Geochemical markers of sedimentary organic matter in Todos os Santos Bay, Bahia – Brazil. Indicators of sources and preservation

de Souza, José Roberto Bispo; do Rosário Zucchi, Maria; Costa, Alexandre Barreto; de Azevedo, Antonio Expedito Gomes; Spano, Saulo

Geochemical markers of sedimentary organic matter in Todos os Santos Bay, Bahia – Brazil. Indicators of sources and preservation

2017

de Souza, José Roberto Bispo | do Rosário Zucchi, Maria | Costa, Alexandre Barreto | de Azevedo, Antonio Expedito Gomes | Spano, Saulo

Natural stable isotopes, such as carbon (C) and nitrogen (N), are modern tools to assess geochemical processes. C and N in organic matter can carry fingerprints of their hydrologic flows and sedimentary processes, including any anthropogenic modification on the natural system. This study focuses on the determination of aliphatic and polycyclic aromatic hydrocarbons and isotopic ratio in the sediment of Todos os Santos Bay (TSB). The isotopic results of the total organic matter indicate varied contribution marine and terrigenous. Typical rates of PAHs mainly indicate a pyrogenic source and mixture between pyrogenic and petrogenic sources. Typical ratios for the n-alkanes indicate the presence of petroleum hydrocarbons. The isotopic composition of n-alkanes suggests a mixture of sources, with the possible contribution of petrogenic.

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