Metal-free desilylative C–C bond formation by visible-light photoredox catalysis
2019
Uygur, Mustafa | Danelzik, Tobias | Garcia Mancheño, Olga
A newly developed methodology for the use of organosilanes as radical precursors under metal-free and visible-light conditions is presented. The strong oxidant character of the 9-mesityl-10-methylacridinium salt in its excited state enables the transformation of simple silanes to the corresponding carbon-centered radicals, which were trapped by various acceptor molecules.
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