Role of Humic Substances on Cr(VI) Removal from Groundwater with Pyrite

Kantar, Cetin; Bulbul, Muhammet Samet; Keskin, Selda

Role of Humic Substances on Cr(VI) Removal from Groundwater with Pyrite

2017

Kantar, Cetin | Bulbul, Muhammet Samet | Keskin, Selda

Groundwater composition may have a pronounced impact on long-term performance of permeable reactive barriers (PRBs). Here, batch and column experiments were conducted to investigate the effects of humic acid (HA) on Cr(VI) removal by pyrite in systems containing cations such as Ca²⁺ and Mg²⁺. HA was observed to have inhibitory effect on Cr(VI) uptake by pyrite under the experimental conditions studied (e.g., pH 3 to 8). HA sorbed onto pyrite surface and thus (1) competed against Cr(VI) for pyritic surface sites and/or (2) increased electrostatic repulsion between Cr(VI) and pyrite. In systems with HA and Ca²⁺/Mg²⁺, the Cr(VI) uptake by pyrite decreased drastically relative to HA alone due to the aggregation of HA with Ca²⁺/Mg²⁺. The formation of such HA aggregates/precipitates blocked Cr(VI) ions to reach its binding sites, thereby resulting in a substantial decrease in Cr(VI) uptake. Overall, the results have major implications for proper design and operation of PRBs with pyrite as the reactive material.

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