In the present work, the composite MgAl-LDH/biochar using activated carbon from bovine bone as support for the layered double hydroxide particles was successfully synthesised and used as an alternative adsorbent for caffeine removal from water. Kinetic studies showed that the equilibrium was achieved in only 20 min of contact between the adsorbent and the adsorbate. The pseudo-first-order model represented the experimental data more satisfactorily (R² = 0.95), suggesting a physical adsorption process. The isotherms were performed at three temperatures, in which it was observed the decrease in the adsorption in higher temperatures. It was obtained a maximum adsorption capacity of 26.219 mg/g at 40 °C, and the experimental data were better adjusted by Redlich–Peterson, R² > 0.9942. In short, the study demonstrated that the composite was satisfactorily synthesised and its use in the caffeine removal was quite attractive, being a potential adsorbent for water treatment applications.

In recent decades, climate change and environmental pollution have been at the center of global environmental debates. Nowadays, researchers have turned their attention to the linkage between real output and environmental quality and test the environmental Kuznets curve. Majority of the studies focus on a single pollutant aspect and measure the deterioration of the environment through carbon emission (CO₂) only. In contrary, the current study uses a comprehensive proxy, ecological footprint, to measure the environmental quality of the sixteen Central and Eastern European Countries (CEECs). The aim of this paper is to discover the impact of financial development, economic growth, and energy consumption (renewable and non-renewable) on the environment. In addition, for the first time, the current study includes biocapacity and human capital in the growth–energy–environment nexus in the case of CEECs. In doing so, we used annual data of sixteen CEE countries in perspective of the One Belt One Road (OBOR) initiative and cover the period of 1991–2014. For reliable findings, this study focuses on second-generation econometric approaches to check stationarity, cross-sectional dependency, and co-integration among the model parameters. The long-run estimations of the “Dynamic Seemingly Unrelated-co-integration Regression” (DSUR) signify that the effect of economic growth on ecological footprint is not stable and validate N-shaped relationship for cubic functional form between per capita income and ecological footprint (environmental quality). Empirical evidence divulges that financial development and energy use significantly contribute to environmental degradation while renewable energy improves environmental quality by declining ecological footprint significantly. Moreover, the significant effects of biocapacity and human capital are positive and negative on the ecological footprint, respectively. In robustness check through the “Feasible Generalized Least Square” (FGLS) and “Generalized Method of Moment” (GMM) models, we found consistent result. Lastly, the “Dumitrescu-Hurlin (D-H) Panel Causality Test” demonstrates that two-way causal relationship exists between EF and GDP, EF and FD, EF and EU, EF and BC, and EF and HC, while one-way causality is running from RE to EF. This study puts the present scenario of CEE economies in front of the policymakers and suggests that they should consider the vital role of renewable energy and human capital to get sustainability.

Bioelectrochemical systems (BESs) including microbial electrolysis cells (MECs) and microbial fuel cells (MFCs) are promising for hexavalent chromium [Cr(VI)] reduction and total chromium (Cr) removal from wastewater. This study assessed the performance of simple, inexpensive, and continuous flow BESs with neither cathode catalyst nor proton exchange membrane for Cr(VI) reduction and total Cr removal. The effect of bioreactor configuration and wastewater feed mode on the performance of the BESs was investigated. Biological Cr(VI) reduction in the MEC followed a first-order kinetics with a rate constant of 0.103 d⁻¹, significantly higher than that of the control (0.033 d⁻¹). For comparison, the first-order reduction rate constants in the MFCs with the Cr(VI) fed to the anodic and the cathodic zones were 0.072 and 0.064 d⁻¹, respectively. The BESs improved total Cr removal through coprecipitating Cr(III) and phosphors as evidenced from the scanning electron microscopy energy-dispersive X-ray spectroscopy analysis. The total Cr removal efficiencies in the control, MFCs, and MEC were 26.1%, 56.7%, and 66.2%, respectively. Only 25.1% to 26.7% of total Cr was present intracellularly in the BESs (both MFCs and MEC), whereas 31.8% ± 1.4% and 38.0% ± 0.9% of total Cr in the anodic and cathodic zones of the control were present intracellularly. Overall, the BESs demonstrated a great potential to reduce Cr(VI) and remove total Cr with the MEC having the fastest Cr(VI) reduction and most efficient total Cr removal. Furthermore, the BESs significantly reduced the intracellular total Cr content.

Yeast biomass from ethanol industry (YB) was evaluated as a biosorbent to 17α-ethinylestradiol (EE) alone and along with estrone (EST). This material is rich in sorption sites and has a good cost-benefit ratio, since it is an industrial residue largely produced (around 30 g for each liter of ethanol). A 2ᵏ-factorial design was carried out to evaluate the sorption capacity of YB for EE considering the variables pH, biosorbent dose (BD), and ionic strength (IS), at two hormone concentration (HC) levels. The best conditions assessed for individual EE adsorption (pH = 10, IS = 0.1 mol/L, and BD = 0.5 mg/L) were also established for adsorption carried out in the presence of EST. Individuals EE and EST experimental sorption capacities (SCₑₓₚ) were, respectively, 24.50 ± 0.07 and 0.80 ± 0.07 mg/g, fairly similar to Qₘₐₓ (EE, 21.41 ± 1.27 mg/g; EST, 0.93 ± 0.075 mg/g) from Langmuir model. The Freundlich model best fitted the experimental data for EE adsorption (r² = 0.9925; χ² = 0.5575). The study carried out in the presence of EST showed an associative/competitive sorption process between EE and EST, which may be explained by their similar chemical structures and organic carbon-water partition coefficients Kₒc.

Placer gold mining is important anthropogenic sources of dust and metals that can strongly influence the environmental quality of the surrounding ecosystem. However, scarce studies have focused on evaluating the influence of placer gold mining on historical metal deposition in the surrounding ecosystem in the northern Great Hinggan Mountains, which is located at northeast of China. To address this research gap, four peatland cores with different distances to a gold placer in the northern Great Hinggan Mountains were selected in this study. Based on the ²¹⁰Pb depth-age model, historical variations in the Pb isotope and deposition fluxes of Pb, Cu, and Zn were reconstructed. The results show that metal deposition in the northern Great Hinggan Mountains was mainly influenced by the placer gold mining around the 1900s when the gold placer started to produce gold, and placer gold mining more seriously influenced the western sites that were closer to the placer gold mining. With increasing global metal productions after 1930, the proportion of the metals from placer gold mining sources gradually decreased, and part of Pb were transported via the atmosphere from other regions (e.g., Europe, East Asia). With the implementation of environmentally friendly policies and the decreasing anthropogenic production of Pb, Cu, and Zn around the world, deposition fluxes of these metals in the northern Great Hinggan Mountain began to decrease after 2000.

The effect of selenium on excessive fatty acid–induced apoptosis and abnormal amino acid metabolism in the liver is well known, because it is an important site in the fatty acid metabolism pathway. However, the protective role of nano-elemental selenium (nano-Se) supplementation against hexavalent chromium (K₂Cr₂O₇)–induced abnormal fatty acid metabolism has not been evaluated yet. Therefore, we conducted chicken experiments with different nano-Se supplementation doses to investigate the role of nano-Se against Cr(VI)-induced adverse effects. For this purpose, a total of 120 1-day-old chicks were randomly divided into control group, Cr(VI)-exposed group, protection group, treatment group, prevention group, and nano-Se control group. The results of RT-qPCR showed that the nano-Se supplementation notably downregulated (P < 0.01) the messenger RNA (mRNA) expression levels of fatty acid synthase (FASN), whereas nano-Se supplementation significantly upregulated (P < 0.01) the mRNA expression level of acyl-coenzyme A oxidase 1 (ACOX1) in chicken’s liver at day 35 of the experiment. Similar results were further verified by western blot analysis. Moreover, nano-Se supplementation significantly enhanced and reduced the antibody expression levels of ACOX1 and FASN in immunohistochemical analysis, respectively. Thus, finally, it was concluded that nano-Se can alleviate K₂Cr₂O₇-induced abnormal fatty acid metabolism in chicken’s liver.

Exposure to pesticides is a major factor in the cause of dysfunction in the nervous system and neurodevelopment disorders in children at critical periods of great vulnerability. The aim of this study was to review scientific evidence published on neurodevelopmental effects of prenatal and postnatal exposure to organophosphate pesticides (OPs) in different stages, including neonates, infants, toddlers, preschool children, and school-age children. Full-text articles published in PubMed, Scopus, and ISI databases between 1973 and 2019 were reviewed and the scientific evidence was evaluated. Results: Fifty studies were eligible for inclusion in this quantitative synthesis. Fifteen of these papers evaluated the effects on neonates and infants, 18 on the effects on toddlers and preschool children, and 24 the effects on school-age children. Considerable evidence suggests that prenatal exposure to OPs contributes to child neurodevelopment disorders in all stages, whereas data about the effects of postnatal exposure are limited. Therefore, the available evidence supports the theory that sensitive time-windows occur prenatally rather than postnatally. Although 45 out of the total 50 selected articles found an association between OP exposure and child neurodevelopment, some of the evidence is controversial. A standardized methodology is needed to enable the comparison of the results in several studies, and further research studies are needed to warrant firmer conclusions. A systematic review of this evidence should be performed continuously to update the state of knowledge regarding neurodevelopmental effects associated with OP exposure.

The present study investigated PM₁ (aerosol particles with an aerodynamic diameter ≤ 1.0 μm) mass concentrations and sixteen (Al, Ca, Cd, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, S, Ti, and Zn) PM₁-related trace elements. PM₁ samples were collected in an anthropized area of international attention close to oil/gas pre-treatment plants in Agri Valley (Southern Italy). The PM₁ mass concentrations varied from 3 to 16 μg/m³. The decreasing pattern of the trace element concentrations was S > Ca > Na > K ≈ Mg ≈ Fe> Al > Li > Cr > Zn > Ti> Cu > Ni ≈ Mn > Pb ≈ Cd. Anthropogenic local emissions such as biomass burning, vehicular traffic, and industrial sources mainly related to oil/gas pre-treatment plants were identified by the principal component analysis. Further, air mass back-trajectory analyses suggest an important contribute to the long-range transport on PM₁ at Agri Valley. The carcinogenic (Cd, Cr(VI), Ni, and Pb) and non-carcinogenic (Cd, Cr(VI), Cu, Mn, Ni, Pb, and Zn) health risks both for children and for adults were assessed using the United State Environmental Protection Agency (USEPA) methods considering inhalation, ingestion, and dermal contact pathway. Chromium (VI) posed the highest carcinogenic risk for both children and adults. The integrated carcinogenic risks were respectively 3.45 × 10⁻⁵ and 1.38 × 10⁻⁴ for children and adults indicating that attention should be paid for carcinogenic health effects. Nickel posed the highest non-carcinogenic risk for children through inhalation pathway. The integrated non-carcinogenic risk showed a value higher than 1 highlighting that Cd, Cr(VI), Cu, Mn, Ni, Pb, and Zn may cause cumulative non-carcinogenic health effect for children from inhalation exposure.

Layered combined bio-ceramic, zeolite, and anthracite were used as substrates in vertical-flow constructed wetlands (VFCWs) for enhancing contaminant removal from synthetic municipal wastewater. Plant growth and propagation and the removal of organic matter, nitrogen, and phosphorus as well as its spatiotemporal variation were evaluated systematically. The results demonstrated that three different substrates were adequate for the establishment of Canna indica L., especially for zeolite. All small-scale VFCW units were simultaneous efficient in removing CODCᵣ (73.9–78.7%), NH₄⁺-N (83.8–89.9%), TN (88.3–91.5%), SRP (93.8–98.6%), and TP (87.1–90.9%) with a little significant difference on treatment performance. Different pollution removal processes followed a different trend because of their different removal mechanisms driven by the synergy of substrate, plant, and microorganism. Purification space moved down due to the adsorption capacity consumption of upper layer substrate over time. It was concluded that VFCWs filled with layered combined bio-ceramic, zeolite, and anthracite had great potential for treating municipal wastewater.

We know very little about the effects of two global stressors, elevated temperature and contaminants, on the grazing of marine copepods. To address this issue, we tested the hypotheses that the individual and combined effects of these two stressors may reduce grazing rates and may depend on food availability and gender. We exposed male and female Calanus finmarchicus copepods to pyrene at two temperatures (10 and 14 °C) and six food concentrations (25–800 μg C Rhodomonas baltica L⁻¹) and measured fecal pellet size, and grazing rate (GR) from pellet production. Males had smaller fecal pellets and lower GR than did females. Temperature and pyrene exposure had no effect on pellet size. Temperature alone had no effect on GR of males, but females had lower GR at elevated temperature. Pyrene-exposed males and females had lower GR only at the food concentrations of 200–800 μg C R. baltica L⁻¹ and those patterns were independent of temperature. Pyrene-induced reduction in GR was stronger in females than in males. The negative effects of both elevated temperature and pyrene may reduce the abundance and trophic success of C. finmarchicus in a warmer, more polluted future.