Enantioselective synthesis of both enantiomers of dimethyl cis-(4-acetoxycyclopent-2-enyl)malonate, key intermediates for epijasmonate
2002
Tanimori, S. (Osaka Prefectural Univ., Sakai (Japan)) | Tsuji, Y. | Kirihata, M.
Both enantiomers (3 and 4) of dimethyl cis-(4-acetoxycyclopent-2-enyl)ma!onate (3), known intermediates for the synthesis of epijasmonate, were prepared in an enantio-enriched form from common starting material 2 based on desymmetrization of the m&yo-character by palladium-catalyzed asymmetric allylic alkylation.
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