Formation of a highly-ordered rigid multichromophoric 3D supramolecular network by combining ionic and coordination-driven self-assembly

Kaloudi-Chantzea, Antonia; Martinou, Elisabeth; Seintis, Kostas; Karakostas, Nikolaos; Giastas, Petros; Pitterl, Florian; Oberacher, Herbert; Fakis, Mihalis; Pistolis, George

Formation of a highly-ordered rigid multichromophoric 3D supramolecular network by combining ionic and coordination-driven self-assembly

2016

We present here the self-assembly of a green-emitting metallosupramolecular rhomboid into a rigid, highly-ordered 3D multichromophoric network through the mediation of a tetra-anionic violet-blue molecular emitter. Control was obtained on the spatial topology, the electronic energy landscape and the fluorescence polarization of the interacting dipoles.

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