New ligand platforms for developing the chemistry of the TiN–NR₂ functional group and the insertion of alkynes into the N–N bond of a TiN–NPh₂ ligand

Selby, Jonathan D.; Manley, Catherine D.; Feliz, Marta; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip

New ligand platforms for developing the chemistry of the TiN–NR₂ functional group and the insertion of alkynes into the N–N bond of a TiN–NPh₂ ligand

2007

Two broadly applicable strategies for extending the available ligand platforms of the virtually unexplored terminal TiN–NR₂ functional group are described, along with the highly selective room temperature insertion of alkynes into the N–N bond of Ti{MeN(CH₂CH₂NSiMe₃)₂}(NNPh₂)(py) and the catalytic cis-diamination of PhCCMe by diphenylhydrazine.

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