Comparison of Organic Materials for the Passive Treatment of Synthetic Neutral Mine Drainage Contaminated by Nickel: Adsorption and Desorption Kinetics and Isotherms
2020
Richard, Dominique | Mucci, Alfonso | Neculita, Carmen M. | Zagury, Gérald J.
Sorption is an effective process for the remediation of mine water with low metal concentrations. To identify promising low-cost organic sorbents for nickel (Ni), adsorption and retention properties of peat, compost, brown algae, sawdust, and wood ash were compared. Batch adsorption and desorption experiments were conducted at pH 7 in 0.05 M NaNO₃ solutions to simulate the ionic strength and pH of a contaminated neutral drainage. Results of adsorption kinetic experiments were best represented by the Elovich model and the fastest rates were obtained with peat (796,075 mg g⁻¹ min⁻¹) and compost (791 mg g⁻¹ min⁻¹). Results of equilibration adsorption experiments were fitted to Langmuir and Freundlich isotherms and the highest adsorption capacities were observed for peat (around 22 mg g⁻¹) and compost (around 9 mg g⁻¹). Desorption experiments revealed that peat and compost adsorbed more Ni and also released a lower percentage of the adsorbed metal upon exposure to Ni-free solutions.
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