Studies towards the stereoselective total synthesis of Gliomasolide A
2019
Kare, Nagaraju | Kundoor, Govinda Reddy | Palakodety, Radha Krishna
The first synthetic approach towards the Gliomasolide A is described in 15 linear steps with 4% overall yield. The key steps in this approach are RCM protocol for the construction of 14-member macrolide, a Sharpless kinetic resolution, Keck and Brown’s allylations for the installation of desired stereocenters.
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