In this paper, the application of ultrafiltration (UF) technology to treat cadmium (Cd) pollution in surface waters is investigated. The effect of the UF membrane molecular weight cut-off (MWCO), Cd ion (Cd²⁺) concentration, solution pH and ionic strength on the removal, and mass balance of Cd were explored. In addition, the effect of the solution pH on UF membrane fouling was analyzed. The results indicated that UF membranes with a low MWCO resulted in an improved Cd removal rate. In addition, as the Cd²⁺ concentration in feedwater increased, the Cd removal rate decreased, while the Cd concentration in the permeate increased. Since the solution pH and ionic strength had a notable impact on the Cd removal rate, a high pH value and low ionic strength led to a higher removal rate of Cd. Under optimal Cd removal conditions, UF reduced the influent Cd concentration from 1.0 to 0.019 mg/L. For membrane fouling, increasing the solution pH led to more serious membrane fouling. This phenomenon was the result of Cd²⁺ reacting with OH⁻ and forming a Cd (OH)₂ precipitate. The precipitate and humic acid formed compact cakes on the membrane surface and blocked membrane pores. These results provided adequate evidence for the higher removal of Cd with increasing solution pH. In addition, SEM images under different pH conditions were in agreement with the conclusion mentioned above, which provided further support for the effect of the solution pH on Cd removal and membrane fouling.

This study investigated the soil pollution level and evaluated the phytoremediation potential of 25 native plant species on a former gold mine-tailing site in Ghana. Plant shoots and associated soil samples were collected from a tailing deposition site and analyzed for total element concentration of As, Hg, Pb, and Cu. Soil metal(loid) content, bioaccumulation factor (BAFₛₕₒₒₜₛ), and hyperaccumulator thresholds were also determined to assess the current soil pollution level and phytoextraction potential. The concentration of As and Hg in the soil was above international risk thresholds, while that of Pb and Cu were below those thresholds. None of the investigated plant species reached absolute hyperaccumulator standard concentrations. Bioavailability of sampled metal(loid)s in the soil was generally low due to high pH, organic matter, and clay content. However, for Cu, relatively high bioaccumulation values (BAFₛₕₒₒₜₛ > 1) were found for 12 plant species, indicating the potential for selective heavy-metal extraction via phytoremediation by those plants. The high levels of As at the study site constitute an environmental and health risk but there is the potential for phytoextraction of Cu (e.g., Aspilia africana) and reclamation by afforestation using Leucaena leucocephala and Senna siamea.

The objective of this article is to describe the effect of precipitation and temperature on the drought characteristics of Yunnan province in China. The rainfall and temperature data from 10 national meteorological stations in Yunnan province during 1969 to 2018 were used to investigate the spatial and temporal evolution of drought in Yunnan province and the difference of drought index based on Standardized Precipitation Index (SPI) and Standardized Precipitation Evapotranspiration Index (SPEI) at nearly 50a different time scales. The results showed that Yunnan province had a frequent alternation of drought and flood, and the larger the time scale, the gentler the SPI and SPEI changes. The recent 50a drought mainly occurred in 1980–1982, 1988–1990, 2003–2007, and 2010–2015, and there was continuous drought and the duration was prolonged. The changes of SPI and SPEI showed a downward trend in different seasons. The linear slopes of SPI and SPEI in spring, summer, autumn, and winter were − 0.0064, − 0.0088, − 0.0057 and − 0.0.0111, respectively, and the drought trend was the most serious in winter. Continuous spring drought occurred in 2009–2010 and 2012–2014. The SPEI values in 2009–2010 and 2012–2014 were − 0.80, − 0.64, − 0.75, − 1.23, and − 1.17, respectively. The spatial distribution of drought frequency in Yunnan province was greatly different, and its distribution rule was more in the north and east, less in the south and west. The drought frequency in Zhaotong (northeast Yunnan) was the highest at 36.53%, the drought frequency in Deqin and Lijiang (northwest Yunnan) were 33.11% and 33.28%, and the drought frequency in Kunming (central Yunnan) Lincang, Lancang, and Simao (southwest Yunnan) were 29.35%, 30.73%, 32.77%, and 28.35%, respectively. This study provided a scientific basis for revealing the spatial and temporal variation rules, evolution trends, regional drought, and drought impact assessment and risk management of drought in Yunnan province.

In this study, a new ecological dam based on the microbial fuel cell principle (MFCED) was designed to remove pollutants from river sediments and water bodies. Sediment organics were better removed in the MFCED mode in comparison with the other two modes (ecological dam with open circuit (OCED) and ecological dam filled with gravel in cathode chamber (GMFCED)). The difference of nitrogen source in water had little effect on the removal of chemical oxygen demand (COD) (70–80%), while nitrate was more readily removed in the MFCED. The voltage curve and power curve were measured to understand the bioelectricity generation of MFCED. During the stable operation phase of MFCED, the voltage was stabilized between 0.09–0.15 V. The results of high-throughput sequencing indicated that the anode and cathode diversities of MFCED were more than the other systems, and the species diversity of the anode was more than that of the cathode in the MFCED. Graphical abstract

The implementation of the extended producer responsibility (EPR) for e-waste is an important measure to develop an ecological civilization. In order to advance manufacturing enterprises to effectively implement resource and environmental responsibility, this study investigates the main causes of environmental regulation failure from the perspective of government and enterprises. The game theory was used to establish an evolutionary game model between government regulatory departments and electronic and electrical products’ manufacturing enterprises. A system dynamic model was utilized to construct the stock-flow graph of the game between government and enterprises, and to carry out simulation analysis under different strategies. The results found that the probability of an enterprise undertaking extended responsibility gradually increased and stabilized with the increase of government supervision and punishment intensity; the government’s regulatory probability and punishment are important factors affecting the enterprises’ compliance with regulations and responsibilities. The study suggests that government should focus on strengthening environmental regulations from the aspects of improving laws and regulations, establishing a regular monitoring system and innovating incentive and constraint mechanism.

Li₂CuO₂ and different iron-containing Li₂CuO₂ samples were synthesized by solid state reaction. On iron-containing samples, atomic sites of copper are substituted by iron ions in the lattice (XRD and Rietveld analyses). Iron addition induces copper release from Li₂CuO₂, which produce cationic vacancies and CuO, due to copper (Cu²⁺) and iron (Fe³⁺) valence differences. Two different physicochemical conditions were used for analyzing CO₂ capture on these samples; (i) high temperature and (ii) low temperature in presence of water vapor. At high temperatures, iron addition increased CO₂ chemisorption, due to structural and chemical variations on Li₂CuO₂. Kinetic analysis performed by first order reaction and Eyring models evidenced that iron addition on Li₂CuO₂ induced a faster CO₂ chemisorption but a higher thermal dependence. Conversely, CO₂ chemisorption at low temperature in water vapor presence practically did not vary by iron addition, although hydration and hydroxylation processes were enhanced. Moreover, under these physicochemical conditions the whole sorption process became slower on iron-containing samples, due to metal oxides presence.

Usage of atrazine, a widely used herbicide, is now banned in many countries. Although forbidden to use, significant concentration of this herbicide is still present in the environment. The study focused not only on the toxicity of atrazine itself but also on products of homogeneous photocatalytic degradation. Such degradation was very fast in given conditions (sufficient amount of Fe(III) in the reaction system)—more than 95% of the initial amount of atrazine was eliminated after 30 min of irradiation. The toxicity of atrazine and its photodegradation products were examined on the aquatic plant Lemna minor and microcrustacean Daphnia magna in both acute and chronic tests. While the growth inhibition assay of atrazine for Lemna minor revealed EC₅₀ value of 128.4 μg dm⁻³, the herbicide did not affect Daphnia in the acute toxicity assay. A degradation product, desethyl-atrazine, has been demonstrated to have a pronounced negative effect on the plant growth. Both atrazine and desethyl-atrazine affect negatively the number of juveniles and number of clutches of Daphnia magna in the chronic toxicity assay. Photocatalytic degradation lowers the negative effect of atrazine in Daphnia magna while photodegradation products still negatively affect Lemna growth.

The endophytic bacteria live in close nuptial relationship with the host plant. The stress experienced by the plant is expected to be transferred to the endophytes. Thus, plants thriving at polluted sites are likely to harbor pollutant-degrading endophytes. The present study reports the isolation of phenylurea herbicides assimilating Bacillus sps. from Parthenium weed growing at diuron-contaminated site. The isolated endophytes exhibited plant growth–promoting (PGP) activities. Among five isolated diuron-degrading endophytes, the most efficient isolate Bacillus licheniformis strain SDS12 degraded 85.60 ± 1.36% of 50 ppm diuron to benign form via formation of degradation intermediate 3, 4-dichloroaniline (3,4-DCA). Cell-free supernatant (CFS) obtained after diuron degradation by strain SDS12 supported algal growth comparable with the pond water. The chlorophyll content and photosynthetic efficiency of green algae decreased significantly in the presence of diuron-contaminated water; however, no such change was observed in CFS of strain SDS12, thus, suggesting that strain SDS12 can be applied in aquatic bodies for degrading diuron and reducing diuron toxicity for primary producers. Further, the use of PGP and diuron-degrading bacteria in agriculture fields will not only help in remediating the soil but also support plant growth.

Improving digestibility, fermentation characteristics, and reducing greenhouse biogases to protect the environment without the use of synthetic materials is an important goal of modern-day farming and nutritionist. Plant extracts are capable of solving these. This is due to the digestive enzymes and the bioactive components capable of performing antimicrobial functions inherent in these plants. This study was aimed to investigate the effect of standard maize substrate treated with selected herbs and spices extracts on ruminal environmental biogas production and pressure during fermentation via biogas production technique. Herbs (Azadirachta indica leaves (T1), Moringa oleifera leaves (T2), Ocimum gratissimum leaves (T3) and spices (Allium sativum bulb (T4), Zingiber officinale rhizome (T5)) were harvested, air dried, and milled using standard procedures. Methanolic extracts of the herbs and spices were prepared and used as additives at different concentrations (50, 100, and 150 μL) to the maize substrate for in vitro biogas production. Data were analyzed using regression analysis. There were significant (P < 0.05) differences across all the treatments on the volume and pressure of biogas. The pressure and volume of biogas when compared with the levels tested showed differences (P < 0.05) across all the treatments for the prediction of volume from pressure of biogas. The pressure and volume of gas produced in vitro increased (P < 0.05) and biogases decreased (P < 0.05) by the substrate treated with herbs and spices but for the drum stick leaves which was similar for the levels of concentration tested. This means that the level tested had a pronounced mitigation effect on pressure of biogas and volume of biogas produced. It was concluded that the herb and spice extracts have the potential to improve rumen fermentation and reduce the production of biogases in ruminant diet.

Robust and simple composite films for the removal of methyl orange (MO) and Cr(VI) have been prepared by combining chitosan, saponin, and bentonite at a specific ratio. There are several composite films (chitosan-saponin-bentonite (CSB)) prepared; among them, the composite films CSB₂:₃ and CSB₁:₁ have the highest removal efficiency toward MO and Cr(VI) where the maximum removal is 70.4% (pH 4.80) and 92.3% (pH 5.30), respectively. It was found that different types of adsorbate have different thermodynamic properties of the adsorption process; the adsorption of MO onto CSB₂:₃, chitosan, and acid-activated bentonite (AAB) proceeded endothermically, while the adsorption of Cr(VI) onto CSB₁:₁, chitosan, and AAB proceeded exothermically. The parameters of the adsorption were modeled by using isotherm and kinetic equations. The models of Langmuir, Freundlich, Redlich-Peterson, Sips, and Toth were used for fitting the adsorption isotherm data at a temperature of 30, 45, and 60 °C; all of the isotherm models could represent the data well. The result indicates that CSB₂:₃ has the highest adsorption capacity toward MO with qₘ of 360.90 mg g⁻¹ at 60 °C; meanwhile, CSB₁:₁ has the highest adsorption capacity toward Cr(VI) with qₘ 641.99 mg g⁻¹ at 30 °C. The pseudo-second-order model could represent the adsorption kinetics data better than the pseudo-first-order equation. The adsorption mechanism was proposed, and the thermodynamic properties of the adsorption were also studied.