Electrochemical Regeneration of FAD by Catalytic Electrode Without Electron Mediator and Biochemical Reducing Power
2005
Jeon, S.J. (Seokyeong University, Seoul, Republic of Korea) | Shin, I.H. (Seokyeong University, Seoul, Republic of Korea) | Sang, B.I. (Korea Institute of Science and Technology, Seoul, Republic of Korea) | Park, D.H. (Seokyeong University, Seoul, Republic of Korea), E-mail: [email protected]
We created a new graphite-Cu(Ⅱ) electrode and found that the electrode could catalyze FADH₂ oxidation and FAD reduction coupled to electricity production and consumption, respectively. In a fuel cell with graphite-Cu(Ⅱ) anode and graphite-Fe(Ⅲ) cathode, the electricity was produced by coupling to the spontaneous oxidation of FADH₂. Fumarate and xylose were not produced from the enzymatic oxidation of succinate and xylitol without FAD, respectively, but produced with FAD.
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