In this paper, Pd/C catalysts are synthesized via Ar glow-discharge plasma reduction using activated carbon as the support and Pd(acac)₂, Pd(NO₃)₂, K₂PdCl₄, and H₂PdCl₄ as the Pd precursors, and their catalytic performances are investigated by hydrogen production from dodecahydro-N-ethylcarbazole (H12-NEC). Pd/C-A, prepared from Pd(acac)₂, which has the smallest palladium nanoparticles (1.7 nm), the highest dispersion (34%) and no residue of inorganic ions, exhibits the best catalytic activity with a hydrogen release of 5.28 wt.%, which is 2.2 times that of Pd/C-H. The order of the apparent activation energies of the prepared Pd/C catalysts, according to the kinetics of the H12-NEC dehydrogenation reaction, is as follows: Pd/C-A ≈ Pd/C-N < Pd/C-K < Pd/C-H. When Pd(acac)₂ with a large ligand acts as a cation Pd precursor, the effect of coulombic attraction to Pd²⁺ during the plasma reduction process makes it difficult for Pd nanoparticles (NPs) to migrate, which leads to the formation of ultrafine Pd NPs.

In recent decades, the frequency and severity of inland river seawater intrusion has increased in the Pearl River Estuary (PRE) of China. Based on time series of water salinity data, river discharges, tides, and wind records for the period 2003–2015, this study aims to examine the regular pattern and underlying mechanisms of the seawater intrusion in the Modaomen channel of the PRE. Toward this end, the autocorrelation and spectral analysis are used to quantify the periodicity of runoff, tide, and water salinity and to infer the regular patterns of seawater intrusion. The Pearson correlation and the LMG metric are used to examine the effects of influencing factors on seawater intrusion. Results indicate that seawater intrusion in the Modaomen channel has distinct annual (369 days) and half-monthly (14.8 days) cycles, corresponding well with annual and half-monthly tidal cycles. Spatially, the frequency, severity, and periodicity of seawater intrusion decrease with increased landward distance away from the channel mouth. The prevention of seawater intrusion by incoming river flow becomes more remarkable as freshwater flows downstream. Shifts in wind speed and direction can strengthen or weaken seawater intrusion, depending on if wind is in the opposite or same direction of river flow. Further analysis using the LMG metric suggests that river discharge plays a dominant role in governing seawater intrusion. Overall, river discharges, tides, and wind are three major forces triggering the inland river seawater intrusion and account for, respectively, 46%, 15%, and 15% of the variation of water salinity in the Modaomen channel. The study is featured in not only identifying the major factors in driving seawater intrusion but also quantifying their relative contribution. Thus, the findings are important for water resources manager to predict and manage inland river seawater intrusion in the PRE of China.

The Rio do Campo and Rio Km 119 rivers are under constant human pressure. Thus, it is necessary to assess the adverse effects caused by waters of these rivers to living organisms. Phytotoxicity and enzymatic modulation of waters from eight sites was evaluated against Lactuca sativa L.—five located in Rio do Campo (P1, P2, P3, P4, and P5) and three located in Rio Km 119 (P6, P7, and P8)—strategically making up the surroundings of Campo Mourão. For every site, two samplings were made in 2019, one during the dry season (first sampling) and another during the rainy season (second sampling). Waters from P2 and P8, collected in the dry season reduced the seed germination rate. With the exception of P7 in sampling 1, waters from the other sites, in both seasons considered, significantly inhibited radicle elongation. In the dry season, there was an increase in CAT activity, mainly in roots exposed to waters from P3 and P7. In the rainy season, there was a reduction in the activity of this enzyme in roots, caused by waters from P1, P2, P4, P6, and P7. Except for P3 in the first sampling, roots exposed to waters from the eight sites, in samplings 1 and 2, had inhibition in SOD activity. Therefore, waters from the eight sites caused significant phytotoxicity and oxidative stress to L. sativa. These results complement and corroborate studies to assess the toxicity of waters of the Rio do Campo and Rio Km 119 rivers present in the literature. The imminent intervention of the public management of Campo Mourão and of the State government is necessary in the urban and agricultural human activities carried out in these springs, given the significant degradation and putting the survival of different species at risk.

Since the invasion of the fall armyworm moth (Spodoptera frugiperda) in China in January 2019, damage to maize crops has gradually intensified, and chemical control has become the main control measure. This study aimed to examine methods of effective pest control while monitoring the environmental impact of pesticide use. The effectiveness of S. frugiperda pest control by foliar spraying and root irrigation of maize plants with acephate was determined, and the absorption, distribution, and dissipation of acephate and methamidophos by maize were studied. Field trials showed that acephate treatment at 6000 g a.i. ha⁻¹ was the most effective for controlling S. frugiperda. Acephate and methamidophos were absorbed from the roots, transported upward, and concentrated in the leaves, particularly new leaves. The terminal residues of acephate and methamidophos in maize grains were below detectable levels at 60 days after treatment. The results demonstrate that acephate treatment via root irrigation can more effectively control the infestation of S. frugiperda in maize than acephate treatment via foliar spraying. The translocation and distribution of acephate and methamidophos by root irrigation were more uniform, and the holding efficiency was higher than those in foliar spraying, suggesting an extended period of control efficacy. This pest control method could be utilized to reduce pesticide residues while safely and efficiently controlling S. frugiperda infestation.

Trichloroethylene (TCE) was a widely used industrial solvent but is now regarded as a notorious groundwater contaminant. Both physicochemical and biological methods have been applied to remediate groundwater contaminated by TCE. For medium to low level of TCE contamination, bioremediation could be more cost-effective. However, bioremediation approaches suffer from slow degradation rates and accumulation of vinyl chloride (VC). In addition, bioaugmentation is often highly encouraged but may introduce foreign genes and increase the pace of microbial evolution. In this study, a microbiome reengineering strategy by heat selection is applied to solve these problems. Out of eight heat-treated mixed cultures, two showed a much-improved TCE degradation rate, more than 70 times higher than the untreated. The biodegradation half-life (t₁/₂) of TCE was 0.0627 d or shorter. No VC was detected by a gas chromatography equipped with flame ionization detector (GC-FID) and only a minimal amount by a GC-mass spectrometer (GC-MS). Ethene achieved a fairly good mass balance. Polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) and next-generation sequencing (NGS) results showed that the heating process did not kill most bacteria, but Dehalococcoides were either not present or very scarce. Acetoanaerobium and Methanosarcina could be the most important species in this reductive dechlorination process. Kinetic study results showed that the maximum specific TCE degradation rate was approximately 1,271 nmole/min/mg cell protein, which are two orders of magnitude higher than that of the mixed cultures reported in literature. These results suggest that apart from biostimulation and bioaugmentation, microbiome reengineering could be a promising approach for rapid bioremediation of TCE-contaminated aquifers.

The pandemic of coronavirus disease 2019 (COVID-19), caused by the novel coronavirus SARS-CoV-2, is generating a high number of deaths worldwide. One of the current questions in the field of environmental science is to explain how air pollution can affect the impact of COVID-19 pandemic on public health. The research here focuses on a case study of Italy. Results suggest that the diffusion of COVID-19 in cities with high levels of air pollution is generating higher numbers of COVID-19 related infected individuals and deaths. In particular, results reveal that the number of infected people was higher in cities with more than 100 days per year exceeding limits set for PM₁₀ or ozone, cities located in hinterland zones (i.e. away from the coast), cities having a low average speed of wind and cities with a lower average temperature. In hinterland cities having a high level of air pollution, coupled with low wind speed, the average number of infected people in April 2020—during the first wave of the COVID-19 pandemic—is more than tripled compared to cities with low levels of air pollution. In addition, results show that more than 75% of infected individuals and about 81% of deaths of the first wave of COVID-19 pandemic in Italy are in industrialized regions with high levels of air pollution. Although these vital results of the first wave of the COVID-19 from February to August 2020, policymakers have had a low organizational capacity to plan effective policy responses for crisis management to cope with COVID-19 pandemic that is generating recurring waves with again negative effects, déjà vu, on public health and of course economic systems.

Main aim of the present research is to explore the potential use of Vetiveria zizanioides L. for phytoremediation of arsenic, fluoride, and manganese simultaneously from synthetic wastewater in a batch scale floating platform unit. Half strength Hoagland’s nutrient solution spiked with arsenic, fluoride, and manganese concentrations of 1, 20, and 10 mg/L, respectively has been used. The effects of pH and treatment time on simultaneous removal of arsenic, fluoride, and manganese have been performed. V. zizanioides has exhibited optimum growth at pH 8 and the removal of arsenic and fluoride is observed to be 59.6 and 38.1%, respectively. This plant has successfully removed all of the manganese (99.3%). The uptake of manganese is found to be faster than the arsenic and fluoride. The trend of arsenic, fluoride, and manganese accumulation in various parts of V. zizanioides is found as roots > stems > leaves. Result showed that the use of V. zizanioides would be appropriate to treat arsenic, fluoride, and manganese contaminated wastewater.

The research of the environmental fate of pesticides has demonstrated that applied compounds are altered in their molecular structure over time and are distributed within the environment. To assess the risk for contamination by transformation products (TP) of the herbicides flufenacet and metazachlor, the following four water body types were sampled in a small-scale catchment of 50 km² in 2015/2016: tile drainage water, stream water, shallow groundwater, and drinking water of private wells. The TP were omnipresent in every type of water body, more frequently and in concentrations up to 10 times higher than their parent compounds. Especially metazachlor sulfonic acid, metazachlor oxalic acid, and flufenacet oxalic acid were detected in almost every drainage and stream sample. The transformation process leads to more mobile and more persistent molecules resulting in higher detection frequencies and concentrations, which can even occur a year or more after the application of the parent compound. The vulnerability of shallow groundwater and private drinking water wells to leaching compounds is proved by numerous positives of metazachlor-TP with maximum concentrations of 0.7 μg L⁻¹ (drinking water) and 20 μg L⁻¹ (shallow groundwater) of metazachlor sulfonic acid. Rainfall events during the application period cause high discharge of the parent compound and lower release of TP. Later rainfall events lead to high displacement of TP. For an integrated risk assessment of water bodies, the environmental behavior of pesticide-TP has to be included into regular state-of-the-art water quality monitoring.

The Wanshan mercury mine, which is an abandoned mine located in northeastern Guizhou Province in Southwest China, has introduced serious Hg pollution to the local ecosystem resulting from previous mining and smelting activities. However, it is not clear to date whether soil pollution has actually improved after treatment by related departments. Therefore, the present study investigates the vegetation community and heavy metal contents of the soil and plants in the Wanshan mercury mining area. The results showed that most of Hg, Cd, As, Cu, and Zn contents in soil samples were higher than those of Soil Environment Quality Risk Control Standard for Soil Contamination of Agricultural Land in China (GB15618-2018). The observed plant species mainly consisted of Compositae, followed by Leguminosae. Unfortunately, this investigation found that heavy metal concentrations in these plants were not extremely high and far below the standard of hyperaccumulator. Despite all this, the maximum values of bioaccumulation factor for Pb, Cd, Hg, As, Cu and Zn were Serissa japonica (Thunb.) Thunb., Rhus chinensis Mill., Potentilla sibbaldii Haller f., Erigeron canadensis L., Clerodendrum bungei var. bungei. and Rhus chinensis Mill., respectively. Regardless of the carcinogenic or noncarcinogenic risk index, the potential risk to urban children is higher. Our results suggest that heavy metal pollution was indeed relieved since their contents in soil significantly decreased in comparison with those reported in other previous studies. This finding provides a reference for the long-term treatment of heavy metal pollution in the local environment and other areas employing analogous environmental protection measures.

China has pledged to peak its carbon dioxide emissions (CEM) before 2030 and achieve carbon neutrality before 2060. The energy consumption related to land urbanization (LURB) and internet penetration (INT) may have a significant impact on CEM. It is critical for China to obtain a better understanding of the interaction among them in order to tackle challenges of climate change in the digital era. Initially, the multivariate panel bootstrap Granger causality test is conducted to estimate the causal effects of LURB and INT on CEM in China. The results reveal that the interaction patterns among them varied across different provinces, and particularly LURB and INT are two determinants of CEM mainly in Eastern China, which is consistent with the stochastic differential model. Then, CEM is not a Granger-cause of LURB and INT in the majority of Chinese provinces, as LURB and INT largely depend on government policies and industrial development. In addition, there are no significant interactions between LURB and CEM in over two-thirds of the provinces and there are also none between INT and CEM in over half of the Chinese provinces. Therefore, Chinese policymakers should further adopt differentiated and efficient policies targeting the weak links and achieve environmental sustainability through low carbon transition.