Haze pollution is one of the most concerning environmental issues, and controlling haze pollution without affecting economic development is of immense significance. Using the panel data composed of PM₂.₅ concentration and other data from 278 cities in China between 2003 and 2016, this paper empirically investigates the impact of urban innovation on haze pollution and its transmission mechanism. Based on the fixed effect model, the research finds that increasing urban innovation significantly reduces haze pollution. Even after dealing with possible endogenous problems, the result still holds. Energy consumption and industrial agglomeration are two important transmission channels through which urban innovation affects haze pollution. Furthermore, time heterogeneity analysis shows that the negative effect of urban innovation on haze pollution increases with time. Spatial heterogeneity analysis shows that urban innovation has a more significant mitigation effect on haze pollution in eastern cities than in central and western cities in China. This paper indicates that technological innovation, as the main driving force for development, can provide vital support to China to improve the ecological environment.

Atmospheric CO₂ source and sink is among the most debated issues that have puzzled climate change geochemist for decades. Here, we tested whether heavy metal pollutants in river sediments favor preservation of organic matter through shielding microbial degradation. We measured CO₂ emission and extracellular enzyme activities at land-water interface (LWI) of 7 sites along a 285 km main stem of the Ganga River and 60 locations up- and downstream of two contrasting point sources discharging urban (Assi drain; Asdr) and industrial (Ramnagar drain; Rmdr) wastewaters to the river. We found the lowest CO₂ flux at Rmdr mouth characterized by the highest concentrations of Cu, Cr, Zn, Pb, Ni, and Cd. The fluxes were relatively higher at locations up- and downstream Rmdr. Substrate induced respiration (SIR), protease, FDAase, and β-D-glucosidase all showed a similar trend, but phenol oxidase and alkaline phosphatase showed opposite trend at the main river stem and Asdr. Sites rich in terrestrially derived organic matter have high phenol oxidase activity with low CO₂ emission. The CO₂ emission in the main river stem showed curvilinear relationships with total heavy metals (∑THM; R² = 0.68; p < 0.001) and TOC (R² = 0.65; p < 0.001). The dynamic fit model of main stem data showed that the ∑THM above 337.4 µg g⁻¹ were able to significantly decrease the activities of protease, FDAase, and β-D-glucosidase. The study has implications for understanding C-cycling in human-impacted river sediments where metal pollution shields microbial degradation consequently carbon and nutrient release and merits attention towards river management decisions.

The present study reports on the synthesis of Cu-bismuth oxide (CuBi₂O₄)–based nanorods by using a simple co-precipitation method for the photocatalytic degradation of caffeic acid (CA). The incorporation of Cu metal ions during the synthesis of CuBi₂O₄ nanorods might be advantageous to avoid the aggregation and control the leach out of metal ions. The calculated bandgap values of ~ 1.04, 1.02, and 0.94 eV were observed for CuBi₂O₄ with different amounts of Cu 1.0, 0.50, and 0.25 g, respectively. Varying the quantity of Cu metal ions easily tuned the bandgap value within the CuBi₂O₄-based nanorods. However, a further decrease in the bandgap value increased the recombination rate, and the less photocatalyst performance was observed. The CA degradation could be explained based on the species distribution. The CA pKa was mainly located between pKa₁ and pKa₂ of 4.43 and 8.6, respectively. The Cu within the CuBi₂O₄-based nanorods changed the electronic properties and the antibacterial ability. Therefore, the synthesized CuBi₂O₄-based nanorod cluster might be a promising material for the photocatalytic degradation of CA.

Mangroves are among the world's most productive ecosystems and a part of the “blue carbon” sink. They act as a connection between the terrestrial and marine ecosystems, providing habitat to countless organisms. Among these, microorganisms (e.g., bacteria, archaea, fungi, phytoplankton, and protozoa) play a crucial role in this ecosystem. Microbial cycling of major nutrients (carbon, nitrogen, phosphorus, and sulfur) helps maintain the high productivity of this ecosystem. However, mangrove ecosystems are being disturbed by the increasing concentration of greenhouse gases within the atmosphere. Both the anthropogenic and natural factors contribute to the upsurge of greenhouse gas concentration, resulting in global warming. Changing climate due to global warming and the increasing rate of human interferences such as pollution and deforestation are significant concerns for the mangrove ecosystem. Mangroves are susceptible to such environmental perturbations. Global warming, human interventions, and its consequences are destroying the ecosystem, and the dreadful impacts are experienced worldwide. Therefore, the conservation of mangrove ecosystems is necessary for protecting them from the changing environment—a step toward preserving the globe for better living. This review highlights the importance of mangroves and their microbial components on a global scale and the degree of vulnerability of the ecosystems toward anthropic and climate change factors. The future scenario of the mangrove ecosystem and the resilience of plants and microbes have also been discussed.

To clarify the chemical characteristics, source contributions, and health risks of pollution events associated with high PM₂.₅ in typical industrial areas of North China, manual sampling and analysis of PM₂.₅ were conducted in the spring, summer, autumn, and winter of 2019 in Pingyin County, Jinan City, Shandong Province. The results showed that the total concentration of 29 components in PM₂.₅ was 53.4 ± 43.9 μg·m⁻³, including OC/EC, water-soluble ions, inorganic elements, and metal elements. The largest contribution was from the NO₃⁻ ion, at 14.6 ± 14.2 μg·m⁻³, followed by organic carbon (OC), SO₄²⁻, and NH₄⁺, with concentrations of 9.3 ± 5.5, 9.1 ± 6.4, and 8.1 ± 6.8 μg·m⁻³, respectively. The concentrations of OC, NO₃⁻, and SO₄²⁻ were highest in winter and lowest in summer, whereas the NH₄⁺ concentration was highest in winter and lowest in spring. Typical heavy metals had higher concentrations in autumn and winter, and lower concentrations in spring and summer. The annual average sulfur oxidation rate (SOR) and nitrogen oxidation rate (NOR) were 0.30 ± 0.14 and 0.21 ± 0.12, respectively, with the highest SO₂ emission and conversion rates in winter, resulting in the SO₄²⁻ concentration being highest in winter. The average concentration of secondary organic carbon in 2019 was 2.8 ± 1.9 μg·m⁻³, and it comprised approximately 30% of total OC. The concentrations of 18 elements including Na, Mg, and Al were between 2.3 ± 1.6 and 888.1 ± 415.2 ng·m⁻³, with Ni having the lowest concentration and K the highest. The health risk assessment for typical heavy metals showed that Pb poses a potential carcinogenic risk for adults, whereas As may pose a carcinogenic risk for adults, children, and adolescents. The non-carcinogenic risk coefficients for all heavy metals were lower than 1.0, indicating that the non-carcinogenic risk was negligible. Positive matrix factorization analysis indicated that coal-burning emissions contributed the largest fraction of PM₂.₅, accounting for 35.9% of the total. The contribution of automotive emissions is similar to that of coal, at 32.1%. The third-largest contributor was industrial sources, which accounted for 17.2%. The contributions of dust and other emissions sources to PM₂.₅ were 8.4% and 6.4%, respectively. This study provides reference data for policymakers to improve the air quality in the NCP.

Methane (CH₄) emissions from reservoirs have received widespread attention. The central urban area of Chongqing in the Three Gorges Reservoir area was selected as the study area in 2020. The temporal and spatial distribution of dissolved CH₄ concentration and flux, key generation pathways, and influencing factors have been studied. The dissolved CH₄ concentration in low-water-level period and impoundment period varied from 0.037~0.12 μmol·L⁻¹ and 0.11~0.23 μmol·L⁻¹, with the average values of (0.066 ± 0.0067) μmol·L⁻¹ and (0.13 ± 0.034) μmol·L⁻¹. The CH₄ flux was (0.941 ± 0.217) μmol·m⁻²·h⁻¹ in low-water-level period and (1.915 ± 0.204) μmol·m⁻²·h⁻¹ in impoundment period. CH₄ was produced by CO₂ reduction and acetic acid fermentation, accounting for 17.95% and 82.05% of the total CH₄ production, respectively. The dissolved CH₄ concentration was significantly positively correlated with DO and NO₃⁻-N, and it is opposite with dissolved inorganic carbon. The dissolved CH₄ concentration in this study area is affected by water environment (33.42%), inorganic nitrogen (29.60%), organic carbon (23.88%), and inorganic carbon (13.10%), and anthropogenic influences promoted dissolved CH₄ concentration.

The catalytic production of bio-oil can potentially solve the impending fossil fuel depletion crisis. Two practical problems related to bio-oil are the yield and quality, which are determined by the catalyst. Until recently, little work has focused on the relationship between biomass, catalyst, yield, and quality. To cover this deficiency, this work reviews the influence of metal oxides and zeolites on the yields and qualities of bio-oil derived from woody, herbaceous, agricultural, and algae biomasses. Generally, both catalysts decreased the yield and increased the quality at the same time, and more acidic catalysts decreased the yield further. Thus, zeolites usually decreased the yield more than metal oxides. Although the quality was increased, the oxygen content and calorific value were both increased, which favored further applications. Wood biomass had a lower ash content and nitrogen content than herbaceous, agricultural, and algae biomasses, simultaneously resulting in better yield and quality. This review helps understand the current status of bio-oil investigations and can help find new research directions in the future.

Coronavirus disease 2019 (COVID-19) is a rapidly growing pandemic that requires urgent therapeutic intervention. Finding potential anti COVID-19 drugs aside from approved vaccines is progressively going on. The chemically diverse natural products represent valuable sources for drug leads. In this study, we aimed to find out safe and effective COVID-19 protease inhibitors from a library of natural products which share the main nucleus/skeleton of FDA-approved drugs that were employed in COVID-19 treatment guidelines or repurposed by previous studies. Our library was subjected to virtual screening against SARS-CoV Main protease (Mpro) using Molecular Operating Environment (MOE) software. Twenty-two out of those natural candidates showed higher binding scores compared to their analogues. We repurpose these natural products including alkaloids, glucosinolates, and phenolics as potential platforms for the development of anti-SARS-CoV-2 therapeutics. This study paves the way towards discovering a lead used in the treatment of COVID-19 from natural sources and introduces phytomedicines with dual therapeutic effects against COVID-19 besides their original pharmacological effects. We recommend further in vitro evaluation of their anti-COVID-19 activity and future clinical studies.

Although the development and application of nanomaterials is a growing industry, little data is available on the ecotoxicological effects on aquatic organisms. Therefore, we set up a workflow to address the potential uptake of weathered multi-walled carbon nanotubes (wMWCNTs) by a model organism, the pulmonary mud snail Lymnaea stagnalis (L. stagnalis), which plays an important role in the food web. It represents a suitable organism for this approach because as a grazer it potentially ingests large amounts of sedimented wMWCNTs. As food source for L. stagnalis, benthic biofilm was investigated by the use of a transmission electron microscope (TEM) and a scanning electron microscope (SEM) after exposure with wMWCNTs. In addition, isotopic labeling was applied with ¹⁴C-wMWCNTs (0.1 mg/L) to quantify fate, behavior, and enrichment of ¹⁴C-wMWCNTs in benthic biofilm and in L. stagnalis. Enrichment in benthic biofilm amounted to 529.0 µg wMWCNTs/g dry weight and in L. stagnalis to 79.6 µg wMWCNTs/g dry weight. A bioconcentration factor (BCF) for L. stagnalis was calculated (3500 L/kg). We demonstrate the accumulation of wMWCNTs (10 mg/L) in the digestive tract of L. stagnalis in an effect study. Moreover, the physiological markers glycogen and triglycerides as indicators for the physiological state, as well as the RNA/DNA ratio as growth indicator, were examined. No significant differences between exposed and control animals were analyzed for glycogen and triglycerides after 24 days of exposure, but a decreasing trend is recognizable for triglycerides. In contrast, the significant reduction in the RNA/DNA ratio of L. stagnalis indicated an inhibition of growth with a following recovery after depuration. The described workflow enables a comprehensive determination of the fate and the behavior of wMWCNTs specifically and in general all kinds of CNTs in the aquatic environment and therefore contributes to a holistic risk assessment of wMWCNTs.

The Douhe Reservoir is an important diversion water source and drinking water resource for Tianjin and the Tangshan cities. Panjiakou, Daheiting, Qiuzhuang, and the Douhe Reservoirs located from top to bottom in the LuanHe River region forming a group of cascade reservoirs. After over 30 years of aquaculture, the concentration of nitrogen (N) and phosphorus (P) have exceeded Class III of Environmental Quality Standard for Surface Water in China. We selected the Douhe Reservoir as the study site and choose sampling points in several upstream reservoirs and main reservoir area, and we collected a total of 18 water samples. Moreover, the distribution characteristics of N and P levels in flood season and dry season were studied in the Douhe Reservoir and upstream water channel, respectively. The results indicated that there were significant spatial differences between N and P distribution in the Douhe Reservoir and the upstream sites. We observed that the distribution of N and P had seasonal characteristics, and the contents of nitrate(NO3⁻-N), nitrogen(TN), total phosphorus(TP), and total dissolved phosphorus(TDP) in flood periods were higher than those in dry periods. The microbial community structure illustrated that the dominant phylum displayed seasonal differences between the upstream channel and the reservoir area. Among them, the abundance of some genera changed with the location of the channel, the microbial community structure, and the levels of N and P, especially in flood season. Particularly, NO₃⁻-N and TN had the most significant correlation. Hence, this study presented an important theoretical foundation for the risk prevention and the control of nutrient elements in the LuanHe River basin in the future, which would enhance the drinking water safety of Tianjin and Tangshan residents.