Corrosion products have been takenfrom 130 copper or bronze outdoor objects all overEurope. Their chemical composition and crystalsymmetry have been determined by means of scanning electron microscopy (SEM/EDS) and X-ray powderdiffraction. Data on location, sampling, objectcharacteristics, general environment and air pollutionlevel; type, colour and chemical composition of thecorrosion layers have been obtained and evaluated by multivariate statistical analysis. The resultsverify that the highest air pollution levels are usually associated with the occurrence of thick,black or dark grey corrosion layers on copper orbronze objects, preferentially containing soot, ironoxide hydroxides, and antlerite,Cu₃(SO₄)(OH)₄. Pale green corrosionusually contains brochantite,Cu₄(SO₄)(OH)₆, and is rather associatedwith less polluted areas. Atacamite, a copper hydroxide chloride with the chemical formula Cu₂Cl(OH)₃, is preferentially observed in coastal regions.In addition, sulphur isotope analyses have beenperformed on eleven corrosion samples from citycenters. The δ³⁴S values are typically inthe region from +4 to +6‰ relative to the sulphurisotope standard CDT (Canyon Diablo Troilite) with amean value of 4.7±1.2 (1σ), therebyindicating that the sulphur in the corrosion layers,in the form of brochantite or antlerite, mainlyoriginates from a similar source despite geographicvariation, most likely sulphur contained in air pollutants.

The objectives of this investigation in the HolyCross Mountain region of Poland were (1) to determineconcentration ranges and (2) mobility of elements within fivedetailed soil profiles and their apparent impact on thechemistry of some plant bioindicators, i.e. lichen thalli ofthe species Hypogymnia physodes (L.) Nyl. and Scotspine (Pinus sylvestris L.) bark. The results ofelemental determinations performed on soils and vegetationfrom the Holy Cross Mts show that some concentrations ofelements are elevated primarily due to air pollution.However, since 1994 a steady decrease in the content of S andsome heavy metals has been recorded in all the mediaexamined. Concentrations of many elements in H.physodes thalli and P. sylvestris needles of the Holy Cross Mountains are generally similarto those in other areas of Europe.

The odor emissions from three types of biosolidsfrom King County, WA, were measured usingdilution-to-threshold olfactometry and mass spectralanalyses. This article describes thermal desorption andcryogenic GC/MS methods developed to characterizeodorant emissions from biosolids application to forestsoil. The major odorous compounds volatilized from twoanaerobically digested biosolids were ammonia anddimethyl disulfide, with lesser quantities of carbondisulfide, dimethyl sulfide, trimethyl amine, acetoneand methyl ethyl ketone. A third type of biosolidswas formed by centrifuge and drying one of the otherbiosolids at 190 °C. This dry biosolids producedmore odor and volatilized a more complex array ofvolatile compounds including: dimethyl disulfide,dimethyl sulfide, carbon disulfide, methylethyldisulfide, methane thiol, trimethyl amine, aceticacid, propionic acid, and butyric acid. Odor unitemissions were not found to correlate with microbialactivity, initial biosolids ammonium, organicnitrogen, and total sulfur. Variability in odoremission were explained by the number of odorouscompounds volatilized from each material, surface areaof biosolids and drying of the biosolids.

Our field survey showed that thequality of shallow groundwater around the KatsuraRiver in the Kyoto Basin was strongly affected by theinfiltration of river water. Furthermore, that thedeterioration of the groundwater in the southern areato the west of the Katsura River may be related to theincrease in groundwater extraction. To clarify themechanism of groundwater deterioration, we havedeveloped a stochastic method to simulate groundwaterflow. The results showed that there was a largereduction in the groundwater level where groundwaterextraction was intense and recharge flowed from theKatsura River to the high extraction areas in thesouthern region. Another simulation showed that if thegroundwater extraction was 10% of the present removalrate, there would be little recharge from the KatsuraRiver into the groundwater and the quality of thegroundwater would be improved. Thus, we conclude thatthe cause of groundwater deterioration is probably dueto the induced recharge of deteriorated river waterfrom the Katsura River.

Using ¹³C/¹²C ratios in particulate organic carbon(POC), this study evaluated the fraction of terrestrially derivedPOC in Winyah Bay, South Carolina, an anthropogenically impactedestuary in the southeastern United States. Results from themixing model, which should be viewed as an upper limit becauseof possible dilution from additional potential end-members,showed that between 50 and 90% of POC in the Winyah Bay estuaryis of terrestrial origin. As this POC may be associated withriver-transported pollutants, the potential for accumulation ofpollutants in Winyah Bay is high because POC may become trappedin the estuary as part of either estuarine bottom sediments,circulation or food webs. Thus strategies for pollutionmonitoring and control in the estuary and its watershed arenecessary for the future management of Winyah Bay naturalresources.

Soil erosion has both on-farm and off-farm impacts. Reduction ofsoil depth can impair the land's productivity, and the transportof sediments can degrade streams, lakes, and estuaries. Since1933, soil conservation policies have existed in the UnitedStates. Originally they focused on the on-farm benefits ofkeeping soil on the land and increasing net farm income.Beginning in the 1980s, however, policy goals increasinglyincluded reductions in off-site impacts of erosion. As aconsequence of conservation efforts associated with explicitU.S. government policies, total soil erosion between 1982 and1992 was reduced by 32% and the sheet and rill erosion ratefell from an average of 4.1 tons per acre per year in 1982 to 3.1 tons per acre in 1992. Wind erosion rate fell from anaverage of 3.3 tons per acre per year to 2.4 tons per acre peryear over the same period. Still, soil erosion is imposingsubstantial social costs. These costs are estimated to be about$37.6 billion annually. To further reduce soil erosion andthereby mitigate its social costs, there are a number of policyoptions available to induce farmers to adopt conservationpractices including education and technical assistance,financial assistance, research and development, land retirement,and regulation and taxes.

Twenty-eight volatile organic compounds have been measured in a 3-month monitoring campaign. The sampling point is locatedin the urban centre of La Coruña, a medium-size town in theNorthwest of Spain. Only a petrol refinery can be consideredas an important point VOCs source in its surrounding area.The municipal landfill collapsed in September 1996, and rebuilding works caused strong odour episodes at the urbancentre. We tried to check how this problem affected urban airquality. Samples were taken with Tenax-TA tubes and analysedby thermal desorption-GC-MS. From the results obtained, traffic emissions were recognised as the main VOCs source inthe sampling zone. On November 9th a contaminationepisode took place. Aromatic and aliphatic compounds levelswere probably affected by emissions from fuel treatmentprocesses in a nearby petrol refinery. No influence onquantified VOCs concentrations from the remaking landfillworks was observed. Several compounds (organosulphurs, estersand alcohols) were recognised as the cause of odour problems.

Roads play a major role intransporting sediment associated nonpoint sourcepollutants to urban stream networks via storm drains. In urban areas the relationship of erodible soil toroads may be of critical importance in controllingmetal contributions to roads. Two 50-m transects(Park and School) were investigated perpendicular toroads in Manoa basin, Oahu, Hawaii. Concentrations ofnine elements were compared to background control soillocations and to five supplemental samples from nearbyrecreational parks. Sediment from curbside areas ofroads (road deposited sediment) was collected as thestarting point of each transect, and subsequently soilwas sampled from two depths (0–2.5 cm and 7.5–10.0 cm)along the transects. Total and 0.5 M HCl extractableconcentrations were determined for aluminum (Al),calcium (Ca), chromium (Cr), copper (Cu), iron (Fe),manganese (Mn), nickel (Ni), lead (Pb) and zinc (Zn)using either inductively coupled plasma-atomicemission spectroscopy (ICP-AES) or flame atomicemission spectroscopy (FAAS). Ca, Cu, Pb and Znexhibited anthropogenic enhancement, with Pb and Znhaving the greatest enrichment in road sedimentfollowed by locations nearest the road. Copperdisplayed a narrower band of contamination than eitherPb or Zn, and this may reflect larger aerosolassociations and more rapid fall velocities. Lead andZn exhibited substantial decay in concentration at 50 m compared to the road sediment, but enrichment wasstill apparent. The positioning of a band of soilbetween the road-curb area and the sidewalk for thePark transect facilitated deposition and storage oftrace metals, and with subsequent erosion by splash orconcentrated flow this area can account for continuedtransport of contaminated sediment to adjacent roadsurfaces. On the other hand the School transect hadno soil directly beside the road, and the nearestsample from the road (5 m) displayed enrichment butsubstantially lower than the Park transect. Thesepreliminary data suggest that remobilization of soilstored metals in close proximity to roads cansignificantly prolong the environmental contaminationof urban road systems and eventually stream sediments.

Subsurface tile drainage systems with drainspacings of 15 m in 0.4 ha and 25 m in 3.2 ha wereinstalled at the farmers' field in 1986 and 1987,respectively, to study their effect on the reclamationof the coastal saline sodic clay soils. The system'sperformance in terms of the changing physical andchemical properties of the soil and rice yield wascontinuously monitored for a decade. Field datasuggested the possibility of adopting wider drainspacings and thus, drainage system with 35 and 55 mspacings was laid in 1997 in a 4 ha area. On theseinstallations the losses of NH₄ ⁺-N throughsub-surface drainage effluent were estimated. Thearea under 25 m drain spacing was the control with nocrops, fertilization and irrigation. Analysis ofwater samples collected daily for 10 days startingfrom 40 DAT from the drain laterals revealed thatthere were no trace of NH₄ ⁺-N in theeffluent from 15 and 25 m drain spacings. However,the effluent from 35 and 55 m spacings contained anaverage of 6.704 mg L⁻¹ and 4.205 mg L⁻¹ of NH₄ ⁺-N, respectively, before irrigation and2.438 and 1.650 mg L⁻¹ after irrigation. Themagnitudes of the losses of NH₄ ⁺-N duringthe crop season were 6.43 kg ha⁻¹ in 35 m spacingwith a drainage rate of 5.6 mm d⁻¹ and 2.14 kgha⁻¹ in 55 m spacing with a drainage rate of 3.5 mm d⁻¹. The rice yield was 6.5 Mg ha⁻¹ in15 m drain spacing where no ammonium losses throughsubsurface drainage effluent occurred. The rice yieldsunder 35 and 55 m drain spacings were 1.9 and 1.8 Mgha⁻¹, respectively. The poor yield was due tosignificant loss of ammonium form of nitrogen throughthe drainage effluent and lesser availability of totalnitrogen to the plants. The plant uptake of nitrogen in the unreclaimed area with 55 m spacing was half ofthat in the reclaimed area with 15 m spacing.