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Removal of Thymol Blue from Aqueous Solution by Natural and Modified Bentonite: Comparative Analysis of ANN and ANFIS Models for the Prediction of Removal Percentage Texto completo
2021
Koyuncu, Hülya | Aldemir, Adnan | Kul, Ali Rıza | Canayaz, Murat
In this study natural bentonite (NB) and acid-thermal co-modified bentonite (MB) were utilized as adsorbents for the removal of Thymol Blue (TB) from aqueous solution. The batch adsorption experiments were conducted under different experimental conditions. The artificial neural network (ANN) and adaptive neuro fuzzy inference systems (ANFIS) were applied to estimate removal percentage (%) of TB. Mean squared error (MSE), root mean square error (RMSE) and coefficient of determination (R2) values were used to evaluate the results. In addition, the experimental data were fitted isotherm models (Langmuir, Freundlich and Temkin) and kinetic models (pseudo first order (PFO), pseudo second order (PSO) and intra-particle diffusion (IPD)). The adsorption of TB on both the NB and MB followed well the PSO kinetic model, and was best suited Langmuir isotherm model. When the temperature was increased from 298 K to 323 K for 20 mg/L of TB initial concentration, the removal percentage of TB onto the NB and MB increased from 74.91% to 84.07% and 81.19% to 93.12%, respectively. This results were confirmed by the positive ΔH° values indicated that the removal process was endothermic for both the NB and MB. The maximum adsorption capacity was found as 48.7805 mg/g and 117.6471 mg/g for the NB and MB, respectively (at 323 K). As a result, with high surface area and adsorption capacity, the MB is a great candidate for TB dye removal from wastewater, and the ANFIS model is better than the ANN model at estimating the removal percentage of the dye.
Mostrar más [+] Menos [-]Production of Eco-Friendly Geopolymer Concrete by using Waste Wood Ash for a Sustainable Environment Texto completo
2021
Arunkumar, Kadarkarai | Muthukannan, Muthiah | Suresh Kumar, Arunachalam | Chithambar Ganesh, Arunasankar | Kanniga Devi, Rangaswamy
Climate change could be exacerbated by waste disposal problems, which destroy the ecosystem. Utilizing waste byproducts in creating eco-friendlier geopolymer concrete was hypothesised to be suitable and sustainable to overcome the negative impacts of wastes. The researchers had missed out on developing an alternate binder due to increasing demand for fly ash, high alkaline activators, and higher curing temperatures. This research used waste wood ash that is readily accessible in local restaurants and has an inherent potassium constituent. It has decided to replace the fly ash with waste wood ash obtained through nearby restaurants at intervals of 10 percent. The fresh and mechanical features have been discovered over long curing periods to assess the impact of waste wood ash. SEM and XRD have been used for characterising the microstructure of selected geopolymer mixes. In terms of setting properties and all mechanical parameters, replacing 30 percent waste wood ash produced enhanced results. The optimised mix could be used in geopolymer to replace fly ash and reduce the cost of alkaline activators while also reducing ecosystem damage.
Mostrar más [+] Menos [-]Developmental assays using invasive cane toads, Rhinella marina, reveal safety concerns of a common formulation of the rice herbicide, butachlor Texto completo
2021
Shuman-Goodier, Molly E. | Singleton, Grant R. | Forsman, Anna M. | Hines, Shyann | Christodoulides, Nicholas | Daniels, Kevin D. | Propper, Catherine R.
X-ray absorption spectroscopy evidence of sulfur-bound Cadmium in the Cd-hyperaccumulator Solanum nigrum and the non-accumulator Solanum melongena Texto completo
2021
Pons, Marie-Noëlle | Collin, Blanche | Doelsch, Emmanuel | Chaurand, Perrine | Fehlauer, Till | Levard, Clément | Keller, Catherine | Rose, Jérôme
It has been proposed that non-protein thiols and organic acids play a major role in cadmium phytoavailability and distribution in plants. In the Cd-hyperaccumulator Solanum nigrum and non-accumulator Solanum melongena, the role of these organic ligands in the accumulation and detoxification mechanisms of Cd are debated. In this study, we used X-ray absorption spectroscopy to investigate Cd speciation in these plants (roots, stem, leaves) and in the soils used for their culture to unravel the plants responses to Cd exposure. The results show that Cd in the 100 mg.kg-1 Cd-doped clayey loam soil is sorbed onto iron oxyhydroxides. In both S. nigrum and S. melongena, Cd in roots and fresh leaves is mainly bound to thiol ligands, with a small contribution of inorganic S ligands in S. nigrum leaves. We interpret the Cd binding to sulfur ligands as detoxification mechanisms, possibly involving the sequestration of Cd complexed with glutathione or phytochelatins in the plant vacuoles. In the stems, results show an increase binding of Cd to -O ligands (>50% for S. nigrum). We suggest that Cd is partly complexed by organic acids for transportation in the sap.
Mostrar más [+] Menos [-]Factors affecting farmers’ use of organic and inorganic fertilizers in South Asia Texto completo
2021
Aryal, Jeetendra P | Sapkota, Tek Bahadur | Krupnik, Timothy J. | Rahut, Dil B | Jat, Mangi Lal | Stirling, Clare M
Factors affecting farmers’ use of organic and inorganic fertilizers in South Asia Texto completo
2021
Aryal, Jeetendra P | Sapkota, Tek Bahadur | Krupnik, Timothy J. | Rahut, Dil B | Jat, Mangi Lal | Stirling, Clare M
Fertilizer, though one of the most essential inputs for increasing agricultural production, is a leading cause of nitrous oxide emissions from agriculture, contributing significantly to global warming. Therefore, understanding factors affecting farmers’ use of fertilizers is crucial to develop strategies to improve its efficient use and to minimize its negative impacts. Using data from 2528 households across the Indo-Gangetic Plains in India, Nepal, and Bangladesh, this study examines the factors affecting farmers’ use of organic and inorganic fertilizers for the two most important cereal crops – rice and wheat. Together, these crops provide the bulk of calories consumed in the region. As nitrogen (N) fertilizer is the major source of global warming and other environmental effects, we also examine the factors contributing to its overuse. We applied multiple regression models to understand the factors influencing the use of inorganic fertilizer, Heckman models to understand the likelihood and intensity of organic fertilizer (manure) use, and a probit model to examine the over-use of N fertilizer. Our results indicate that various socio-economic and geographical factors influence the use of organic and inorganic fertilizers in rice and wheat. Across the study sites, N fertilizer over-use is the highest in Haryana (India) and the lowest in Nepal. Across all locations, farmers reported a decline in manure application, concomitant with a lack of awareness of the principles of appropriate fertilizer management that can limit environmental externalities. Educational programs highlighting measures to improving nutrient-use-efficiency and reducing the negative externalities of N fertilizer over-use are proposed to address these problems.
Mostrar más [+] Menos [-]Factors affecting farmers’ use of organic and inorganic fertilizers in South Asia Texto completo
2021
Aryal, Jeetendra Prakash | Sapkota, Tek Bahadur | Krupnik, Timothy J. | Rahut, Dil Bahadur | Jat, Mangi Lal | Stirling, Clare M.
Fertilizer, though one of the most essential inputs for increasing agricultural production, is a leading cause of nitrous oxide emissions from agriculture, contributing significantly to global warming. Therefore, understanding factors affecting farmers’ use of fertilizers is crucial to develop strategies to improve its efficient use and to minimize its negative impacts. Using data from 2528 households across the Indo-Gangetic Plains in India, Nepal, and Bangladesh, this study examines the factors affecting farmers’ use of organic and inorganic fertilizers for the two most important cereal crops – rice and wheat. Together, these crops provide the bulk of calories consumed in the region. As nitrogen (N) fertilizer is the major source of global warming and other environmental effects, we also examine the factors contributing to its overuse. We applied multiple regression models to understand the factors influencing the use of inorganic fertilizer, Heckman models to understand the likelihood and intensity of organic fertilizer (manure) use, and a probit model to examine the over-use of N fertilizer. Our results indicate that various socio-economic and geographical factors influence the use of organic and inorganic fertilizers in rice and wheat. Across the study sites, N fertilizer over-use is the highest in Haryana (India) and the lowest in Nepal. Across all locations, farmers reported a decline in manure application, concomitant with a lack of awareness of the principles of appropriate fertilizer management that can limit environmental externalities. Educational programs highlighting measures to improving nutrient-use-efficiency and reducing the negative externalities of N fertilizer over-use are proposed to address these problems.
Mostrar más [+] Menos [-]Factors affecting farmers’ use of organic and inorganic fertilizers in South Asia Texto completo
2021
Aryal, J.P. | Sapkota, T. | Krupnik, T.J. | Rahut, D.B. | Jat, M.L. | Stirling, C.
Fertilizer, though one of the most essential inputs for increasing agricultural production, is a leading cause of nitrous oxide emissions from agriculture, contributing significantly to global warming. Therefore, understanding factors affecting farmers’ use of fertilizers is crucial to develop strategies to improve its efficient use and to minimize its negative impacts. Using data from 2528 households across the Indo-Gangetic Plains in India, Nepal, and Bangladesh, this study examines the factors affecting farmers’ use of organic and inorganic fertilizers for the two most important cereal crops – rice and wheat. Together, these crops provide the bulk of calories consumed in the region. As nitrogen (N) fertilizer is the major source of global warming and other environmental effects, we also examine the factors contributing to its overuse. We applied multiple regression models to understand the factors influencing the use of inorganic fertilizer, Heckman models to understand the likelihood and intensity of organic fertilizer (manure) use, and a probit model to examine the over-use of N fertilizer. Our results indicate that various socio-economic and geographical factors influence the use of organic and inorganic fertilizers in rice and wheat. Across the study sites, N fertilizer over-use is the highest in Haryana (India) and the lowest in Nepal. Across all locations, farmers reported a decline in manure application, concomitant with a lack of awareness of the principles of appropriate fertilizer management that can limit environmental externalities. Educational programs highlighting measures to improving nutrient-use-efficiency and reducing the negative externalities of N fertilizer over-use are proposed to address these problems. | 51480-51496
Mostrar más [+] Menos [-]A comprehensive assessment of endocrine-disrupting chemicals in an Indian food basket: Levels, dietary intakes, and comparison with European data Texto completo
2021
Sharma, Brij Mohan | Bharat, Girija K. | Chakraborty, Paromita | Martiník, Jakub | Audy, Ondřej | Kukučka, Petr | Přibylová, Petra | Kukreti, Praveen Kumar | Sharma, Anežka | Kalina, Jiří | Steindal, Eirik Hovland | Nizzetto, Luca
A comprehensive assessment of endocrine-disrupting chemicals in an Indian food basket: Levels, dietary intakes, and comparison with European data Texto completo
2021
Sharma, Brij Mohan | Bharat, Girija K. | Chakraborty, Paromita | Martiník, Jakub | Audy, Ondřej | Kukučka, Petr | Přibylová, Petra | Kukreti, Praveen Kumar | Sharma, Anežka | Kalina, Jiří | Steindal, Eirik Hovland | Nizzetto, Luca
Endocrine-disrupting chemicals (EDCs) in diet are a health concern and their monitoring in food has been introduced in the European Union. In developing countries, EDC dietary exposure data are scarce, especially from areas perceived as pollution hotspots, including industrialized countries like India. Several persistent organic pollutants (POPs) act as EDCs and pose a pressure to human health mainly through dietary exposure. In the present study a range of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), dioxins and furans were measured in several food items collected in an Indian urban (Delhi) and a rural area (Dehradun). Food basket contamination data were used to estimate dietary exposure and compare it with that of the average European population estimated from available monitoring data. All targeted contaminants were found in most food items, especially in dairies and meat products. OCPs were the main contributors. Food supplied to Delhi's markets had higher contamination than that supplied to the peri-urban market in Dehradun. Despite looser control and restrictions, Indian dietary exposure of OCPs and PBDEs were comparable with that of Europe and were lower for PCBs and dioxins. Higher meat consumption in Europe only partly explained this pattern which was driven also by the higher residues in some European food items. A substantial part of endocrine disrupting potential in the diet derives from food and animal feeds internationally traded between developed and developing countries. With increasingly globalized food systems, internationally harmonized policies on EDC in food can lead to better protection of health in both these contexts. | publishedVersion
Mostrar más [+] Menos [-]A comprehensive assessment of endocrine-disrupting chemicals in an Indian food basket: Levels, dietary intakes, and comparison with European data Texto completo
2021
Sharma, Brij Mohan | Bharat, Girija K. | Chakraborty, Paromita | Martiník, Jakub | Audy, Ondřej | Kukučka, Petr | Přibylová, Petra | Kukreti, Praveen Kumar | Sharma, Anežka | Kalina, Jiří | Steindal, Eirik Hovland | Nizzetto, Luca
Endocrine-disrupting chemicals (EDCs) in diet are a health concern and their monitoring in food has been introduced in the European Union. In developing countries, EDC dietary exposure data are scarce, especially from areas perceived as pollution hotspots, including industrialized countries like India. Several persistent organic pollutants (POPs) act as EDCs and pose a pressure to human health mainly through dietary exposure. In the present study a range of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), dioxins and furans were measured in several food items collected in an Indian urban (Delhi) and a rural area (Dehradun). Food basket contamination data were used to estimate dietary exposure and compare it with that of the average European population estimated from available monitoring data. All targeted contaminants were found in most food items, especially in dairies and meat products. OCPs were the main contributors. Food supplied to Delhi's markets had higher contamination than that supplied to the peri-urban market in Dehradun. Despite looser control and restrictions, Indian dietary exposure of OCPs and PBDEs were comparable with that of Europe and were lower for PCBs and dioxins. Higher meat consumption in Europe only partly explained this pattern which was driven also by the higher residues in some European food items. A substantial part of endocrine disrupting potential in the diet derives from food and animal feeds internationally traded between developed and developing countries. With increasingly globalized food systems, internationally harmonized policies on EDC in food can lead to better protection of health in both these contexts. | publishedVersion
Mostrar más [+] Menos [-]A comprehensive assessment of endocrine-disrupting chemicals in an Indian food basket: Levels, dietary intakes, and comparison with European data Texto completo
2021
Sharma, Brij Mohan | Bharat, Girija K. | Chakraborty, Paromita | Martiník, Jakub | Audy, Ondřej | Kukučka, Petr | Přibylová, Petra | Kukreti, Praveen Kumar | Sharma, Anežka | Kalina, Jiří | Steindal, Eirik Hovland | Nizzetto, Luca
Endocrine-disrupting chemicals (EDCs) in diet are a health concern and their monitoring in food has been introduced in the European Union. In developing countries, EDC dietary exposure data are scarce, especially from areas perceived as pollution hotspots, including industrialized countries like India. Several persistent organic pollutants (POPs) act as EDCs and pose a pressure to human health mainly through dietary exposure. In the present study, a range of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), dioxins and furans were measured in several food items collected from Indian urban (Delhi) and peri-urban (Dehradun) areas. Food basket contamination data were used to estimate EDC dietary exposure and compare it with that of the average European population estimated from available monitoring data. All the target contaminants were found in most food items, especially in dairies and meat products. OCPs were the main contributers to the measured EDC contamination. Food supplied to Delhi's markets had higher EDC contamination than that supplied to the peri-urban market in Dehradun. Despite lax compliance and control measures, Indian dietary exposure of OCPs and PBDEs were comparable with that of Europe and were lower for PCBs and dioxins. Higher meat consumption in Europe only partly explained this pattern which was driven also by the higher EDC residues in some European food items. A substantial part of endocrine disrupting potential in the diet derives from food and animal feeds internationally traded between developed and developing countries. With increasingly globalized food systems, internationally harmonized policies on EDC content in food can lead to better protection of health in both these contexts.
Mostrar más [+] Menos [-]Distribution of pesticides and some of their transformation products in a small lentic waterbody: Fish, water, and sediment contamination in an agricultural watershed Texto completo
2021
Slaby, Sylvain | Le Cor, François | Dufour, Vincent | Auger, Lucile | Pasquini, Laure | Cardoso, Olivier | Curtet, Laurence | Baudoin, Jean-Marc | Wiest, Laure | Vulliet, Emmanuelle | Feidt, Cyril | Dauchy, Xavier | BANAS, Damien
A review on occurrence of emerging pollutants in waters of the MENA region Texto completo
2021
Haddaoui, I. | Mateo-Sagasta, Javier
Little is known about the occurrence of emerging pollutants (EPs) in waters in the Middle East and North Africa (MENA) region despite the extensive use of low-quality water there. Available data dealing with the sources, occurrence and removal of EPs within the MENA region in different categories of water is collected, presented and analyzed in this literature review. According to the collected database, the occurrence and removal efficiency of EPs in the water matrix in the MENA region is available, respectively, for 13 and six countries of the 18 in total; no available data is registered for the rest. Altogether, 290 EPs have been observed in different water matrices across the MENA countries, stemming mainly from industrial effluents, agricultural practices, and discharge or reuse of treated wastewater (TWW). Pharmaceutical compounds figure among the most frequently reported compounds in wastewater, TWW, surface water, and drinking water. Nevertheless, pesticides are the most frequently detected pollutants in groundwater. Worryingly, 57 cases of EPs have been reported in different fresh and drinking waters, exceeding World Health Organization (WHO) and European Commission (EC) thresholds. Overall, pharmaceuticals, organic compounds, and pesticides are the most concerning EP groups. The review revealed the ineffectiveness of treatment processes used in the region to remove EPs. Negative removals of some EPs such as carbamazepine, erythromycin, and sulfamethoxazole were recorded, suggesting their possible accumulation or release during treatment. This underlines the need to set in place and strengthen control measures, treatment procedures, standards, and policies for such pollutants in the region.
Mostrar más [+] Menos [-]Catches in abandoned snow crab (Chionoecetes opilio) pots in the Barents Sea Texto completo
2021
Humborstad, Odd Børre | Eliassen, Lasse Krøger | Siikavuopio, Sten Ivar | Løkkeborg, Svein | Ingolfsson, Olafur Arnar | Hjelset, Ann Merete
publishedVersion
Mostrar más [+] Menos [-]Catches in abandoned snow crab (Chionoecetes opilio) pots in the Barents Sea Texto completo
2021
Humborstad, Odd Børre | Eliassen, Lasse Krøger | Siikavuopio, Sten Ivar | Løkkeborg, Svein | Ingolfsson, Olafur Arnar | Hjelset, Ann Merete
During a 2018 retrieval cruise for abandoned snow crab (Chionoecetes opilio) pots in the Barents Sea, approximately 8600 pots abandoned 1.5 years earlier were recovered. Forty-three percent of a subsample of 1000 pots contained snow crabs, with an average of three crabs per pot. Most of the crabs were alive (~98%) and dominated by large males. Pinch injuries and limb loss were common and tended to decline with increasing crab size. Reflex testing showed that the crabs were vital (i.e. the crabs moved their legs, chelipeds and maxillipeds when stimulated), which was supported by a relatively high meat content. However, energy reserves in the digestive glands (hepatopancreas reserves) were low, indicating overall energy deficiencies. Our results indicate considerable unaccounted mortality due to self-baiting, continued catch and cannibalism. The findings demonstrate that snow crab pots which are lost or abandoned in the Barents Sea fishery maintain huge potential for ghost-fishing impacts. | publishedVersion
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