Oxygen-releasing compounds (ORCs) have recently gained much attention in contaminated groundwater remediation. We investigated the impact of calcium peroxide nanoparticles on the groundwater indigenous bacteria in a bioremediation process by permeable reactive barrier (PRB). Three sand-packed columns were applied, including (1) control column (fresh groundwater), (2) natural remediation column (contaminated groundwater), and (3) biostimulation column (contaminated groundwater amended with CaO₂). Actinobacteria and Proteobacteria constituted the main phyla among the identified isolates. According to the results of next-generation sequencing, Proteobacteria was the dominant phylum (81% relative abundance) in the natural remediation condition. But, it was declined to 38.1% in the biostimulation column. Meanwhile, the abundance of Actinobacteria and Bacteroidetes were increased to 25.9% and 15.4%, respectively, by exposing the groundwater microbial structure to CaO₂ nanoparticles. Furthermore, orders Chlamydiales, Nitrospirales, and Oceanospirillales existing in the control column were detected in the presence of naphthalene. Shannon index was 4.32 for the control column samples, while it was reduced to 2.73 and 2.00 in the natural and biostimulation columns, respectively. Therefore, the present study provides a considerable insight into the impact of ORCs on the groundwater microbial community during the bioremediation process.

The evaluation of the toxicological effects of titanium dioxide nanoparticles (TiO₂NPs) is increasingly important due to their growing occupational and industrial use. Curcumin is a yellow curry spice with a long history of use in herbal medicine and has numerous protective potentials such as antioxidant, antimicrobial, anti-inflammatory, and anti-apoptotic effects. Accordingly, we tested the hypothesis that curcumin could ameliorate TiO₂NP-induced cardiotoxic and genotoxic effects in adult male albino rats. For this purpose, 48 adult male albino rats were randomized into five groups; all treatment was by oral gavage once daily for 90 days: group I (8 rats), untreated control; group II (16 rats), subdivided into vehicle control IIa (8 rats) received saline and vehicle control IIb (8 rats) received corn oil; group III (8 rats) orally gavaged with curcumin dissolved in 0.5 ml corn oil at a dose of 200 mg/kg b.w./day; group IV treated with TiO₂NPs at a dose of 1200 mg/kg b.w./day (1/10 LD₅₀) suspended in 1 ml of 0.9% saline; group V treated with curcumin + TiO₂NPs (the same previously mentioned doses). Curcumin was orally gavaged for 7 days before TiO₂NPs treatment was initiated, and then they received TiO₂NPs along with curcumin at the same doses for 90 days. TiO₂NPs administration resulted in several myocardial cytomorphic changes as structurally disorganized, degenerated, and apoptotic cardiomyocytes and the newly implemented 3-nitrotyrosine immune expression rendered strong evidence that these effects derived from the cardio myocellular oxidative burden. Furthermore, comet assay results confirmed TiO₂NP-related DNA damage. Remarkably, all these changes are partially mitigated in rats treated with both curcumin and TiO₂NPs. Our results suggest that concurrent curcumin treatment has a beneficial role in ameliorating TiO₂NP-induced cardiotoxicity and this may be mediated by its antioxidative property.

The article Temporal trends of contaminants in Arctic human populations, written by Khaled Abass, Anastasia Emelyanova and Arja Rautio, was originally published electronically on the publisher’s internet portal (currently SpringerLink) on 25 August 2018 without open access.

Road transport is the main source of pollution to the environment in urban areas; therefore, there is a need to accurately estimate the amount of exhaust gases emitted by motor vehicles. The development of systems for measuring emissions of exhaust gases caused the exit from stationary chassis dynamometers to real road test. This paper presents an analysis of emission data from the PEMS system for real driving cycles of various types of vehicles, complying with EURO2-EURO6 standards, fueled with petrol, LPG, and diesel in urban, rural, and motorway areas as well as detailing roundabouts. The results show that in the range of roundabouts, there is an increased emission of harmful exhaust components, such as CO₂, THC, CO, and NOx. Due to the specific traffic conditions that prevail at the roundabout (acceleration, braking, acceleration to a certain speed), the methodology for creating an exhaust emission model for this type of objects has been proposed. Statistical analysis of the received boosted regression tree models based on the coefficient of regression, root mean square error, and mean absolute error and based on the visual assessment of the results show that the obtained models are well represented by real data. The obtained results of emission calculations on roundabouts may be used to identify areas of increased emission of harmful exhaust components, as well as an introduction to prepare new roundabout design guidelines concerning emission data.

A gradual increase in the importance of water environment infrastructure has provided an opportunity to bring in various initiatives for the supply of sewage. Such initiatives include the dissemination of public sewage systems and the use of subcontractors in management of sewage systems. However, despite the existence of various methods to increase the rate of sewage supply, there are few studies analyzing each alternative in terms of social, economic, and environmental aspects. Therefore, we investigated investment directions for water environment infrastructure facilities related to the supply of sewage treatment systems in rural areas through cost-benefit analysis. We analyzed the economic costs and social benefits of two sewage treatment systems: installation of a public sewage treatment system and utilization of a private sewage treatment system via service contract. When we considered only economic costs and benefits, the benefit-cost ratio for the public system (0.02) was smaller than that for the private system (0.264). However, the results of the two alternatives changed when we considered the social benefits to people in urban areas from establishment of public sewage treatment systems in rural areas. To be specific, by considering the social benefits for non-rural areas, this study found that the benefit-cost ratio for the public system increased to 0.267, which was higher than the ratio for the private system. Based on these results, we propose appropriate operations and management plans for supplying sewage treatment systems to rural areas. Further, this study indicates that policymakers who conduct cost-benefit analyses of infrastructure related to water environments should consider all social, environmental, and economic factors that can alter the analysis results.

Air pollution and dust storms are associated with increased cardiovascular hospital admissions. The aim of this study was to investigate the association between short-term exposure to ambient air pollutants and CVD (cardiovascular disease) events in a long-term observational period. The study included the events of cardiovascular diseases (namely coronary artery disease, ischemic heart disease, myocardial infarction, and pneumo thrombo embolism) within the population of Shiraz, from March 21, 2009 to March 20, 2015. Also, each patient’s demographics were recorded. Main meteorological variables and five ambient pollutants (CO, O₃, SO₂, NO₂, and PM₁₀) were recorded. Statistical analysis was performed using linear regression (GLM) and a generalized additive model (GAM) estimating Poisson distribution and adjusted for the main risk factors and ambient meteorological variables. A mild prevalence (51.5%) of coronary artery disease (CAD) was registered in 6425 events. In GLM analysis, we observed an association among the pollutants with the coronary artery disease hospital admissions which was in the order of CO, NO₂, and PM₁₀. The highest association of each pollutant with hospital admission was observed as PM₁₀ at lag 4 (RR = 1.08; 95% CI 1.02, 1.14 and p < 0.05), NO₂ at lag 0 (RR = 1.22; 95% CI 1.00, 1.48), and CO at lag 0 (RR = 1.52 95% CI = (1.16, 1.99)). However, on dusty days, there were significantly higher numbers of referrals of cardiovascular patients (mean = 7.54 ± 4.44 and p = 0.002,) than on non-dusty days. According to these data, dust storms and some types of pollutants in the air are responsible for more admissions to hospitals for cardiovascular problems.

The soil permeability and underground water level greatly affect the performance of low-impact development (LID) practices. Shanghai is located in the area of estuary and is characterized by its high groundwater level and low soil infiltration rate. The LID practices in Fuxing Island Park, Shanghai, including a bioretention cell, swales, a permeable pavement, and a combined LID practices were studied in the present paper. The performance of LID practices during the period of eight rainfall events was evaluated in terms of hydrology and water quality. Due to the detention of the LID practices, a significant delay between the peak rainfall and the peak surface runoff was observed. On-site tests show it is suitable for the applicability of LID in a rainy city with low soil infiltration rate and high groundwater level. Moreover, the Stormwater Management Model (SWMM) was also used to compare the hydrologic effects before and after these four LID practices application in the park. Results indicated the LID practices could effectively reduce the runoff volume and the peak flow in the park. Furthermore, the runoff water quality evaluation showed the pollutants were effectively removed by these four LID practices due to both runoff treatment and flow volume reduction. The bioretention system proved to be effective as a result of its larger facility area while the swales had the obvious reduction volume both per facility area and per catchment area.

Mercury (Hg) is a complex and multifaceted global pollutant. Artisanal and small-scale gold mining activities are largely responsible for Hg contamination in developing countries, in many cases impacting areas of high biodiversity such as the Amazon. The aim of the study was to establish Hg exposure in indigenous citizens from the Tarapaca village, Cotuhe and Putumayo Rivers, at the Colombian Amazon. Total Hg (T-Hg) concentrations were measured employing a DMA-80 Hg analyzer. For that purpose, 190 hair samples were taken from volunteers living in different communities of Tarapaca. The overall mean T-Hg level for all samples was 10.6 ± 0.4 μg/g, with values ranging from 0.61 to 31.1 μg/g. The mean T-Hg level decreased in the order Puerto Huila > Puerto Ticuna > Ventura > Nueva Union > Buenos Aires > Santa Lucia > Puerto Nuevo > Caña Brava > Pupuña. Based on recommendations from the United States Environmental Protection Agency (US EPA), 99.5% of the samples exceeded the maximum level of 1.0 μg/g. Hg content in human hair was significantly associated with fish consumption (ρ = 0.253; p < 0.001). According to the health survey, at least 24.7% of the volunteers manifested some signs and symptoms of Hg poisoning. In short, these data support the extensive Hg exposure in the environment of the Colombian Amazon, a process that could be impacting the quality of life of its vulnerable indigenous groups. Immediate actions must be taken by competent authorities to protect these communities from Hg poisoning.

The aim of this study was to determine the photocatalytic performance of copper-doped TiO₂ (Cu-TiO₂) specimens on the degradation of dissolved organic matter (DOM) represented by a model humic acid (HA). TiO₂ was synthesized by sol-gel method from an alkoxide precursor. Cu-doped TiO₂ specimens containing 0.25 wt% and 0.50 wt% Cu were prepared by wet impregnation method using sol-gel synthesized as well as bare TiO₂ P-25 and characterized by XRD, SEM, XPS, Raman spectroscopy, UV-DRS, and BET measurements. Their photocatalytic activities were evaluated with regard to degradation kinetics of HA in terms of UV-vis and fluorescence spectroscopic parameters and organic contents. HA fluorescence excitation emission matrix (EEM) contour plots indicated that the solar photocatalytic degradation pathway was TiO₂-type specific and Cu dopant content.

The original corresponding authorship was transferred from Changwon Kim to Yejin Kim by Changwon Kim’s request. All the authors agreed to that.