Critical periods (CPs) and critical source areas (CSAs) refer to the high-risk periods and areas of nonpoint source (NPS) pollution in a watershed, respectively, and they play a significant role in NPS pollution control. The upstream Daning River Basin is a typical watershed in the Three Gorges Reservoir area. In this study, a Hydrological Simulation Program-Fortran (HSPF) model was used to simulate phosphorus loss in the upstream Daning River Basin. Co-analysis of critical periods and critical source areas (CACC) is a quantitative collaborative analysis method for the identification of CSAs in CPs, and it was used to classify the periods and areas of NPS pollution as CPs, sub-CPs, non-CPs, CSAs, and non-CSAs. The CPs occurred in months 5–7 and accounted for 53.7% of the total phosphorus (TP) loads, and the sub-CPs occurred in months 1, 3, 4, and 8 and accounted for 29.2% of the TP loads. In CSAs, 49.4% of the TP loads occurred in 26.8% of the basin. Furthermore, we proposed the following multilevel priority control measure for NPS pollution in the upstream Daning River Basin: CSAs in CPs (with load-area rate of 1.4), CSAs in sub-CPs (0.7), CSAs in non-CPs (0.4), non-CSAs in CPs (0.3), non-CSAs in sub-CPs (0.2), and non-CSAs in non-CPs (0.1). CSAs in CPs accounted for 25.8% of the TP loads from 19.0% of the areas in only 3 months while 49.4% of the TP loads from similar areas over an entire year. These findings indicated that the CSAs in CPs located in farmland along the Daning, Dongxi, and Houxi Rivers should be prioritized for pollution management measures.

Total suspended particles (TSP) were collected in Lumbini from April 2013 to March 2016 to better understand the characteristics of carbonaceous aerosol (CA) concentrations, compositions and sources and their light absorption properties in rural region of severe polluted Indo-Gangetic Plain (IGP). Extremely high TSP (203.9 ± 109.6 μg m⁻³), organic carbon (OC 32.1 ± 21.7 μg m⁻³), elemental carbon (EC 6.44 ± 3.17 μg m⁻³) concentrations were observed in Lumbini particularly during winter and post-monsoon seasons, reflecting the combined influences of emission sources and weather conditions. SO₄²⁻ (7.34 ± 4.39 μg m⁻³) and Ca²⁺ (5.46 ± 5.20 μg m⁻³) were the most dominant anion and cation in TSP. These components were comparable to those observed in urban areas in South and East Asia but significantly higher than those in remote regions over the Himalayas and Tibetan Plateau, suggesting severe air pollution in the study region. Various combustion activities including industry, vehicle emission, and biomass burning are the main reasons for high pollutant concentrations. The variation of OC/EC ratio further suggested that biomass such as agro-residue burning contributed a lot for CA, particularly during the non-monsoon season. The average mass absorption cross-section of EC (MACEC) and water-soluble organic carbon (MACWSOC) were 7.58 ± 3.39 and 1.52 ± 0.41 m² g⁻¹, respectively, indicating that CA in Lumbini was mainly affected by local emissions. Increased biomass burning decreased MACEC; whereas, it could result in high MACWSOC during the non-monsoon season. Furthermore, dust is one important factor causing higher MACWSOC during the pre-monsoon season.

Montmorillonite-cysteine could be used as the immobilizer, detector, and detoxifier of heavy metals. To further the understanding and the application, the interaction between the montmorillonite and cysteine and the adsorption of cysteine on montmorillonite and characterization of the composites need to be studied further. In present work, the effects of pH, contact time and initial concentration of cysteine on the adsorption, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and Cd(II) adsorption on the composites were conducted to characterize the composites synthesized at different pH conditions. The results showed that the adsorption amount of cysteine on montmorillonite decreased with the increase of pH in the range of 2.4–8.0, reached equilibrium in about 1 min and increased with the initial concentration of cysteine and reached the maximum at 160 mg/g. The adsorption data fitted with Langmuir better than Freundlich, fitted with first-order and second-order better than the intraparticle diffusion model. XRD patterns and FTIR spectra showed that the interlayer spacing of the composite synthesized in the range of pH 2.4–4.3 was larger than that at pH 4.5–8.0 and the bonding of cysteine and montmorillonite mainly depended on the action of the amino group. Adsorption of Cd(II) on composites indicated more cysteine loaded (pH < 4.5) composite had greater capacity for Cd(II). The above results demonstrated that the composite synthesized under lower pH could retain more active cysteine, which might be beneficial to its various applications.

Phytoremediation potential of duckweeds (Lemna minuta, Lemna minor) to remove nutrients from simulated wastewater was analyzed. In two separate experiments, the two species were grown for 28 days in waters enriched with nitrate and phosphate to simulate nutrient concentrations of domestic wastewater. Water physical and chemical measurements (temperature, pH, conductivity, oxygen) and plant physiological and biochemical analysis (biomass, relative growth rate–RGR, nutrient and chlorophyll contents, peroxidative damage, bioconcentration factor–BCF) were made to test and compare the phytoremediation capacity of the two Lemna species. L. minuta biomass increased almost tenfold during the time-course of the treatment resulting in a doubling of the mat thickness and a RGR of 0.083 ± 0.001 g/g day. Maximum frond content of phosphate was reached by day 21 (increase over 165%) and nitrate by day 7 (10%). According to the BCF results (BCF > 1000), L. minuta was a hyperaccumulator for both nutrients. On the other hand, L. minor biomass and mat thickness decreased continuously during incubation (RGR = − 0.039 ± 0.004 g/g day). In L. minor fronds, phosphate content increased until day 14, after which there was a decrease until the end of the incubation. Frond nitrate content significantly decreased by day 7, but then remained relatively constant until the end of the experiment. L. minor proved to be hyperaccumulator for phosphates, but not for nitrates. Results indicated L. minuta has a greater potential than L. minor to remove both nutrients by bioaccumulation, especially phosphates, demonstrated also by better physiological and biochemical responses. However, during the incubation, the chlorophyll content of L. minuta mat did continuously decrease and peroxidative damage had increased until day 14, indicating that the system was under some kind of stress. Strategies to avoid this stress were discussed.

Phosphorus reuse by application of biochar is a recent concept that needs to be supported by long-term field data. To monitor biochar’s long-term effects on P turnover, one-off biochar was applied in 2013 with mineral NPK fertilizers being applied every year since then. Biochar application rates included 0 t ha⁻¹ (CK), 15.75 t ha⁻¹ (BC1), 31.5 t ha⁻¹ (BC2), and 47.25 t ha⁻¹ (BC3). Over the 5 years’ field experiment, P distribution in soil profile, inorganic and organic P fractions in bulk, and rhizosphere soil and maize P uptake were determined. The results showed that biochar reduced the inorganic P fractions (Ca₂-P, Ca₈-P, Al-P, Fe-P and O-P by 4.8–33.7%, 8.8–59.0%, 13.7–28.6%, 8.4–17.6%, and 3.3–25.5%, respectively), and increased organic P fractions (MLOP and HROP by 67.2–11.6% and 18.8–87.7%, respectively) in bulk soil, while in rhizosphere soil, Fe-P and MLOP were decreased by 13.4–34.5% and 67.2–111.6%, respectively, in 2017. After the application of biochar for 5 years, moderately labile organic phosphorus (MLOP), moderately resistant organic phosphorus (MROP), and highly resistant organic phosphorus (HROP) with different biochar treatments were enhanced by 12.8–42.7%, 20.1–48.0%, and 5.5–66.6%, respectively, but Ca₈-P, Al-P, O-P, and Ca₁₀-P were all decreased by 18.6–24.9%, 16.4–21.4%, and 3.3–23.48%, respectively. Total P storage in 0–100 cm was declined by biochar. Increases in maize P uptake in the stover (38.6–71.3%) and grain (20.9–25.5%) were occurred after 31.5 t ha⁻¹ and 47.25 t ha⁻¹ biochar addition. To sum up, biochar is found to regulate the distribution, storage, and transformation of soil P, which lead to increase in maize P uptake.

Our paper examines the environmental Kuznets curve (EKC) relationship through a heterogeneous panel analysis of 34 Annex I countries for the 1990 to 2016 period. We confirm the long-run equilibrium relationship between carbon emissions, trade openness, fossil fuel usage, and GDP through the panel cointegration tests that is robust to cross-sectional dependence. Overall, our finding is that the empirical results show no consistent evidence of the EKC hypothesis in Annex I countries via mean group and long-run estimation. Country-specific estimation shows that only 5 of the 34 countries support the EKC hypothesis. From the cointegration test to long-run vector estimation, we indirectly show that fossil fuel usage can distort the EKC results by causing endogeneity, since being strong is related to economic growth. From the synthesized statistics of empirical results, Annex I countries do not follow the EKC relationship. This could imply that because no mitigation has been achieved, climate change can become a much more serious issue, although country-specific results show that mitigation is constantly in progress.

This research with a factorial arrangement was undertaken to investigate physiological responses of ajowan plants to foliar treatment of salicylic acid (1 mM) and nano-Fe₂O₃ (3 mM) under various salinity levels (0, 4, 8, 12 dS m⁻¹ NaCl, respectively). Rising salinity enhanced sodium and endogenous SA contents, soluble sugars, protein, glycine betaine, proline, antioxidant enzymes activities, ROS generation, and lipid peroxidation, while reduced potassium and iron contents, membrane stability index, leaf water content, leaf pigments, root and shoot biomasses, and seed yield. Application of particularly SA and SA+nano-Fe₂O₃ alleviated salt toxicity via enhancing K⁺ uptake, K⁺/Na⁺ ratio, Fe content, endogenous level of SA, the activities of antioxidant enzymes (superoxide dismutase, catalase, peroxidase, and polyphenol oxidase), and most of the osmolytes. These changes were resulted in improving membrane stability index, leaf water content, leaf pigments, root and shoot growth, and finally seed yield of plants under moderate and severe salinities. Therefore, these treatments can additively enhance salt tolerance and physiological performance of ajowan through increasing antioxidant capacity, osmolytes, and photosynthetic pigments. Graphical Abstract .

A facile solution processing strategy has been developed for the formation of Ag-modified ZnO microneedles at various calcination temperatures such as 300, 500, and 700 °C (AZ3, AZ5, and AZ7 respectively). Due to the heavy doping of AgNO₃, Ag⁺ ions have been incorporated in to the crystal lattice of ZnO in all the Ag-ZnO samples, which facilitated the formation of Ag-ZnO microneedle morphology with minimized defect states, and obviously, the plasmon peaks were observed due to Ag modification. These Ag-ZnO microneedle structures have been evaluated for their photocatalytic performance using methylene blue as model target contaminant and their activity was compared with the commercially available titania P25 photocatalyst. The photoactivity of all the Ag-ZnO microneedle structures was significantly higher than that of the commercially available P25 photocatalyst with the most active Ag-ZnO material having a photocatalytic activity ~ 1.4 times greater than that of P25 titania.

Intensive use of the chlorinated pesticide chlordecone from the 1970s to 1993 to prevent crop damage in banana plantations of Guadeloupe and Martinique led to diffuse pollution of soils and surface waters, affecting both fauna and human beings in the contaminated areas. Since 2001, drinking water production plants have been equipped with filters containing activated carbon that must be treated after saturation. The objective of this work is to produce a hybrid material composed of activated carbon and vitamin B12 (VB12) for the degradation of chlordecone (CLD). The preparation of such a hybrid material is carried out by non-covalent fixation to achieve an eco-friendly solution for the serious environmental problem of contamination by chlorinated pesticides. It is thus proposed to degrade CLD by a physico-chemical treatment allowing salvage of the catalyst, which is adsorbed on the carbon surface to generate less waste that is inexpedient to treat. Activated carbon (AC) is produced locally from available sugarcane bagasse subjected to phosphoric acid activation. The main characteristics of this material are a major mesoporous structure (0.91%) and a specific (BET) surface area ranging from 1000 to 1500 m² g⁻¹. The experimental results showed that BagP1.5 has a high adsorption capacity for VB12 due to its large surface area (1403 m² g⁻¹). The binding of VB12 to the bagasse-derived AC is favoured at high temperatures. The adsorption is optimal at a pH of approximately 6. The maximum adsorption capacity of VB12 on the AC, deduced from the Langmuir model, was 306 mg g⁻¹, confirming the high affinity between the two components. The hybrid material was characterised by FTIR, Raman, X-ray fluorescence spectroscopy and SEM analysis. CLD removal by this hybrid material was faster than that by VB12 or BagP1.5 alone. The CLD degradation products were characterised by mass spectrometry.

Based on the observed heavy metals in the Danshui River estuarine system, the concentration of manganese (Mn) exceeds the water quality standards. High concentrations of manganese in aquatic environment can cause disturbances in the sodium balance, disturb the metabolism of carbohydrates, and impair the immunological functions of fish. Therefore, a three-dimensional heavy metal transport model was developed and incorporated into the hydrodynamics, salinity, and suspended sediment transport model to evaluate the concentration distribution of the heavy metal manganese (Mn) in the Danshui River estuarine system of northern Taiwan. The model was validated with observational data for water level, tidal current, salinity, suspended sediment concentration, and heavy metal (Mn) concentration that was measured in 2015. The indicators of statistical error, including mean absolute error (MAE), root mean square error (RMSE), and skill score (SS), were adopted to evaluate the model performance. There was good quantitative agreement between the simulation results and measurements. Sensitivity analysis of suspended sediment and heavy metal transport model was carried out to understand which parameters were important to be cautiously determined. Furthermore, the validated model was used to investigate the influence of suspended sediment on the concentration distribution of heavy metals (Mn) in tidal estuaries. If the suspended sediment transport module was excluded in model simulations, the predicted results for the heavy metal (Mn) concentration underestimated the measured data. The modeling results showed that the inclusion of the suspended sediment transport module in the model simulations was critically important to the results of the heavy metal (Mn) concentration in the tidal estuarine system in Taiwan.