In this study, the physicochemical properties, microstructure, and heavy metal leaching potential of various municipal solid waste incinerated-bottom ash (MSWI-BA) particle sizes were detected. The environmental risks that possibly result from the utilization of MSWI-BA aggregate in road construction are discussed. The air-dried MSWI-BA was sieved into four groups, including 4.75–9.5 mm, 2.36–4.75 mm, 0.075–2.36 mm, and < 0.075 mm. X-ray fluorescence (XRF), X-ray diffraction (XRD), and scanning electron microscopy (SEM) analyses were conducted. It was found that the main elements of MSWI-BA are Ca, Si, and Al; the major heavy metals are Zn, Cu, Cr, and Pb, and the main mineral compositions are quartz and calcite. Even though the major elements were found to be related to MSWI-BA particle size, the micropores, attached particles, and hydration products were shown to be independent on the particle size. The standard leaching test and a simulated leaching experiment with four solid/liquid ratios were implemented to study the leaching behavior of Zn, Cu, Pb, and Cr. Results showed that the leaching characteristics of selected metals were affected by the species of metal, MSWI-BA particle size, solid/liquid ratio, and the test method. The MSWI-BA aggregate was found to be an appropriate substitute material for natural aggregate in road construction due to its low metal leaching potential.

Streams and surrounding terrestrial ecosystems are closely linked by numerous resource subsidies including anthropogenic subsidies which are increasingly entering streams due to intensive human activities. Also, streams are threatened by stressors such as glyphosate—the most widely used herbicide worldwide. However, the ecological consequences of anthropogenic subsidies and glyphosate on freshwaters are not fully understood. Here, we deployed leaf litter (Cinnamomum camphora) bags containing neither, either, or both treatments of anthropogenic carrion subsidy (chicken meat) and glyphosate (coated in agar) in four streams, which had different land use (i.e., forest, village, and suburban) in Huangshan, Anhui Province, China. We aimed to investigate the individual and combined effects of anthropogenic carrion subsidy and glyphosate on macroinvertebrates in streams and whether these effects differ with land use change. Macroinvertebrate communities significantly differed among streams: biodiversity index and total taxon richness were highest in village streams and lowest in suburban stream. Overall effects of carrion subsidy and glyphosate on macroinvertebrates were not significant. However, several taxa were affected in one or more streams by the individual or combined effects of carrion subsidy and glyphosate, indicating the importance of local community structure and physical habitats in driving the response of macroinvertebrates to carrion subsidy and glyphosate. Collectively, these results imply that the effects of carrion subsidy and glyphosate on macroinvertebrates are site-specific, and future studies should cover more streams and last longer time to better understand the ecological mechanisms driving such pattern.

In this study, we want to clarify the driving factors of phytoplankton community in a set of eutrophic lakes in the lowland areas of Huaihe River, one of seven biggest rivers in China. We analyzed the phytoplankton community of five lakes located in the lowland areas of Huaihe River using Reynolds functional groups (RFG) approach, with simultaneous measurement of several environmental variables in monthly sampling campaigns during 2 years. The annual average phytoplankton biovolume of the five lakes ranged from 3.7 to 9.9 mm³/L, with the highest values occurring during warm seasons. The shallow eutrophic lakes primarily contained mixing and low-light adaptive species with C and D groups as dominant all-round the year. Representatives of X2, Y, and W1 were predominant during the spring and the autumn with high nutrients and organic matter concentrations. Cyanobacteria were mainly represented by group S1 especially during the summer. Mixing, temperature, together weak light caused by phytoplankton biomass, could shape phytoplankton assemblage more than nutrients in the shallow eutrophic lakes with warm-temperate climate.

The aim of this study is to examine the relationship between climate change and political instability in the MENA region. To this extent, 18 Middle East and North African (MENA) countries are analyzed covering the period 1985:01–2016:12 with monthly data. In econometric analysis, at first cross-sectional dependency analysis is applied, and existence of cross-sectional dependency among countries is found. Therefore, CADF-second generation panel unit root test applied, and finally, Dumitrescu and Hurlin (2012) panel causality test that consider the cross-sectional dependency are utilized. For empirical analysis, temperature and precipitation data representing climate change, political instability, and conflict data are employed. According to the findings, there is a causal relationship from climate change to political instability in 16 countries and to conflict in 15 countries. In addition to this, at least one causal relationship is determined from climate change to political instability or conflict in all MENA countries. Therefore, empirical results support the assumption that climate change acts as a threat multiplier in MENA countries since it triggers, accelerates, and deepens the current instabilities.

The overmining of groundwater makes the aquifer in a coastal area prone to seawater intrusion and further leads to deterioration of water quality and ecosystem degradation. However, the vulnerability evaluation of seawater intrusion can provide a scientific basis for the prevention of seawater intrusion, and then ensure the sustainable use of groundwater. In this paper, Baihai City was taken as the study area, and the analytic hierarchy process (AHP), variable power theory, and fuzzy comprehensive evaluation method were used synthetically. The vulnerability of seawater intrusion in the study area was divided into lowest vulnerability, low vulnerability, medium vulnerability, and high vulnerability, and these correspond to 1739.98, 133.88, 664.32, and 737.55 km². On this basis, combined with the groundwater quality and quantity and ecosystem of the study area, the groundwater is divided into concentrated groundwater supply area (8.16%), decentralized groundwater supply area (12.44%), protected area (78.94%), and reserved zone (0.45%), which can provide the basis for the rational exploitation and management of groundwater. By analyzing the results of constant right and variable weight evaluation, combined with the history of seawater intrusion, it is proved that the variable weight evaluation model can effectively solve the unreasonable situation caused by the internal differences of the indicator, so that the evaluation results are more in line with reality. In addition, the application of the fuzzy comprehensive evaluation method makes the evaluation results clearer.

This paper uses static and dynamic panel regression to measure the effect of energy consumption on air quality of 20 heavily polluted cities in the Yangtze River Delta of China. Further, the influence of the relevant policies on the relationship between energy consumption and air quality is tested with the method of regression discontinuity. This study concluded the following: (1) When energy consumption structure, industrial structure, and energy efficiency are taken into account, the effect coefficient of energy consumption on air quality is 0.4579, meaning that controlling energy consumption tends to improve the air quality positively. (2) The emission of sulfur dioxide is characterized by inertia; the annual increase in sulfur dioxide emissions in the previous year will lead to an increase of 0.427% in the annual emissions. (3) The relationship between energy consumption and air quality of different cities varies, and these cities can be divided into four categories. (4) The relevant policies for improving air quality are effective to some extent. This study indicates that the Yangtze River Delta should focus on actively changing the mode of energy development.

Phytoremediation potential of duckweeds (Lemna minuta, Lemna minor) to remove nutrients from simulated wastewater was analyzed. In two separate experiments, the two species were grown for 28 days in waters enriched with nitrate and phosphate to simulate nutrient concentrations of domestic wastewater. Water physical and chemical measurements (temperature, pH, conductivity, oxygen) and plant physiological and biochemical analysis (biomass, relative growth rate–RGR, nutrient and chlorophyll contents, peroxidative damage, bioconcentration factor–BCF) were made to test and compare the phytoremediation capacity of the two Lemna species. L. minuta biomass increased almost tenfold during the time-course of the treatment resulting in a doubling of the mat thickness and a RGR of 0.083 ± 0.001 g/g day. Maximum frond content of phosphate was reached by day 21 (increase over 165%) and nitrate by day 7 (10%). According to the BCF results (BCF > 1000), L. minuta was a hyperaccumulator for both nutrients. On the other hand, L. minor biomass and mat thickness decreased continuously during incubation (RGR = − 0.039 ± 0.004 g/g day). In L. minor fronds, phosphate content increased until day 14, after which there was a decrease until the end of the incubation. Frond nitrate content significantly decreased by day 7, but then remained relatively constant until the end of the experiment. L. minor proved to be hyperaccumulator for phosphates, but not for nitrates. Results indicated L. minuta has a greater potential than L. minor to remove both nutrients by bioaccumulation, especially phosphates, demonstrated also by better physiological and biochemical responses. However, during the incubation, the chlorophyll content of L. minuta mat did continuously decrease and peroxidative damage had increased until day 14, indicating that the system was under some kind of stress. Strategies to avoid this stress were discussed.

Manure-based fertilizer is usually applied to agricultural soils to increase soil fertility and improve soil quality. However, this practice has an impact on the soil environment, e.g., increasing heavy metal contents. The aim of this study was to evaluate and estimate the accumulation tendencies of eight heavy metals, including arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), lead (Pb), manganese (Mn), and zinc (Zn) in a soil fertilized continuously with dairy manure through a 5 years’ field-scale experiment. Contents of the As, Cd, Cr, Cu, Mn, and Zn gradually increased with the fertilization time of dairy manure at the stable rate of around 326 t hm⁻² year⁻¹, leading to annual mean increases of 3.6%, 2.4%, 3.9%, 3.8%, 4.2%, and 6.1%, respectively. Based on the prediction of a dynamic mass balance model using the current practice, the contents of Cd and Zn in the fertilized soil would reach the Chinese standard values for agricultural soils in 48 and 35 years. The mitigation measures, such as lower application rates, for the environmental risk of heavy metal accumulation should be considered.

A facile solution processing strategy has been developed for the formation of Ag-modified ZnO microneedles at various calcination temperatures such as 300, 500, and 700 °C (AZ3, AZ5, and AZ7 respectively). Due to the heavy doping of AgNO₃, Ag⁺ ions have been incorporated in to the crystal lattice of ZnO in all the Ag-ZnO samples, which facilitated the formation of Ag-ZnO microneedle morphology with minimized defect states, and obviously, the plasmon peaks were observed due to Ag modification. These Ag-ZnO microneedle structures have been evaluated for their photocatalytic performance using methylene blue as model target contaminant and their activity was compared with the commercially available titania P25 photocatalyst. The photoactivity of all the Ag-ZnO microneedle structures was significantly higher than that of the commercially available P25 photocatalyst with the most active Ag-ZnO material having a photocatalytic activity ~ 1.4 times greater than that of P25 titania.

Due to a technologic progress, a growth in the renewable energy markets including a high number of manufactures coming to being, the Renewable Energy Sources (RES) are both a tool for mitigating climate changes and investments that can provide direct economic profits and reduce a political or economic dependence resulting from import of fossil fuels. One of the many key solutions toward fulfilling the global increasing demand for energy and reduction of CO₂ emissions is applying solar technologies. This paper presents the results of the analysis conducted for a small public office building located in Bialystok (Poland), where solar collectors were considered as the RES for domestic hot water (DHW) system, on the understanding that existing oil boiler would be an additional source. Low values of recommended water consumption in office buildings resulted in a low energy demand. However, concerning a potential of all office governmental buildings in Poland, it would be possible to reduce CO₂ emission by 17,248 tonnes. In the comprehensive analysis, the same building in two more locations (Cordoba (Spain) and Kaunas (Lithuania)) was considered using simulation tools delivered within the framework of VIPSKILLS project as well as EnegyPlus software. The results allow to compare the mean monthly efficiency of systems or number of collectors necessary to deliver similar amount of solar energy.