Rapidly reversible adsorption of methane with a high storage capacity on the zeolite templated carbons with glucose as carbon precursors
2015
Shi, Jinsong | Li, Weibin | Li, Dan
Microporous carbon material with a high surface area of 1562m2/g is prepared via an impregnation method with NaY zeolite as hard template. The results indicate that glucose, an environmental friendly material, could be used as the carbon precursor of zeolite templated carbons, in comparison with the toxicity of furfuryl alcohol and lower surface area of carbons generated from sucrose. Effects of reactant molar ratios and carbonization conditions on the textural properties are addressed. Although higher carbonization temperature favors more complete carbonization reactions, it also causes the collapse of small pores and the formation of large pores at the same time. Further characterizations of the obtained carbon materials with XRD, SEM and N2 adsorption–desorption measurements are presented. Methane adsorption tests on carbon materials are investigated with the static volumetric method at 300K. The higher adsorption amount of 9.9wt.% was achieved at 3.5MPa on sample with a higher micropore volume, indicating that micropores were playing a crucial role for the methane storage process.
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