New ligand platforms for developing the chemistry of the TiN–NR₂ functional group and the insertion of alkynes into the N–N bond of a TiN–NPh₂ ligand
2007
Selby, Jonathan D. | Manley, Catherine D. | Feliz, Marta | Schwarz, Andrew D. | Clot, Eric | Mountford, Philip
Two broadly applicable strategies for extending the available ligand platforms of the virtually unexplored terminal TiN–NR₂ functional group are described, along with the highly selective room temperature insertion of alkynes into the N–N bond of Ti{MeN(CH₂CH₂NSiMe₃)₂}(NNPh₂)(py) and the catalytic cis-diamination of PhCCMe by diphenylhydrazine.
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