Thermal–optical analysis is one of the most widely–recognized methods for measuring organic carbon (OC) and elemental carbon (EC) in atmospheric particulates. Up to date however, there is no standard protocol of analysis and different protocols give varying OC/EC apportionments. This study aims to find an optimal thermal–optical analysis protocol for Philippine OC/EC samples by comparing three widely–used protocols: NIOSH, IMPROVE_A and EUSAAR_2. Philippines is particularly interesting because it has one of the highest EC concentration and lowest OC/EC ratio in the region. In terms of total OC and EC quantification, NIOSH and IMPROVE_A show negative and positive EC bias, respectively – NIOSH exhibits premature EC evolution in the OC4 pure He phase, while IMPROVE_A OC4 temperature step (580 °C) is not sufficiently high, causing some OC to be carried over to He/O2 phase to be measured mainly as EC2. EUSAAR_2 minimizes both effects and may be most accurate in this aspect. However, IMPROVE_A is the only method that is capable of properly resolving individual OC and Philippines’s particularly abundant EC fractions owing to the protocol’s variable step durations. Concurrently, IMPROVE_A and EUSAAR_2 yield lowest pyrolized carbon (PC) formation for urban and rural site, respectively. Minimal PC formation is desired to minimize errors associated with its correction. Finally, transmittance laser correction is preferred over reflectance as it is capable of accounting for char formed within filter. The study thus recommends a modified IMPROVE_A, with increased OC4 temperature step (650 °C, adopted from EUSAAR_2) and transmittance laser correction, as optimal. This protocol is expected to give proper OC and EC evolution, fractionation, and measurement with minimized PC formation and proper correction, leading to more accurate results. Preliminary testing shows that recommended protocol meets those expectations. Application to larger number and wider variety of samples is needed to more properly assert these findings.

Ten years of aerosol and Radon–222 (radon) data from Gosan, Korea, were analyzed. Seasonal cycles were strongly linked to changes in fetch and time of year. We estimated that 7.21t/m y of PMio aerosol pass Gosan in the atmospheric boundary layer, increasing annually by 0.3t/m y. Contributions to aerosol loading were characterized by fetch: South China, North China, Korea and Japan. While the highest, and most variable, contributions typically originated from South China, these air masses contributed to only 6% of the overall dataset. PM10 distributions were broader from South and North China than for Korea or Japan, reflecting differences in natural/anthropogenic soil sources, and number/distribution of large point sources. Employing radon to select air masses more representative of targeted fetch regions typically resulted in greater reported pollutant concentrations and rates of change over the decade. Estimated rates of PM10 increase from North China and Korea over the decade were 1.4 and 0.9μg/m3 y, respectively. Total suspended particulate (TSP) elemental analysis indicated that the (non–sea–salt) nss–SO42− content of aerosols has been gradually increasing over the past decade and more recently an increase in NO3− was seen. However, on average, rates of increase in nss–SO42− have reduced since 2007, which were higher in South than North China.

In Mar del Plata (Argentine, SW Atlantic), a large seaside resort, the sewage discharges impact the littoral ecosystem. The invader polychaete Boccardia proboscidea has developed reefs since spring of 2008. The effect of this species on the richness, diversity and structure of epilithic intertidal community was assessed through an MBACI design in both sewage-impacted and reference sites, and Before/After the invasion. The presence of reefs of B. proboscidea since spring 2008 has caused a significant reduction of total individuals, total taxa and diversity in sewage-impacted sites regarding the reference ones. The species analyzed showed a high variable response because patterns were dominated by small-scale variability. Occasional peaks in abundance were observed on a single sampling site and time and a large variation among replicates. The associated fauna, formerly rich and diverse in impacted sites, shows a tendency to disappear as the ecosystem engineer Brachidontes rodriguezii is replaced by monocultures of B. proboscidea.

The whole-sediment Toxicity Identification Evaluation (TIE) approach is a useful technique that allows for the identification of the contaminants responsible for the toxicity of complex sediment samples. This study aimed to compare the effectiveness of this technique in identifying the causes of toxicity when the test organism used in the toxicity test is capable of ingesting sediment particles. Two forms of exposure were compared: whole-sediment (WS), which integrates dermic and dietary exposures; and sediment–water interface (SWI), which involves dermic exposure only. The combined analysis of the TIE experiments revealed that metals, ammonia and, at one station, organic compounds, were responsible for sediment toxicity. The integrated use of WS and SWI TIE manipulations provided a more complete overview of the causes of toxicity, and thus enabled a better comprehension of complex contamination situations and, consequently, a better ecological assessment.

This paper reports on the distribution of three natural radionuclides 238U, 232Th and 40K in coastal sediments from Pattipulam to Devanampattinam along the East coast of Tamilnadu to establish baseline data for future environmental monitoring. Sediment samples were collected by a Peterson grab samples from 10m water depth parallel to the shore line. Concentration of natural radionuclides were determined using a NaI(Tl) detector based γ-spectrometry. The mean activity concentration is ⩽2.21, 14.29 and 360.23Bqkg−1 for 238U, 232Th and 40K, respectively. The average activity of 232Th, 238U and 40K is lower when compared to the world average value. Radiological hazard parameters were estimated based on the activity concentrations of 238U, 232Th and 40K to find out any radiation hazard associated with the sediments. The radiological hazard parameters such as radium equivalent activity (Raeq), absorbed gamma dose rates in air (DR), the annual gonadal dose equivalent (AGDE), annual effective dose equivalent (AEDE), external hazard index (Hex) internal hazard index (Hin), activity utilization index (AUI) and excess lifetime cancer (ELCR) associated with the radionuclides were calculated and compared with internationally approved values and the recommended safety limits. Pearson correlation, principal component analysis (PCA) and hierarchical cluster analysis (HCA) have been applied in order to recognize and classify radiological parameters in sediments collected at 22 sites on East coast of Tamilnadu. The values of radiation hazard parameters were comparable to the world averages and below the recommended values. Therefore, coastal sediments do not to pose any significant radiological health risk to the people living in nearby areas along East coast of Tamilnadu. The data obtained in this study will serve as a baseline data in natural radionuclide concentration in sediments along the coastal East coast of Tamilnadu.

Biodegradation of diethyl phthalate (DEP) and di-n-butyl phthalate (DBP) by three marine algae was investigated. When they were coexistent, DBP was degraded more quickly than DEP. The first-order biodegradation rate constants of DBP in the algal solutions were in the order of Cylindrotheca closterium (0.0169h−1)>Dunaliella salina (0.0035h−1) and Chaetoceros muelleri (0.0034h−1). When singly existed, DEP was degraded more quickly than in a mixture with DBP, indicating that DBP had inhibitory effect on the biodegradation of DEP. Moreover, the degradation trends of DEP and DBP in both extra- and intracellular crude extracts were similar to those in algal solutions. At the end, DEP was largely in water phase, whereas DBP remained in both water phase and algal phase. It can be concluded that biodegradation of DEP was mainly by algal extracellular enzymes, and both extra- and intracellular enzymes played key roles in the degradation of DBP.

Antibiotic use is a well-described practice to promote animal health whether for prevention or treatment. Nonetheless, it can also cause a number of potentially harmful effects that dictate the need to implement regulation to assure a reduction of hazards to the consumers and the environment. Chloramphenicol (CAP) is a broad-spectrum antibacterial excluded from use in animal food production but despite this, reports of illegal use still persist. More recently, awareness has risen that the surrounding natural ecosystems can potentially be contaminated by pharmaceuticals and the extent of their effects in non-target organisms is already under the scope of researchers. To face the demanding new challenges a methodology for the determination of CAP in the green macroalgae Ulva lactuca by ultra-high performance liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS/MS) was developed, optimized and fully validated following the guidelines of the EC Decision 2002/657.

Sewage pollution is one of major concerns of coastal and shoreline settlements in Southeast Asia, especially Brunei. The distribution and sources of LABs as sewage molecular markers were evaluated in surface sediments collected from Brunei Bay. The samples were extracted, fractionated and analyzed using gas chromatography- mass spectrometry (GC-MS). LABs concentrations ranged from 7.1 to 41.3ngg−1 dry weight (dw) in surficial sediments from Brunei Bay. The study results showed LABs concentrations variably due to the LABs intensity and anthropogenic influence along Brunei Bay in recent years. The ratio of Internal to External isomers (I/E ratio) of LABs in sediment samples from Brunei Bay ranged from 0.56 to 2.17 along Brunei Bay stations, indicating that the study areas were receiving primary and secondary effluents. This is the first study carried out to assess the distribution and sources of LABs in surface sediments from Brunei Bay, Brunei.

Previous studies near historical gold mining districts in Nova Scotia have identified significant enrichment of metal(loid)s in coastal marine sediments. Most of this inventory is buried below biologically active zones, although in some areas arsenic has bioaccumulated in marine biota resulting in localised bivalve shellfish closures. Isaacs Harbour is poised for future industrial development, but before potential impacts are predicted, current marine baseline conditions must be determined. To address this gap, this study established a baseline using surface sediments and biota (mussel and lobster tissues), to provide a broader picture of metal(loid)s in the marine environment. Results confirmed previous studies showing that most sediment metal(loid) concentrations still exceeded Canadian Marine Sediment Quality Guidelines, and also provided evidence of Canadian Food Inspection Agency fish tissue exceedances of arsenic in lobster and lead in mussel tissues indicating that some bioaccumulation of legacy contaminants in marine biota continues to the present day.

The present study was carried out on the Porites coral growth bands (1979 to 2014) to measure the metal accumulation for assessing the environmental pollution status. The concentrations of studied metals are compared with similar global studies, which indicate that the metals are probably derived from natural sources. The identical peaks of Fe and Mn are perfectly matched with Cu, Cr and Ni concentrations. However, the metal profile trend is slightly depressed from a regular trend in Zn, Cd and Pb peaks. The metal accumulation affinity of the reef skeleton is ranked in the following order Cr>Cd>Pb>Fe>Mn>Cu>Ni>Zn. The distribution of metal constituents in coral growth bands is primarily controlled by Fe and Mn in the reef skeleton. Other reef associated metals such as Pb and Cd are derived from other sources like coastal developments and anthropogenic sources.