The present study aims at evaluating the risk of Mutagen X (MX) (3-chloro-4-(dichloromethyl)-5-hydroxy-2 (5H)-furanone) and adverse health effects, associated with direct ingestion of chlorinated drinking water in west of Tehran, supplied by chlorinated drinking water from surface and underground water sources. For one year, MX concentrations in tap water samples has been measured for consumers in four different zones in western Tehran. It has been found that average MX concentration in the whole study area is 24.16 ng/L, with the highest concentration being in Zone 1 with a value of 38 ng/L. Also, the role of water sources, seasonal changes, and effective factors such as Total Organic Carbon (TOC) have been evaluated on MX formation. The highest of excess lifetime cancer risk (ELCR), estimated as 0.0037E-05, belongs to Zone 1, which uses surface water to supply drinking water, while the lowest can be seen in Zone 4, being 0.0021E-05. This latter zone utilizes underground water as the water source. In all zones, the highest risk of excessive cancer is related to winter, ranging from 0.0045E-5 in Zone 1 to 0.0023E-5 in Zone 4. The estimated number of cancer cases for Zones 1 to 4 have been 0.012, 0.016, 0.016, and 0.004, respectively, based on their population. The estimated average risk and the number of ELCR, caused by exposure to MX, through direct ingestion of drinking water have been 0.0030E-5 and 0.047, respectively, in the entire studied area for the duration of one year.

The presence of synthetic dyes in textile wastewater is a problematic issue for environmentalist. Nowadays, dye removal is practiced via different methods. Among all these methods, biodecolorization is an ideal technique. The present research apples vermicompost microflora to remove reactive black- C, pH = 7, and under anaerobic condition. At 36h, removal efficiencies of 94.79%, 94.06%, and 93.6% are obtained for concentrations of 800, 850, and 950 mg/ L, respectively. It has also been observed that when the initial concentration rises to 1400 mg/ L, the efficiency drops to 51.57% at 36h. Also, methyl red, methyl orange, eriochrome black-t, and acid blue-113 could be decolorized by the isolated bacterial strain with an efficiency of 94.29%, 92.10%, 90.83%, and 88.95%, respectively. Phytotoxicity Test shows that the parent form of reactive black-5 has not been toxic for the seeds (100% germination for Triticum aestivum and 90% for Maize). When reactive black-5 is treated with isolated bacterial strain under anaerobic condition, none of the seeds remain germinated which might be due to the possible formation of toxic aromatic amines intermediates. Therefore, ultraviolet C + 100 mM H2O2 has been used as the post-treatment process for detoxifying of by-products. After the integrated treatment of synthetic wastewater, containing RB-5, complete germination (100%) of Triticum aestivum and Maize is observed. In the post-treatment process, due to the generation and activation of hydroxyl radicals, the toxic aromatic amines compounds convert to the less toxic compounds.

The present paper tries to assess different scenarios for solid waste management in Khorramabad industrial park. It uses a new hybrid method of fuzzy Rapid Impact Assessment Matrix, and proposes the Fuzzy theory, the ranking method of which is innovated so that the accuracy and flexibility of the RIAM method could be improved. Four scenarios are studied, namely open dumping, sanitary landfill, gasification, and incineration. They are then evaluated in terms of their physical/chemical, biological/ecological, social/cultural, and economic/operational effects. Afterwards, two scenarios have been selected with the aim of energy production. The evaluation of these aspects for each scenario is in accordance to the expert's judgments and field study, with the results showing that sanitary landfill has had the least undesirable effects. Hence, this approach is selected as the best scenario for waste management in the studied area. According to the obtained results, it is suggested to consider sanitary landfills as the main part of the waste management hierarchy program of the studied area. Also, it is highly recommended to use the Fuzzy RIAM technique in similar studies and to compare the results with the new ones in order to examine the accuracy of the new improved method.

The present study deals with sequential extraction of fine particulate matter (PM2.5) bound trace metals in an industrial area of Firozabad, India. During the study period, daily PM2.5 concentration ranged between 73.49 μg/m3 and 113.26 μg/m3 with poor air quality index of 196.37. In the present study, Ca recorded the highest while Co had the lowest concentration among all analysed metals. Mn, Ni, Pb, Co, and Cu had high bioavailability (34.80%-65.80%) than other elements. Cd, Pb, and Cu were found to be highly enriched (EF> 289-6516) by varied anthropogenic activities. Hazard Quotient (HQ) for Ni, Mn, and Cr and Excess Lifetime Cancer Risk (ELCR) of Cr(VI) and Ni exceeded the respective safer limit (HQ>1 and ELCR≥ 10-6), thus implying serious risk to the receptors. All the metals had the highest concentration in less mobile and residual fraction except for Ni and Co, which inferred greater risk due to their high toxicity. Overall, the results present exposure and risk assessment of metal associated particles; that provides in-depth knowledge of the risk factors through inhalation exposure pathway of particles associated with industrial environment.

Air is one of the precious natural resources that are essential for animal including the human being. It is also the most important gift of nature without which human cannot survive. Pollution in the urban areas like Cairo, Delhi, Mexico and Dhaka far surpasses the acceptable limits set by the World Health Organization (WHO). Urban air pollution in the South Asian region is approximated to cause more than 300,000 deaths and billions of cases of respiratory disease per year. In Bangladesh, about 200000 people die each year due to the air pollution as the WHO estimates in 2018. The air in Dhaka City, the capital of Bangladesh, has become worsen to a level that the city has been identified as one of the most polluted cities in the world. Taking the problem with utmost importance into consideration as it is related with the public health, air pollution is being treated as one of the priority issues. The level of pollution at roadside environment is deeply connected with the density of motor vehicles plying on the roads. This situation is expected to worsen further in the upcoming days due to the increasing number of motor vehicles resulted from rapid economic growth and industrialization. This paper aims to provide the present statues of the air pollution in Dhaka city and some specific recommendations for making the city as a better living place through reducing its air pollution.

It has been more than 20 years that the Measurement of Pollution in The Troposphere (MOPITT) mission onboard the NASA Terra satellite keeps providing us CO atmospheric concentration measurements around the globe. The current paper observes CO mixing ratio from the MOPITT Version 8 (MOP03J_V008) instrument in order to study the spatiotemporal analysis of CO (spanning from April 2000 to February 2020) in the Troposphere of Iran. Results indicate that the average CO in Iran’s troposphere has been 133.5 ppbv (i.e., 5.5 ppbv lower than the global mean CO). The highest distribution of CO (with an average of 150 ppbv) belongs to the city of Tehran (the capital of Iran) as well as the Caspian Sea coastal area, while the lowest value (with an average of less than 110 ppbv) has been estimated on the Zagros Mountains (southwestern Iran). The highest and lowest CO values have been observed in cold and hot months, respectively. Seasonally speaking, it is also clear that the highest and lowest carbon monoxide values occur in winter and summer, respectively. The vertical profile of MOPITT CO shows the maximum CO concentration at lower levels of the troposphere. It has been expanded up to 150 hPa. The trend is investigated by means of Pearson correlation coefficient statistical method. Overall, long-term monitoring of MOPITT CO in Iran indicates a decreasing trend of tropospheric CO over the 20 years (Y=-0.008X+449.31). Possible reasons for such a decrease can be related to improved transportation fleet, increased fuel quality, plans for traffic control, promotion of heating systems, and promotion of industrial fuels and factories.

Textile manufacturing industry produces a huge amount of pollutants from its textile dyeing units. To combat the problem of water pollution, various processes are being already adopted by textile industries to treat wastewater before its discharge into the nearby environment. However, the inadequate traditional treatments are leading towards the development of different technologies with major concern on material’s high efficacy. One of the newest advancement in this area is nanotechnology. The zero valent iron nanoparticles (nZVI) are gaining extreme importance, due to its potential capabilities of reducing chemical substances, dye colour and other constituents from the waste effluent. In the present article, synthesis of nZVI particles was carried out by borohydride chemical reduction method using ferrous heptahydrate sulphate salt. Its characterization such as surface morphology and structure was analyzed by using X-Ray diffraction (XRD), Scanning Electron Microscope (SEM) and Brunauer- Emmett-Teller method (BET). Further, the stability of nanoparticles was also investigated via chemical and thermal processes at different pH ranges and temperatures. The results revealed that the synthesized nanoparticles were as per the available literature in terms of size, surface morphology, structure & stability. Hence, ready for the batch experimental studies on laboratory scale.

Sludge/TiO2 composite was synthesized from drinking water treatment sludge, as a waste material and TiO2 , by a sol- gel method. Various sludge adsorbent / TiO2 ratios (1:1, 1:2 and 2:1 w/w) were prepared, and characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray Fluorescence (XRF), and BET. The prepared composites were applied successfully for photodegradation of methylene blue (MB) dye from a solution. The photocatalytic degradation of MB dye was investigated using UV irradiation, or UV/H2O2. Initial dye concentration, solution pH, composite dosage, and UV irradiation time were applied to study the optimum conditions for MB degradation. The results revealed the highest MB dye degradation with composite (2:1). It was found that the maximum MB degradation efficiency was at pH=7, 4 h irradiation time, 0.125 g composite dose, and 50 ppm initial dye concentration. MB removal efficiency was 95.7% using UV irradiation, and 99.8% of that using UV/ H2O2. The rate of MB dye degradation followed the first order kinetics. Results from this study offer the best conditions for recycling drinking water treatment sludge, and use it for wastewater treatment.

The impact of Industrialization has always been related to the better economic and social transformation. However, it should be well planned for environmental sustainability. Landfilling is the most used municipal solid waste (MSW) disposal method in Malaysia. Raw and treated leachate collected from Jerangau-Jabor Landfill Site (JJLS), Kuantan, Pahang were analysed for the content of silver, cadmium, chromium, copper, iron, lead, zinc using Flame Atomic Absorption Spectrometry (FAAS) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The metal analyses result were compared with standard limits from the Environmental Quality (Control of Pollution from Solid Waste Transfer Station and Landfill) Regulations 2009, Malaysian Environmental Quality Act 1974 (Act 127) set by the Department of Environment, Ministry of Natural Resources and Environment, Malaysia and used to calculate the sub-leachate pollution index of heavy metals (sub-LPIhm) to evaluate the pollution potential of the heavy metals. The sub-LPIhm is one of the sub-index needed to calculate the Leachate Pollution Index (LPI) together with the sub-LPI organic (sub-LPIorg) and sub-LPI inorganic (sub-LPIinorg). LPI is the level of leachate pollution potential of a landfill site. All the heavy metals in the raw leachate were significantly higher than the treated leachate. Some were found to be above the permissible standard limit stipulated in the regulation. However, the sub-LPIhm showed that the level of heavy metal pollution potential of the leachate is low. It is recommended that the treated leachate should undergo continuous treatment to ensure the discharge leachate complied with the standard limit.

Hydrocarbon storage tanks, the major source of volatile organic compounds (VOCs) emission, have unfavorable effects on atmospheric chemistry and human health. The present study aims at calculating the amount of VOCs’ loss with an emphasis on benzene, toluene, ethylbenzene, and xylene (BTEX). It has been performed by means of TANKs 4.0.9d and WATER9 Software Programs, as well as field measurement for validation. It, then, provides control strategies to reduce the amounts of VOCs in the shipping port area. Emission sources include 32 internal and external floating roof storage tanks, 7 pump houses, and one wastewater treatment pool. Field sampling has been done, using SKC sampling pump and activated carbon adsorption tube according to NIOSH 1501 standard. The obtained samples have been analyzed with FID and GC-MS. Results show that the total emission of VOCs has been equal to 933.25 tons/year, the majority of which (881.74 tons/year ) comes from storage tanks, followed by pump houses and wastewater treatment pool (47.88 and 3.63 tons/year, respectively). BTEX emission includes 1.49 tons/year of benzene, 3.2 tons/year of toluene, 0.57 tons/year of ethylbenzene, and 1.53 tons/year of xylenes. In order to reduce the emission of VOCs from the storage tanks, the paper proposes to change the design of tanks’ roof and sealing. As a result, the total emission of VOCs could be reduced by 18.27%, equivalent to 158.16 tons/year. The total cost of the oil vapors loss is estimated at 253’000 $/year, part of which (i.e., up to 43’000 $/year) could be saved by applying the proposed control strategies.