Analysis of thermally induced changes in the structure of coal tar pitches by an advanced evaluation method of X-ray scattering data

Loeh, M.O.; Badaczewski, F.; Faber, K.; Hintner, S.; Bertino, M.F.; Mueller, P.; Metz, J.; Smarsly, B.M.

Analysis of thermally induced changes in the structure of coal tar pitches by an advanced evaluation method of X-ray scattering data

2016

Graphite materials generally contain considerable amounts of coal tar pitch binders initially consisting of small, randomly arranged stacks of graphene layers exhibiting structural disorder. Here, an advanced evaluation method for the analysis of Wide-Angle X-ray Scattering (WAXS) data of non-graphitic carbons, usually displaying broad and overlapping reflections, is used to systematically investigate the evolution of the carbon microstructure and, thus, the graphitizability of several coal tar pitches, permitting a quantification of the microstructural features on the nanometer scale. Although the investigated pitches exhibit distinctly different elemental and molecular compositions, the results revealed an almost identical development of the microstructure. For instance, the WAXS analysis proved a significant increase in the stack size Lc and the graphene extension La only at temperatures above 1500 °C, starting at 10 Å for the pristine pitches and reaching about 200 Å at a heat treatment temperature of 2100 °C. Furthermore, at temperatures around 500 °C the WAXS analysis exposes the appearance of a mesophase, which is confirmed using optical microscopy, leading to a temporary increase of the stacking height Lc to about 30 Å, whereas the lateral layer size La remains approximately constant.

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