Effect of SiO2 addition on NH4HSO4 decomposition and SO2 poisoning over V2O5–MoO3/TiO2–CeO2 catalyst

Zheng, Chengqiang; Cheng, Teng; Yang, Linjun; Wu, Hao; Fan, Hongmei

Effect of SiO2 addition on NH4HSO4 decomposition and SO2 poisoning over V2O5–MoO3/TiO2–CeO2 catalyst

2020

Zheng, Chengqiang | Cheng, Teng | Yang, Linjun | Wu, Hao | Fan, Hongmei

The deposition of NH₄HSO₄ and the poisoning effect of SO₂ on SCR catalyst are the main obstacles that restrict the industrial application of CeO₂-doped SCR catalysts. In this work, deposited NH₄HSO₄ decomposition behavior and SO₂ poisoning over V₂O₅–MoO₃/TiO₂ catalysts modified with CeO₂ and SiO₂ were investigated. By the means of characterization analysis, it was found that the addition of SiO₂ into VMo/Ti–Ce had an impact on the interaction existed between catalyst surface atoms and NH₄HSO₄. Temperature-programmed methods and in situ diffused reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments indicated that the doping of SiO₂ promoted the decomposition of deposited NH₄HSO₄ on VMo/Ti–Ce catalyst surface by reducing the thermal stability of NH₄HSO₄ and enhancing the NH₄HSO₄ reactivity with NO in low temperature. And this improvement may be the reason for the better catalytic activity than VMo/Ti–Ce in the case of NH₄HSO₄ deposition. Accompanied with cerium sulfate species generated over catalyst surface, the conversion of SO₂ to SO₃ was inhibited in SiCe mixed catalyst. The addition of SiO₂ could promote the decomposition of cerium sulfate, which may be a potential strategy to enhance the resistance of SO₂ poisoning over CeO₂-modifed catalysts.

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