Metal-free desilylative C–C bond formation by visible-light photoredox catalysis

Uygur, Mustafa; Danelzik, Tobias; Garcia Mancheño, Olga

Metal-free desilylative C–C bond formation by visible-light photoredox catalysis

2019

Uygur, Mustafa | Danelzik, Tobias | Garcia Mancheño, Olga

A newly developed methodology for the use of organosilanes as radical precursors under metal-free and visible-light conditions is presented. The strong oxidant character of the 9-mesityl-10-methylacridinium salt in its excited state enables the transformation of simple silanes to the corresponding carbon-centered radicals, which were trapped by various acceptor molecules.

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