Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates

Stempfle, Florian; Ortmann, Patrick; Mecking, Stefan

Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates

2016

Stempfle, Florian | Ortmann, Patrick | Mecking, Stefan

Other than their established short-chain congeners, polycondensates based on long-chain difunctional monomers are often dominated by the long methylene sequences of the repeat units in their solid-state structures and properties. This places them between traditional polycondensates and polyethylenes. The availability of long-chain monomers as a key prerequisite has benefited much from advances in the catalytic conversion of plant oils, via biotechnological and purely chemical approaches, likewise. This has promoted studies of, among others, applications-relevant properties. A comprehensive account is given of long-chain monomer syntheses and the preparation and physical properties, morphologies, mechanical behavior, and degradability of long-chain polyester, polyamides, polyurethanes, polyureas, polyacetals, and polycarbonates.

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