Catalytic Oxidation of Volatile Organic Compounds by 13X Zeolite Coated with nZnO in Presence of UV and Ozone at High Bed Temperature

Changsuphan, Amornpon; Kim Oanh, NguyenThi

Catalytic Oxidation of Volatile Organic Compounds by 13X Zeolite Coated with nZnO in Presence of UV and Ozone at High Bed Temperature

2018

Changsuphan, Amornpon | Kim Oanh, NguyenThi

Catalytic oxidation of benzene, toluene, and ethylbenzene (BTE) on virgin zeolite, nZnO-coated zeolite, with and without UV + O₃, at 300 °C bed temperature was investigated using laboratory experiments. The coating was done at three weight ratios of Zn (estimated Zn content in nZnO) to zeolite (0.2:1.0, 0.5:10, 1.0:1.0). The coated adsorbents were examined by scanning electron microscopy, wavelength dispersive X-ray spectroscopy, and Brunauer Emmett Teller analyses. In the catalytic oxidation experiments, the adsorbents were first saturated with BTE by purging an air stream containing a mixture of BTE at 5 ppm each for 28 min. Introduction of UV + O₃ on the coated 13X zeolite (0.5:1.0) bed improved the average removal efficiency (RE) of benzene, toluene, and ethylbenzene (with inlet concentration of 5 ppm each) to 68.7, 90.0, and 99.6%, respectively, from the corresponding values of 57.3, 79.9, and 98.5% when no UV + O₃ was used. An increase in the coating weight ratio from 0.2:1.0 to 0.5:1.0 had produced a higher RE for benzene only, while a further increase to 1.0:1.0 witnessed a decrease in RE for all three compounds, and more for benzene. Avg RE of BTE decreased with the increase in their inlet concentrations, more significantly for an increase from 5 to 50 ppm and less noticeable for a further increase to 100 ppm. The final oxidation products and intermediate products in the outlet streams from the oxidation and thermal desorption were analyzed which showed predominant compositions of CO₂ followed by BTE and some levels of CO and other volatile organic compounds.

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