Composites prepared from natural iron oxides and sucrose: A highly reactive system for the oxidation of organic contaminants in water

Pereira, Márcio C.; Cavalcante, Luis C.D.; Magalhães, Fabiano; Fabris, José D.; Stucki, J. W.; Oliveira, Luiz C.A.; Murad, Enver

Composites prepared from natural iron oxides and sucrose: A highly reactive system for the oxidation of organic contaminants in water

2011

A soil material containing 81% Fe₂O₃ that is inactive towards H₂O₂ was used to prepare composites with charcoal obtained from sucrose. Composites obtained by heating under air at 400, 600, 700 and 800°C were characterized by total Fe, Fe²⁺ and Fe³⁺ chemical analyses, Mössbauer spectroscopy, visible diffuse reflectance, X-ray diffraction and surface area determination. The catalytic activities of the composites were monitored by methylene blue degradation. The results indicate that the activity towards methylene blue degradation was strongly enhanced after heating at 600°C, with almost 100% color removal. Fe²⁺ in the magnetite structure was mainly responsible for the catalytic activity the composites and the mechanism of methylene blue degradation beginning via OH radicals produced by Fe²⁺ in the magnetite structure and H₂O₂. The proposed mechanism is supported by ESI-MS analysis.

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