Spatial distributions illustrated the geographical variations of heavy metal concentrations in the sampling areas. Moreover, maricultured organisms demonstrated lower heavy metal concentrations than did the wild. Health risks of most heavy metals exposed from marine organism consumption were safe, except for As which is associated with the high target cancer risk values.
Mostrar más [+] Menos [-]Distribution and origination of zinc contamination in newly reclaimed heterogeneous dredger fills: Field investigation and numerical simulation Texto completo
2019
Heavy metal elements, including Zn, Cd, As, Ni, Cu, Pb and Cr, were detected in soils (no deeper than 75 m) from newly reclaimed zones of Shanghai, China. The Zn concentration exceeded soil quality limits. The Zn contamination was tested in both dredger fills and sedimentary layers (①₃–₃, ②₃, ④ and ⑤₁–₁). However, it was not detected in layer ⑤₁–₂–⑨. PCA and HCA analysis show that exogenous Zn probably was the contaminant source of dredger fills before the fills were dredged from the neighboring waters. Stochastic heterogeneity of the dredger fills affects the Zn-depollution remarkably. Numerical simulations show both acid precipitation and widespread drainage channels in the zones contributed to Zn-decrease in the dredger fills no deeper than 1.2 m. Acid rainstorms work better than acid constant precipitation in Zn-remediation for layers below 0.4 m. To remove Zn contamination in deep dredger fills, un-consolidation of the fills should be utilized.
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