The present study prepares alkali lignin (AL) via acidification of black liquor, obtained from a pulp and paper factory. The average molecular weight of AL (equal to 2,530 g/mol) has been determined with gel permeation chromatography. AL has been modified by ethylene glycol, while lignin nanoparticles (LN) has been prepared through acid precipitation technology, their size being assessed by means of DLS to show that the average diameter of the nanoparticles at pH = 4 has been 52.7 nm. Afterwards, it has used AL and LN to remove Basic Red 2 (BR2) from aqueous solutions. The absorbent structures and morphologies of AL and LN have been investigated using SEM, and FT-IR spectroscopy. The optimal conditions for the absorption of AL and LN, using 0.1 gr of the absorbent, include 100 min of duration, at pH of 7, and an initial dye concentration amounting to 100 mg/L. Furthermore, the absorption amount has been mathematically described as a function of experimental parameters, modeled by means of Response Surface Methodology (RSM). A central composite design (CCD) has been applied to evaluate the impacts of four independent variables. Optimum absorption values, obtained via empirical methods, completely match with the values, calculated by the program called Design-Expert. Both absorbent AL and LN show agree with Langmuir Isotherm with maximum absorption capacities of AL and LN being 55.2 mg/gr and 81.9 mg/gr, respectively. The experimental results show that both absorbent LN and AL follow both pseudo-second kinetic and the intraparticle diffusion models.

The present study investigates groundwater quality in terms of heavy metals level and microbial contamination as well as the impact of bleaching powder on microbial load of groundwater samples in close proximity to a surface water body inside selected areas of Ibadan Nigeria. To do so, it collects nine water samples from three boreholes and six hand-dug wells from six locations, namely Eleyele, Wofun-Olodo, Oluyole Industrial Estate, Ogunpa, Olorunsogo, and Ojoo, keeping them in 750 mL plastic bottles. The samples are then divided by two, giving a total amount of 18 samples, with 3 and 6 duplicates apiece being treated with bleaching powder and the rest remaining untreated. Both sample sets have been analysed for water quality parameters such as pH, biochemical oxygen demand, and chemical oxygen demand, assessed using standard methods. The coliform count has been determined, using the pour plate method while heavy metal has been set by means of Atomic Absorption Spectrophotometer (AAS) after nitric acid digestion. Results show that the pH ranges within 6.0-6.5, BOD within 1.67-4.33mg of O2/L, and COD  within 2.93-9.43, while heavy metal concentration is from 0.013 to 0.047 mg/L for lead, ND to 0.023 mg/L for chromium, and ND to 0.010 for cadmium. What is more, the coliform count in the samples is between 0.00 and 913.33 CFU/mL. Most of the samples exceed the WHO limits for heavy metals in drinking water, having significant levels of microbial contamination. Bleaching powder treatment alleviated the level of pollution to varying degrees; therefore, constant monitoring of groundwater source and treatment before drinking is of utmost importance.

The present study evaluates health risk assessment for inhabitants who are exposed to chromium in fishes and vegetables of the Gulshan Lake. In the fish, chromium concentration has amounted to 2.2 to 149.7 mg/kg, while in vegetables leaf and vegetables stem it has been 5.6 mg/kg and 12.0 mg/kg, respectively. What is more, in sediment it has been 179.5 to 308 mg/kg and in water, 4.0 to 16.9 mg/l. Higher accumulation of chromium (149.7 mg/kg) has been found in a fish species, relatively most affordable for poor people, called Pangas (Pangasius pangasius). Therefore, due to consumption of this fish the resultant non-cancer health hazard indices to people, living nearby Gulshan Lake has been almost 10 times greater than those induced by safe average daily dosages of the respective chemical. Vegetable pathway is still safe in terms of non-carcinogenic health hazard but may be very likely to act as an additive. It is therefore important to immediately take some remedial measures to not only reclaim Gulshan Lake but prevent any further pollution also.

Water and sediment samples have been collected from five different stations, located along Djendjen River between February and June, 2016 so that the concentrations of Cd, Ni, Zn, and Cu could be determined. The extent of the sediment pollution has been assessed, using the multiple pollution indices, namely Contamination Factor (CF), Pollution Load Index (PLI), and the geoaccumulation index (Igeo).The distribution of trace elements in water and sediment follows Ni>Zn>Cd>Cu and Zn>Ni>Cu>Cd, respectively. The water sample analysis from Djendjen River shows that the total concentrations of Cu, Ni, Cd, and Zn have been lower according to the references. In comparison, sediment mean metal concentrations with several environmental contamination parameters, like probable effect level (PEC) and background levels, indicates that the concentrations of all investigated elements are lesser than PEC, except for Ni, but higher than the background levels. The Igeo values reveal that Cd has been the most accumulated compared to the other metals.  Contamination Factor (CF) confirms that the sediment samples have been moderate in terms of all studied metals contamination. The Pollution Load Index (PLI) values have been above one (>1), indicating an advanced decline of the sediment quality.

The plants, grown in the soils around a Fuel Holding Depot of the Nigerian National Petroleum Corporation, Ibadan, Oyo state, Nigeria have been investigated in this research in terms of their density and species composition so that the impact of contamination by petroleum products on soil seed banks could be determined. The study has used designated plots (25m by 25m) in a site, contaminated by petroleum products, as well as a non-contaminated site. In each plot, replicate soil samples have been collected randomly at 0-5 cm, 5-10 cm, and 10-15 cm, with the soil samples being subjected to emergence of seedling test for three months in order to determine the species composition, species density, and seed viability at different soil depths. Results show that 17 species from 14 families with a total seedling density of 975 seedlings (19,073 seeds/m2) have been encountered in the seed bank of the non-contaminated soil, whereas just one species with 339 seedlings (6,632 seeds/m2) has been recorded in the contaminated soil. Herbaceous species notably, Spermacoce ocymoides, Spermacoce verticillata, and Peperomia pellucida dominate the seed bank of the non-contaminated soil, whereas Eleusine indica is the sole species, encountered in the seed bank of the contaminated soil. There is a general reduction in seed viability as the soil depth is increased. In conclusion, contamination by petroleum products narrow the species composition and density of soil seed bank, though has no effect on seed viability, irrespective of soil depth. Eleusine indica, being the only species encountered in the contaminated soil, may be tolerant to petroleum hydrocarbon, thus portending useful potentials for phytoremediation.

The study evaluates associated health risks of heavy metals in the soil to inhabitants of two mining areas of Nigeria. For so doing, it collects and analyses nine homogenous soil samples for their lead, copper, cadmium, zinc, and chromium levels, using AAS. The samples are then used to calculate health risks to adults and children. For adult population in Agbaja community, the calculated hazard quotients fall below one in all considered pathways. Hazard index values for all the pathways are also less than one, taking the following order: Cu>Cr>Pb>Cd>Zn. It is shown that for all considered heavy metals, the adult population in Agbaja mining community was not at any risk of non-carcinogenic effects from these metals. As for the children in Agbaja, the calculated HQ values for Cd and Zn have been less than one in all the pathways, while the HQ values for Pb, Cr, and Cu have significantly surpassed 1, with the ingestion route being the main pathway. The HI values have been in the following order: Cu>Cr>Pb>Cd>Zn, which poses serious non-carcinogenic health risks to the children, living around this community. The carcinogenic risk has been calculated based on Pb, Cd, and Cr, with the former (Pb) proven to be the highest contributor to cancer risk. USEPA considers acceptable cancer risk within the range of 1×10−6 to 1×10−4. Though insignificant in its values, carcinogenic risk for adults in Agbaja (2.95×10-4) and Itakpe (4.71×10-4) and for children in Itakpe (4.47×10-4) have been higher than the acceptable values. Hence, the adults are more at risk, for whom ingestion is the main contributor to excess lifetime cancer risk, followed by dermal pathways. Considering the health hazards, entailed by the accumulation of these heavy metals, on human health, mining sites and areas require to get monitored properly.

A greenhouse experiment has been planned for this study to delineate the benefits of two types of rice husk biochars (namely B300 and B600 which are prepared at 300°C and 600°C, respectvely) and coal fly ash (CFA), as soil amendments, for decreasing the amount of some heavy metals (like Pb, Cd, Ni, Cr, and Cu) as well as mobility and phytoavailability in an artificially-calcareous multi-element-contaminated soil. The effect of soil amendment on heavy metals’ availability has been evaluated via sequential extraction experiment and phytoavailability of the plant. According to the results, among the studied amendments, B600 has had the highest positive effect on both dry matter yield in corn and heavy metals’ availability reduction in post-harvest soil samples (with the exception of Cr), compared to CFA and B300, due to the increasing specific surface area, CEC, and pH that promote heavy metals’ sorption in the soil through surface complexation and ion exchange mechanisms. Evaluation of heavy metals’ chemical forms in post-harvest soil samples indicates that addition of amendments has significantly decreased mobility factor of heavy metals (with the exception of Cr in CFA-amended soils). In general, application of three soil amendments to this polluted soil has considerable effect on the reduction of heavy metals’ availability and phytoavailability. However, among the studied amendments, B600 and CFA have had the maximum and minimum effect on heavy metals’ availability reduction, respectively.

Carbon dioxide (CO2) is the foremost gas, emanated from human activities, and the best-known greenhouse gas, contributing to global warming, thus its negative effect on human health cannot be disregarded. The current paper investigates the relation between environmental quality variables, socio-economic factors, and human health from 1960 to 2014 in China, using Auto Regressive Distribution Lag (ARDL) Model. It selects three main environmental quality indicators (carbon emissions from coal, natural gas, and petrol) along with two representative socio-economic factors variables (per capita income and urban population) to explain the interaction mechanism. The results validate the long-term negative equilibrium impact of carbon emissions from the consumption of natural gas, coal, and petroleum on human health. The findings also reveal that migration from the countryside to cities and increase in per capita income improve quality of health. It is suggested that lowering emission of Carbon dioxide (CO2), which is the principal cause of greenhouse gas emissions, should be important in setting up the high quality of life for citizens.

The present study investigates the influence of an organophosphorus pesticide, namely Dimethoate, and cadmium on biomarkers of the green alga, Spirogyra sp., in a 14-day experiment. For so doing, it has exposed Spirogyra sp. to 0.0, 100, 200, and 400 mg L-1 of Dimethoate and/or 1 mg L-1 of cadmium chloride (CdCl2) to observe a reduction in chlorophyll a and b level in Spirogyra sp., exposed to 200 and 400 mg L-1 of Dimethoate as well as algae treated with cadmium alone or in combination with Dimethoate. Levels of malondialdehyde (MDA) and total antioxidant in cells, as well as the activity of ascorbate peroxidase (APX) soar in Spirogyra sp., exposed to Dimethoate and/or cadmium (alone or simultaneously). Also Spirogyra’sexposure to cadmium and/or Dimethoate significantly increases catalase (CAT) activity. However, levels of carotenoids in Spirogyra sp., treated with both cadmium and Dimethoate, decline significantly, with no significant change found in catalase activity of Spirogyra sp., exposed to 100 and 200 mg L-1 of Dimethoate, in comparison to the control group. However, CAT activity rises significantly in Spirogyra sp., treated with 400 mg L-1 of Dimethoate. Cadmium can cause cytotoxicity in 1 mg L-1 concentration of the green algae(Spirogyra sp.). On the whole, investigating the biological and biochemical markers in Spirogyra sp., exposed to different concentrations of Dimethoate, has revealed some concentration-dependent toxicity. Furthermore, Dimethoate can synergistically increase toxicity and bioavailability of cadmium in Spirogyra sp.

The present study synthesizes Zn-TiO2 photocatalyst via a simple and economic green rout, in which Green Tea is applied as a green reducing agent due to the presence of polyphenols Molecules. Polyphenol molecules in green tea act as a reductant, thus changing Zn2+ to metallic Zn. The by-produced nanocmposites are characterized by using XRD, FESEM, EDS, and DRS. Zn-TiO2 photocatalyst possesses great efficient charge separation properties. In order to investigate the presence of Zn, different weight ratio of Zn to TiO2 (viz. 5 wt%, 10 wt%, 15 wt%, 20 wt%, 25 wt%, 30 wt%, 35 wt%, 40 wt%, 45 wt%, and 50 wt%) have been synthesized and their performance in Acid Orange 7 (AO7) photodegradation, compared with pure TiO2. According to the results, the compound with 25 wt% Zn shows 97% degradation of AO7 as a model pollutant. Also, it has been shown that after three tests with EDTA, benzoic acid, and under Ar gas, photodegradation of AO7 with Zn-TiO2 photocatalyst mainly depends on photogenerated holes.