Bulk rainfalls were sampled during ten months in the Eastern Channel (Northern France). Chloride and sodium are the heavily loaded major ions in wet deposition, indicating a high influence of seasalt. However, the presence of heavy metals is independent of seasalt emissions and various anthropogenic sources should have an impact on their atmospheric concentrations.The comparison between heavy metals concentrations, always ranked as [Zn] ≫ [Pb] > [Cu] ≫ [Cd], with other values obtained during the same period on European coastal or on urban sites, confirms that ourwestern European station is in a semi-rural area where no local source strongly influences the abundance of atmospheric heavy metals. This semi-rural site could be disturbed by medium and/or long range transportepisodes.The observation of literature data confirms a decrease of Cd, Cu and Pb concentrations in rain waters from the beginning of the nineties. On the other hand, no sharp evolution has been observed for zinc concentrations.The structuring of data by clustering has permitted to extract five clusters, including four different types of origins. Two marine clusters, with relatively low levels of heavy metals, are opposite to three other clusters with higher heavy metal levels and a more important impact of continental polluted sources. In 47% of cases, the heavy metals collected at Cap Gris-Nez could originate from British Islands or north western Europe.Heavy metals fluxes show that this rural coastal European site has a level of contamination higher than those measured in remote area. The wet depositions of heavy metals to the English channel and the southern bight of the north sea are not negligible in the evaluation of global fluxes for this area, representing from 20 to 70% of the total input (riverine, direct and atmospheric inputs).

Changes in land-use or management practices may affect water outflow, sediment, nutrients and pesticides loads. Thus, there is an increasing demand for quantitative information at the watershed scale that would help decision makers or planners to take appropriate decisions. This paper evaluates by a modeling approach the impact of farming practices and land-use changes on water discharge, sediment and NO3-N loads at the outlet of a 51.29 km2 watershed of central Iowa (Walnut Creek watershed). This intensively farmed (corn-soybean rotation) watershed is characterized by a flat topography with tiles and potholes. Nine scenarios of management practices (nitrogen application rates: increase of current rate by 20, 40%, decrease of current rate by 20, 40 and 60%; no tillage) and land-use changes (from corn-soybean rotation to winter wheat and pasture) were tested over a 30 yr simulated period. The selected model (Soil and Water Assessment Tool, SWAT) was first validated using observed flow, sediment and nutrient loads from 1991 to 1998. Scenarios of N application rates did not affect water and sediment annual budgets but did so for NO3-N loads. Lessening the N rate by 20, 40 and 60% in corn-soybean fields decreased mean NO3-N annual loads by 22, 50 and 95%, respectively, with greatest differences during late spring. On the other hand, increasing input N by 20 and 40% enhanced NO3-N loads by 25 and 49%, respectively. When replacing corn-soybean rotation by winter wheat, NO3-N loads increased in early fall, immediately after harvest. Pasture installation with or without fertilization lessened flow discharge, NO3-N and sediment delivery by 58, 97 and 50%, respectively. No-tillage practices did not significantly affect the water resource and sediment loads. Finally, such realistic predictions of the impact of farming systems scenarios over a long period are discussed regarding environmental processes involved.

1,1-bis(p-chlorophenyl)-2,2,2-trichloroethane (p,p′-DDT) is a recalcitrant organic compound that is difficult to remove from contaminated soil due to its low solubility. In this study we investigated the effectiveness of both cosolvents and surfactants in enhancing the solubility of p,p′-DDT from a soil that has been contaminated with DDT for nearly 40 yr. The presence of selected surfactants removed less than 1 to 11% of p,p′-DDT compared to cosolvents, which removed less than 1 to 77% of p,p′-DDT from the same soil. The low solubility of p,p′-DDT in the presence of surfactants was attributed to the decreased surfactant concentration to below critical micelle concentrationfollowing sorption by soil surfaces. Enhanced solubility of p,p′-DDT was achieved with the use of cosolvents that releasedup to 77% of p,p′-DDT from a contaminated soil. Increasing the solution concentration and hydrophobicity of the cosolvent increased the amount of p,p′-DDT desorbed. For example, the amount of p,p′-DDT desorbed increased in the order 5% 1-propanol << 50% ethanol << 50% 1-propanol. Repeated washing of the soil with various cosolvents, in all but two cases, markedly increased the total amount of p,p′-DDT desorbed from the soil. For example, repeated washing of the soil with 50% ethanol increased the amount of p,p′-DDT removed by 42% while repeated washings of the soil with 50% 1-propanol had little effect on the amount of p,p′-DDT desorbed. Increasing the soil-solution ratio from 1:2 to 1:10 in the presence of 40% 1-propanol increased the amount of p,p′-DDT desorbed by 100%; suggesting that the soil-solution ratio was an important parameterin controlling the amount of p,p′-DDT desorbed.

This study investigated the intrinsic perchlorate (ClO₄ ⁻)degradation kinetics of sediments and soils from multiple sites in microcosm studies, including the influence of varying nitrate concentration (NO₃ ⁻-N from 1 to 22.8 ppm) and up to 300 ppm sulfate. The first-order degradation rates and lag times of both ClO₄ ⁻ and NO₃ ⁻ degradation were site-specific and dependent on environmental conditions such as organic substrate availability, nitrate, initial ClO₄ ⁻ concentration, and prior ClO₄ ⁻ exposure. At an initial ClO₄ ⁻ concentration of 5 ppm, ClO₄ ⁻ degradation rates ranged from 0.13 to 0.46 day⁻¹, and lag times of ClO₄ ⁻ degradation ranged from 0 to 60.0 days; while NO₃ ⁻ degradation occurred at rates ranging from 0.03 to 1.42 day⁻¹, with lag times ranging from 0 to 29.7 days. Under the same treatment conditions, NO₃ ⁻ degradation rates were relatively higher than that of ClO₄ ⁻. Perchlorate degradation rates remained constant at both lower (0.5 ppm) and higher (5 ppm) ClO₄ ⁻ concentrations. Generally, ClO₄ ⁻ rates were affected by the availability of organic substrate, which was represented here by Total Volatile Solids (TVS) of sediments and soils, and not by NO₃ ⁻. Nitrate did increase the lag time of ClO₄ ⁻ degradation, which may account for the persistence of ClO₄ ⁻ in the environment, especially when ClO₄ ⁻ is typically ppb levels in the environment compared to ppm levels of NO₃ ⁻. This study showed rapid intrinsic ClO₄ ⁻ degradation in sediments and soils of contaminated sites, and highlighted the potential for natural attenuation of ClO₄ ⁻ in the environment.

This work aims to identify the sources of nitrogencontamination in nitrate vulnerable zones (NVZs) of Spain by means of the nitrogen isotope method. Three categories of nitrogen sources (synthetic fertilisers, animal wastes, and sludges and effluents from waste-water treatment plants) from three NVZs were analysed for their nitrogen isotopic composition (δ¹⁵N) in order to assess the applicability of the method to the identification of these N sources. The mean δ¹⁵N values were: +1.48‰ for synthetic fertilisers, +15.98‰ for animal wastes and +11.52‰ for sludges and effluents. The synthetic fertiliser sources were significantly different from the organic sources and so, the method can be used for their identification. The highest variability was found within the animal waste category. The range of values found for the different kinds of animal wastes (+5.86 to +36.74) was very wide and overlappedthe range found for sludges and effluents from waste-water treatmentplants (+4.57 to +20.18). Accordingly, these two nitrogen sources areisotopically indistinguishable.

Passive capillary samplers, which sample water from the vadose zone via a hanging water column in a fiberglass wick, have shown potential to provide better estimates of actual soil percolation fluxes than alternative field methods. Unsaturated and saturated flows (water and solutes) are extracted continuously and without external vacuum generator from a nondisturbed soil volume, through a significant area (typically 600cm2). In order to achieve a minimal disturbance of the native flow regime, the wick type (hydraulic conductivity and section), length and number and the contact area have to be dimensioned to match as close as possible the expected soil pressure/flow conditions. First, the Hydrus 2D code (Simunek et al., 1999) solving the Richards equation for simulating two dimensional unsaturated flow was used to evaluate the uncertainties in flux estimation by such passive capillary samplers. Two sources of uncertainties were examined. Those associated with the theoretical assumptions of the dimensioning of the wick and those associated to experimental uncertainties. A numerical experimentation was conducted on two reference soils submitted to a 11 days actual hyetograph. Results showed that an analytical dimensioning method proposed in the literature is relevant. But significant errors on the observed fluxes occur when the soil and wick properties do not exactly match, which is the common case since the range of available characteristics of fiberglass wicks is limited. Also, uncertainties in the hydraulic conductivity properties of the soil, in wick length appear to have an important influence on the representativity of the wick fluxes against the actual soil drainage fluxes. Elsewhere, eight such samplers have been installed for an in situ long term experimentation ,initiated this year in the Ardière Watershed (France). The objective is to measure water and pesticides percolation fluxes, at a 50cm depth under a grassed strip receiving contaminated runoff. Flow rate and pesticide concentration in surface runoff water are also measured so as to determine the soil boundary condition above each sampler. Soil water content and soil matric potential are measured at three different depth very close to each instrumented profile in order to explain the volumes extracted by each sampler. We present here the experimental methodology and first results obtained with simulated runoff events.

Background, Aims and Scope: Current dredged material disposal alternatives have several limitations. Options for dealing with dredged materials include leaving them alone, capping them with clean sediments, placing them in confined facilities, disposing of them at upland sites, treating them chemically, or using them for wetlands creation or other beneficial uses. The ability to reuse lake-dredge materials (LDM) for agricultural purposes is important because it reduces the need for offshore disposal and provides an alternative to disposal of the materials in landfills. Often these materials can be obtained at little or no cost to the farmers or landowners. Thus, forage production offers an alternative to waste management since nutrients in the LDM are recycled into crops that are not directly consumed by humans. The objective of this study (Part 2) were to: (1) assess dredge materials from Lake Panasoffkee, Florida as a soil amendment to establish bahiagrass (BG) in a subtropical beef cattle pasture in Sumter County, Florida; and (2) determine the effect of LDM application on the crude protein (CP) and nutrient uptake of BG. This series of two papers aims at providing assessment of the efficacy of lake-dredged materials especially its implication to environment (soil quality, Part 1) and agriculture (forage quality and pasture establishment. Part 2). Methods: The experimental treatments that were evaluated consisted of different ratios of natural soil (NS) to LDM: LDMO (100% NS:0% LDM); LDM25 (75% NS:25% LDM); LDM50 (50% NS:50% LDM); LDM75 (25% NS:75% LDM); and LDM100 (0% NS:100% LDM). Bahiagrass plots at its early establishment were cut to a 5-cm stubble height on Julian days 112 and harvested to the same stubble height on Julian days 238 and on Julian days 546 following the double-ring method. Field layout was based on the principle of a completely randomized block design with four replications. Plant samples harvested at 546 Julian days were ground to pass through a 1-mm mesh screen in a Wiley mill. Ground forage was analyzed for crude protein. Ground forage samples were also analyzed for tissue P, K, Ca, Mg, Mn, Cu, Fe, Al, and Mo concentrations using an ICP spectroscopy. The effects of dredged materials addition on forage yield and on crude protein and nutrient uptake that were taken at 546 Julian days were analyzed statistically following the PROC ANOVA procedures. Results and Discussion: Part 1 of this study demonstrated that the heavy and trace metal contents of LDM were below the probable effect levels and threshold effect levels. As such, the agricultural or livestock industry could utilize these LDM to produce forages. Results showed consistently and significantly (p < or = 0.001) higher BG biomass production and CP from plots amended with LDM than those of BG planted on plots with 0% LDM. Forage yield of BG during its establishment increased linearly (Forage Yield = 1724.3 + 25.64*LDM; R2 = 0.83; p < or = 0.0001) with increasing rates of LDM application. The CP of BG also varied significantly with varying levels of LDM applications. The tissues of BG with 100% LDM had the greatest CP content while the lowest CP content was from the control plots (LDMO). The CP of BG increased linearly with increasing rates of LDM application. The crude protein response to BG application can be described by a linear equation: Crude Protein = 10.38 + 0.052*LDM; R2 = 0.85 p < or = 0.0001. Addition of LDM had increased the levels of Ca by about 1811 % when compared with the level of soil Ca among plots with no LDM application. Liming the field could have some direct and indirect effects on the chemical status of the soils. The physiological functions performed by Ca in plants are not clearly defined, but it has been suggested that Ca favors the formation of and increases the protein content of mitochondria. Conclusions: Beneficial uses of dredged materials from LP, Florida are both economical and environmental. Often these materials can be obtained at little or no cost to the farmers or landowners. Results showed that dredged materials can be used as soil amendments (lime and fertilizer) for early establishment of BG in beef cattle pastures. Environmentally, dredging of sediments that are rich in CaCO3 should restore the 19.4-sq km LP by removing natural sediments from the lake bottom to improve the fishery, water quality, and navigation of the lake. The nutritional uptake of BG grown in unfertile sandy soils of Sumter County was enhanced significantly (p < or = 0.001) by LDM addition. Uptake of TKN, TP, K, Ca, and Mg were remarkably increased as a result of LDM. Recommendation and Outlook: Land application of LDM from LP may not only provide substantial benefits that will enhance the environment, community, and society in south Florida, but also in other parts of the world especially those areas with forage-based beef cattle pastures and similar climatic conditions. The heavy and trace metal contents of these materials were below the PEL and TEL (see Part 1). As such, the agricultural or livestock industry could utilize these LDM to produce forages. LDM should be regarded as a beneficial resource, as a part of the ecological system. Although our results have demonstrated the favorable and beneficial effects of added LDM on the early establishment of BG in pasture fields., further studies are still needed not only in pastures of south Florida, but also in other areas with subtropical or tropical climatic conditions to determine whether the environmental and ecological implications of LDM application are satisfied over the longer term.

On s'interroge sur la qualité physico-chimique et biologique de l'eau des rivières en étudiant les zones actives, les flux et biodisponibilité du phosphore (région du lac Léman), les zones actives et production de matières en suspension (Basse-Normandie) et les zones tampons et teneurs en nitrate dans les cours d'eau (Basse-Normandie). | Wonders about the physicochemical and biological quality of the water of the rivers by studying the active zones, flows and biodisponibility of phosphorus (area of the lake Léman), the active zones and production of suspended matter (Low-Normandy) and the buffer zones and nitrate contents in the rivers (Low-Normandy).

On étudie le phénomène de la diminution de la population des salmonidés, dû à la modification de la gestion de l'espace agricole et l'intensification des pratiques culturales, associées à des conditions climatiques et pédologiques particulières.