Formation of a highly-ordered rigid multichromophoric 3D supramolecular network by combining ionic and coordination-driven self-assembly
2016
Kaloudi-Chantzea, Antonia | Martinou, Elisabeth | Seintis, Kostas | Karakostas, Nikolaos | Giastas, Petros | Pitterl, Florian | Oberacher, Herbert | Fakis, Mihalis | Pistolis, George
We present here the self-assembly of a green-emitting metallosupramolecular rhomboid into a rigid, highly-ordered 3D multichromophoric network through the mediation of a tetra-anionic violet-blue molecular emitter. Control was obtained on the spatial topology, the electronic energy landscape and the fluorescence polarization of the interacting dipoles.
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