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GC–ITMS analysis of PAH contamination levels in the marine sea urchin Paracentrotus lividus in Sardinia
2014
Angioni, Alberto | Cau, Alessandro | Secci, Marco | Addis, Piero
This paper describes the results of a two-year monitoring study examining the pollution of the sea urchin Paracentrotus lividus by polycyclic aromatic hydrocarbons (PAHs) in Sardinia. GC–ITMS analysis of sea urchin gonads showed the presence of 11 and 12 PAHs in the samples of Capo Pecora, and Capitana, respectively. Fluorene, naphthalene and its two degradation products, 1-methyl-naphthalene, and 2-methyl-naphthalene, were detected in all samples analyzed. The ΣPAH residues showed a similar trend over the two-year sampling period. Furthermore, the residues in the first year were slightly higher than in the second year. The information obtained by the multivariate statistical analysis PLS-DA allowed for the determination of samples based on field site and varying habitat types (rocky reef, and Posidonia seabed). The results of this study showed that Posidonia sea urchins are contaminated by high molecular weight PAHs and that Capitana samples are more contaminated due to a higher level of human activity in the area.
Mostrar más [+] Menos [-]The mass concentration and optical properties of black carbon aerosols over a semi–arid region in the northwest of China
2014
Black Carbon (BC) is the predominant absorption component of atmospheric aerosols, and it is believed to be the second largest contributor to global warming. Calculating its radiative forcing requires observational data regarding its physical, chemical and optical properties, so observation is the foundation of this research. The Semi–Arid Climate and Environment Observatory of Lanzhou University aims to improve our understanding in this regard by capturing direct evidence of the impact of human activity on the semi–arid climate over the Loess Plateau of Northwestern China. In this paper, the period from November 2010 to February 2011, which is within the heating period, was selected in order to study the optical properties of BC, such as its depolarization ratio, extinction coefficient, optical depth, Ångström exponent and effective radius. The average BC concentration was 2 334±1 546ng/m3 during the observation. The diurnal evolution of BC concentration had two maximums, which appeared at 10:00 and 20:00 (local time), and two minimums, which appeared at 03:00 and 16:00. The average Aerosol Optical Depth (AOD) during the observation was 0.26±0.2, the aerosols existed mostly between the surface of the Earth and a height of 3km, and the extinction coefficient decreased with height. The average of the depolarization ratio between the surface of the Earth and a height of 3km, the Ångström exponent (α440/870nm) and the effective radius of black carbon aerosols were 0.24, 0.86±0.30 and 0.54±0.17μm, respectively. The maximum distribution frequency of α440/870nm was 27%, with a range of 1.0 to 1.2. The maximum distribution frequency of the effective radius was 28%, with a range of 0.4μm to 0.5μm.
Mostrar más [+] Menos [-]Radioactivity concentrations in mussel (Mytilus galloprovincialis) of Turkish Sea coast and contribution of 210Po to the radiation dose
2014
Kılıç, Önder | Belivermiş, Murat | Çotuk, Yavuz | Topçuoğlu, Sayhan
Radionuclides levels were determined in indigenous and transplanted mussels (Mytilus galloprovincialis) collected from Turkish marine environment. Radioactivity concentrations of 137Cs, 40K, 226Ra, 228Ra, 210Po and 210Pb were determined in the soft tissues of the mussel samples collected in Bosphorus Strait, Coasts of Black Sea, Marmara Sea and Aegean Sea. Mussel transplantation was carried out by using mussel cages in Levantine Sea coast since M. galloprovincialis did not naturally adapt along the coast. The average activity concentrations of 137Cs, 40K, 226Ra, 228Ra, 210Po and 210Pb in the coastline of Turkey were found to be 0.7±0.1, 469±24, 0.9±0.1, 1.0±0.1, 122±4 and 10.9±0.9Bqkg−1 in dry weight (dw), respectively. The average of 210Po/210Pb ratio was found to be ∼14. Total annual effective 210Po dose was calculated to be in the range of 0.25–3.30 μSv due to mussel consumption. Radioactivity and dose levels were compared with those of similar studies carried out in Mediterranean countries.
Mostrar más [+] Menos [-]Mercury in the food chain of the Lagoon of Venice, Italy
2014
Sediments and biota samples were collected in a restricted area of the Lagoon of Venice and analysed for total mercury, monomethyl mercury (MMHg), and nitrogen and carbon isotopes. Results were used to examine mercury biomagnification in a complex food chain. Sedimentary organic matter (SOM) proved to be a major source of nutrients and mercury to primary consumers. Contrary to inorganic mercury, MMHg was strongly biomagnified along the food chain, although the lognormal relationship between MMHg and δ15N was less constrained than generally reported from lakes or coastal marine ecosystems. The relationship improved when logMMHg concentrations were plotted against trophic positions derived from baseline δ15N estimate for primary consumers. From the regression slope a mean MMHg trophic magnification factor of 10 was obtained. Filter-feeding benthic bivalves accumulated more MMHg than other primary consumers and were probably important in MMHg transfer from sediments to higher levels of the food chain.
Mostrar más [+] Menos [-]Microplastic pollution in the Northeast Atlantic Ocean: Validated and opportunistic sampling
2014
Levels of marine debris, including microplastics, are largely un-documented in the Northeast Atlantic Ocean. Broad scale monitoring efforts are required to understand the distribution, abundance and ecological implications of microplastic pollution. A method of continuous sampling was developed to be conducted in conjunction with a wide range of vessel operations to maximise vessel time. Transects covering a total of 12,700km were sampled through continuous monitoring of open ocean sub-surface water resulting in 470 samples. Items classified as potential plastics were identified in 94% of samples. A total of 2315particles were identified, 89% were less than 5mm in length classifying them as microplastics. Average plastic abundance in the Northeast Atlantic was calculated as 2.46particlesm−3. This is the first report to demonstrate the ubiquitous nature of microplastic pollution in the Northeast Atlantic Ocean and to present a potential method for standardised monitoring of microplastic pollution.
Mostrar más [+] Menos [-]Carbonyl concentrations from sites affected by emission from different fuels and vehicles
2014
Concentrations of carbonyl compounds were evaluated on places impacted by emissions from different fuels and vehicles. In order to evaluate the concentrations, four campaigns during the winter and summer of 2011 and 2012 were performed, inside a covered parking area in a commercial establishment where mainly gasohol and ethanol vehicles are in circulation. Also, measurements were done inside a semi–closed bus station, which is the direct source of emissions from heavy duty vehicles (i.e. buses) burning B3–diesel (3% biodiesel and 97% diesel). The results indicated that acetaldehyde is the main aldehyde emitted by light vehicles due to large use of ethanol in Brazil by these vehicles. In addition, the concentrations found in the bus station revealed that B3–diesel fuel increases the emissions of carbonyl compounds and that of acetaldehyde when compared with results from B0–diesel at same bus station. Possible impacts of changing diesel to B3–diesel indicate an increase of ozone formation. In terms of health, a lower impact was estimated considering only the changes in formaldehyde concentrations.
Mostrar más [+] Menos [-]Marine litter in Mediterranean sandy littorals: Spatial distribution patterns along central Italy coastal dunes
2014
Poeta, Gianluca | Battisti, Corrado | Acosta, Alicia T.R.
Sandy shores are generally considered important sinks for marine litter and the presence of this litter may represent a serious threat to biotic communities and dune integrity mostly due to cleaning activities carried out through mechanical equipment. In spring (April–May) 2012 we sampled 153 2×2m random plots to assess the spatial distribution patterns of litter on Central Italy sandy shores. We analysed the relationship between the presence of litter and coastal dune habitats along the sea-inland gradient. Our results showed that the most frequent litter items were plastic and polystyrene. Differences of marine litter spatial distribution were found between upper beach and fore dune habitats and fixed dune habitats: embryo dune and mobile dune habitats show the highest frequency of litter, but, surprisingly, marine litter did not impact fixed dune habitats, these possibly acting as a natural barrier protecting the inner part of the coast from marine litter dispersion.
Mostrar más [+] Menos [-]Eutrophication threatens Caribbean seagrasses – An example from Curaçao and Bonaire
2014
Govers, Laura L. | Lamers, Leon P.M. | Bouma, Tjeerd J. | de Brouwer, Jan H.F. | van Katwijk, Marieke M.
Seagrass beds are globally declining due to human activities in coastal areas. We here aimed to identify threats from eutrophication to the valuable seagrass beds of Curaçao and Bonaire in the Caribbean, which function as nursery habitats for commercial fish species. We documented surface- and porewater nutrient concentrations, and seagrass nutrient concentrations in 6 bays varying in nutrient loads. Water measurements only provided a momentary snapshot, due to timing, tidal stage, etc., but Thalassia testudinum nutrient concentrations indicated long-term nutrient loads. Nutrient levels in most bays did not raise any concern, but high leaf % P values of Thalassia in Piscadera Bay (∼0.31%) and Spanish Water Bay (∼0.21%) showed that seagrasses may be threatened by eutrophication, due to emergency overflow of waste water and coastal housing. We thus showed that seagrasses may be threatened and measures should be taken to prevent loss of these important nursery areas due to eutrophication.
Mostrar más [+] Menos [-]Deep-sea faunal communities associated with a lost intermodal shipping container in the Monterey Bay National Marine Sanctuary, CA
2014
Taylor, Josi R. | DeVogelaere, Andrew P. | Burton, Erica Janis | Frey, Oren | Lundsten, Lonny | Kuhnz, Linda Ann | Whaling, P.J. | Lovera, Christopher | Buck, Kurt R. | Barry, James P.
Carrying assorted cargo and covered with paints of varying toxicity, lost intermodal containers may take centuries to degrade on the deep seafloor. In June 2004, scientists from Monterey Bay Aquarium Research Institute (MBARI) discovered a recently lost container during a Remotely Operated Vehicle (ROV) dive on a sediment-covered seabed at 1281m depth in Monterey Bay National Marine Sanctuary (MBNMS). The site was revisited by ROV in March 2011. Analyses of sediment samples and high-definition video indicate that faunal assemblages on the container’s exterior and the seabed within 10m of the container differed significantly from those up to 500m. The container surface provides hard substratum for colonization by taxa typically found in rocky habitats. However, some key taxa that dominate rocky areas were absent or rare on the container, perhaps related to its potential toxicity or limited time for colonization and growth. Ecological effects appear to be restricted to the container surface and the benthos within ∼10m.
Mostrar más [+] Menos [-]Small-scale early aggregation of green tide macroalgae observed on the Subei Bank, Yellow Sea
2014
Hu, Song | Yang, Hong | Zhang, Jianheng | Chen, Changsheng | He, Peimin
Massive green algae blooms became an environmental disaster in the Yellow Sea from 2008 to 2013. Recent studies suggested that recurrences of early aggregates of macroalgae were found over the Subei Bank, a unique shallow radial sand ridge system off the Jiangsu coast, China. Yearly field surveys have been carried out over this bank during the past five years (2009–2013), with an aim at identifying and qualifying the physical–biological mechanism for the early aggregation of algae. Data synthesis showed that early aggregation of macroalgae usually occurred from April–May as small-scale patches either over the intertidal mudflat of the Subei Bank or along local isobaths in the northern coastal area north of the bank. Both hydrographic and current measurements were performed by tracking a narrow patchy area of floating macroalgae (nearly 4km in length and 5–10m in width) on April 26, 2013, and the results showed that the algae aggregation was mainly caused by tide-induced convergence. This convergence was produced by the local geometrically controlled interaction of tidal currents with mudflats, which is believed to be a key physical mechanism for the early development of algal blooms in addition to marine ecosystem responses and human aquaculture activities.
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