Rhodium acetate/base-catalyzed N-silylation of indole derivatives with hydrosilanes
2012
Itagaki, Shintaro | Kamata, Keigo | Yamaguchi, Kazuya | Mizuno, Noritaka
In the presence of Rh₂(OAc)₄ (OAc = acetate) and TBA₂WO₄ (TBA = tetra-n-butylammonium), the N-silylation of indole derivatives with hydrosilanes efficiently proceeded to give the corresponding N-silylated indoles in high yields. Pyrrole and carbazole were also N-silylated with the combined catalysts.
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