Flocculation is one of the commonly used sludge conditioning methods in water supply plants, which can improve the sludge dewatering performance by reducing the specific resistance of sludge (SRF), decreasing the amount of sludge, and finally lowering the transportation cost and subsequent disposal cost of sludge. Therefore, it is particularly important to develop new and efficient flocculants. In this paper, the template copolymer of acryloxy trimethylammonium chloride (DAC) and acrylamide (AM) was successfully synthesized by microwave-template copolymerization (MV-TP) using sodium polyacrylate (NaPAA) as template. The template copolymer was analyzed by infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), nuclear magnetic resonance hydrogen spectroscopy (¹H NMR), and scanning electron microscopy (SEM). It was found that this template copolymer had obvious cationic microblock structure. In addition, the test results of association constant (KM) and polymerization kinetics showed that the MW-TP was assigned to free radical initiated polymerization and the polymerization mechanism was I Zip-up (ZIP). It confirmed the formation of cation fragment structure again. Due to its dense positive charges in this new cationic microblock structure, it greatly improved the functions of electric neutralization, electrical patching, and adsorption bridging. The cationic fragment structure in the template copolymer could help to generate large and dense floc structure and form stable drainage channels. Under external pressure, these large and compact floc structures had greater compressive resistance, which avoided deformation and blockage of drainage channels and voids. It was beneficial to reduce SRF and evidently enhanced sludge dewatering performance.

The correct destination of waste is an essential factor for sustainable development. Electronic waste, which is very toxic, is the type of waste with the highest rate of increase in its generation. For these reasons, the amount of research on this topic increases year by year, as shown by the literature review carried out by this study. This review aims to identify the main characteristics and proposals of the main study on electronic waste and verify how Brazil is inserted globally in the research on e-waste. Another objective is to suggest a path for researchers who want to start research on e-waste by identifying the keywords most used in the analyzed articles. The results evidenced that the most published countries on the subject are China, the USA, and India. Brazil is in a position of little prominence concerning its research production on the subject. Most of the central studies we analyzed use case study and literature review as the research method. Among the 44 articles analyzed, only one proposed a destination for e-waste. It highlights the need for more research focusing on the environmentally correct destination of e-waste. A good way to start a search on electronic waste is to use the keywords identified in this study, especially those used most frequently in the analyzed articles.

The study examines the prophylactic action of artichoke leaf hydroethanolic extract (ALE) and artichoke flower head hydroethanolic extract (AFE) against diethylnitrosamine (DEN)/acetylaminofluorene (AAF)-induced lung cancer in Wistar rats. To chemically induce lung cancer, DEN was injected intraperitoneally twice a week for a fortnight at a dose of 150 mg/kg body weight (b.w.), followed by oral supplementation of AAF four times a week for 3 weeks at a dose of 20 mg/kg b.w. The DEN/AAF-administered rats were orally supplemented with ALE or AFE at a dose of 100 mg/kg b.w. for 17 weeks starting from the 1st week of DEN injection to the 17th week of the experiment. The lung cancerous injuries resulting from DEN/AAF-administration were significantly improved by the treatment with ALE and AFE as observed in histological examination. In addition, there was a significant reduction in lung lipid peroxidation, with resultant elevation in antioxidant enzymatic activity of glutathione-S-transferase, glutathione peroxidase, glutathione reductase, and superoxide dismutase as well as glutathione content in DEN/AAF-supplemented rats treated with ALE and AFE as compared to DEN/AAF-administered control. The lung tumor suppressor protein (p53) and B-cell lymphoma-2 (Bcl-2) mRNA expression significantly increased in the rats treated with ALE and AFE. In conclusion, the finding showed that ALE and AFE produced anti-cancer prophylactic effects against DEN/AAF-induced lung cancer in rats via suppression of oxidative stress and improved apoptotic signal induction.

The atmosphere security and regulation of climate change are being continuously highlighted as a pressing issue. The crisis of climate change owing to the anthropogenic carbon dioxide emission has led many governments at federal and provincial levels to promulgate policies to address this concern. Among them is regulating the carbon dioxide emission from major industrial sources such as power plants, petrochemical industries, cement plants, and other industries that depend on the combustion of fossil fuels for energy to operate. In view of this, various CO2 capture and sequestration technologies have been investigated and presented. From this review, adsorption of CO2 on porous solid materials has been gaining increasing attention due to its cost-effectiveness, ease of application, and comparably low energy demand. Despite the myriad of advanced materials such as zeolites, carbons-based, metal-organic frameworks, mesoporous silicas, and polymers being researched, research on activated carbons (ACs) continue to be in the mainstream. Therefore, this review is endeavored to elucidate the adsorption properties of CO2 on activated carbons derived from different sources. Selective adsorption based on pore size/shape and surface chemistry is investigated. Accordingly, the effect of surface modifications of the ACs with NH3, amines, and metal oxides on adsorption performance toward CO2 is evaluated. The adsorption performance of the activated carbons under humid conditions is also reviewed. Finally, activated carbon-based composite has been surveyed and recommended as a feasible strategy to improve AC adsorption properties toward CO2. The activated carbon surface in the graphical abstract is nitrogen rich modified using ammonia through thermal treatment. The values of CO2 emissions by sources are taken from (Yoro and Daramola 2020).

The novel SARS-CoV-2 outbreak was declared as pandemic by the World Health Organization (WHO) on March 11, 2020. Understanding the airborne route of SARS-CoV-2 transmission is essential for infection prevention and control. In this study, a total of 107 indoor air samples (45 SARS-CoV-2, 62 bacteria, and fungi) were collected from different wards of the Hajar Hospital in Shahrekord, Iran. Simultaneously, bacterial and fungal samples were also collected from the ambient air of hospital yard. Overall, 6 positive air samples were detected in the infectious 1 and infectious 2 wards, intensive care unit (ICU), computed tomography (CT) scan, respiratory patients’ clinic, and personal protective equipment (PPE) room. Also, airborne bacteria and fungi were simultaneously detected in the various wards of the hospital with concentrations ranging from 14 to 106 CFU m⁻³ and 18 to 141 CFU m⁻³, respectively. The highest mean concentrations of bacteria and fungi were observed in respiratory patients’ clinics and ICU wards, respectively. Significant correlation (p < 0.05) was found between airborne bacterial concentration and the presence of SARS-CoV-2, while no significant correlation was found between fungi concentration and the virus presence. This study provided an additional evidence about the presence of SARS-CoV-2 in the indoor air of a hospital that admitted COVID-19 patients. Moreover, it was revealed that the monitoring of microbial quality of indoor air in such hospitals is very important, especially during the COVID-19 pandemic, for controlling the nosocomial infections.

This study investigates the impacts of climate change on yield of selected cereal crops (wheat and maize) in the northern climatic region of Khyber Pakhtunkhwa (KP) province of Pakistan for the period 1986–2015. The first-generation unit root tests such as the Levin, Lin, and Chu (LLC), augmented Dickey-Fuller (ADF)–Fisher, and the second-generation unit root tests such as cross-sectional augmented Im-Pesaran-Shin (CIPS) and cross-sectional ADF (CADF) are used to check stationarity of the series. The cointegration among the variables is discovered via Pedroni test and Westerlund method. The long- and short-run impacts of climatic variables (average precipitation, maximum temperature, and minimum temperature) on yield of wheat and maize crops are assessed through the autoregressive distributed lag (ARDL) model. The empirical findings reveal that average precipitation has a significantly positive impact on yield of both crops in long- as well as short-run. The results further reveal that the effect of average minimum temperature on both crops is insignificant in long-run. However, the short-run effect of average minimum temperature is significantly positive on yield of maize crop but insignificant on yield of wheat crop. In long-run, an increase in average maximum temperature negatively affects crop yield. In short-run, however, it positively affects the yield of wheat and maize crops. The study recommends that increase in area under cultivation, development of advanced irrigation system, and farmers’ access to metrological information will help in lowering the drastic impacts of climate change on crop productivity.

For the first time, the pedogeochemical contents of some rare earth elements, namely neodymium (Nd), cerium (Ce), lanthanum (La), yttrium (Y), scandium (Sc), and hafnium (Hf), have been investigated in soils and grapevines (leaves) of vineyards in the small municipality of Alcubillas (La Mancha, Central Spain). The content of the elements was determined using an X-ray fluorescence spectrometer in solid mode on a powdered aliquot of each sample (soil or leave). Soil REE concentrations were not as elevated as the territory close to the site under investigation, that are potentially affected by mining of these elements. The order of concentrations follows the general order Ce > La > Nd > Y > Sc > Hf. The bioaccumulation coefficient (BAC) is low, in the range 0.05–0.25, which suggests that leaves only take up rare earth elements in small amounts. The results provide pedogeochemical baseline data for vineyards (soil and plant) not only in the study area but also for similar vineyard zones, with similar environmental conditions.

The aim of this study was to analyze dispersion behavior characteristics and pollution hazard risk after a release of liquid chlorine. A full-scale model of liquid chlorine tanks in an area with a radius range of 3 km was established using FLACS (Flame Acceleration Simulator) code, and the chlorine dispersion characteristics of six leakage scenarios were calculated according to the POOL model, and the individual risk and social risk under different conditions as calculated quantitatively. The results show that leakage occurs in three stages: dynamic dispersion, gravity dispersion, and atmospheric dispersion. Variations in dispersion processes were expressed as “outward expansion” and “inward contraction.” At the same time, dispersion was accompanied by the phenomenon of “cloud separation.” In the six leakage scenarios, the total distance of chlorine dispersion was 84–1000 m for a concentration of 225 ppm, and 27.5–401.3 m for a concentration of 900 ppm. The corresponding times (duration) to the farthest dispersion distance were 235–1345 s and 185–680 s, respectively. Chlorine concentration and dispersion distance are consistent in trend; however, the farthest dispersion distance shows a “delay effect” in time. At 225 ppm and 900 ppm, the delay time was 125–1145 s and 75–480 s indifferent leakage scenarios. The installation of a safety instrument system (SIS) can effectively reduce the risk of chlorine dispersion.

Due to the antibacterial characteristics, numerous-growing applications of silver nanoparticles (AgNPs) and its coated forms impact water treatment by ozone. The influence of ozone on the aggregation of bare AgNPs and polyvinylpyrrolidone-capped form (PVP-AgNPs) was investigated, as toxicity of NPs depends on particle aggregation/surface charge. Full factorial experimental design was employed to investigate the impact of pH, concentration of NPs’ suspension, and ozonation time on bare and PVP-capped AgNPs. Z-Average, zeta potential, and polydispersity index (PdI) of NPs were measured as aggregation criteria. The most effective variables on aggregation of NPs were the coating layer (40–75.5% contribution), pH (14.1–29.6% contribution), and ozonation time (6.5–10.1% contribution), respectively. The aggregation rate increased with increasing ozonation time and decreased with pH. The aggregation of ozonated AgNPs (Z-average up to ~ 4000 nm) was much greater than that of ozonated PVP-AgNPs (Z-average up to ~ 450 nm) due to interaction of ozone–PVP stabilizing layer. During ozonation, the PVP-AgNPs’ surface charge shifted from − 6.62 (steric repulsion) to − 29.17 mV (electrosteric repulsion) at pH 7.5, thereby requiring more treatment time to aggregate compared with AgNPs. Graphical abstract

Studies on the freshwater crab Sinopotamon henanense have shown that acute and sub-chronic Cd²⁺ exposure induced differential alterations in the respiratory physiology and gill morphology. To elucidate Cd²⁺ toxicity under these two exposure conditions, crabs were acutely exposed to 7.14, 14.28, and 28.55 mg/L Cd²⁺ for 96 h and sub-chronically exposed to 0.71, 1.43, and 2.86 mg/L Cd²⁺ for 3 weeks. The Cd²⁺ accumulation, total metallothionein (MT), superoxide dismutase, and malondialdehyde (MDA) contents in the gill tissues were detected. Moreover, the glucose-6-phosphate dehydrogenase (G6PDH) activity, NADPH content, reduced glutathione (GSH), oxidized glutathione (GSSG), and GSH/GSSG ratio in the hepatopancreas were determined. The morphology of the X-organ–sinus gland complex was also observed. The results showed that sub-chronical Cd²⁺ exposure induced lower MT content and higher MDA level in the gills than in the acute exposure. In the hepatopancreas, acute Cd²⁺ exposure decreased the pentose phosphate pathway activity and NADPH content; however, an increased G6PDH activity and NADPH content were detected in sub-chronic Cd²⁺ exposure (2.86 mg/L). Morphological changes occurred in the sinus gland in crabs exposed to 2.86 mg/L Cd²⁺ for 3 weeks. The tightly packed structure composed by the axons, enlarged terminals, and glial cells, became loose and porous. Ultra-structurally, a large number of vacuoles and few neurosecretory granules were observed in the axon terminal. These effects added to our understanding of the toxic effects of Cd²⁺ and provide biochemical and histopathological evidence for S. henanense as a biomarker of acute or long-term waterborne Cd²⁺ pollution.