Synthesis of cellulose triacetate from cotton cellulose by using NIS as a catalyst under mild reaction conditions
2015
El Nemr, Ahmed | Ragab, Safaa | El Sikaily, Amany | Khaled, Azza
This research discusses the acetylation of cotton cellulose with acetic anhydride without solvents. The acetylation was done in the presence of different amounts of N-Iodosuccinimide (NIS) as a catalyst; this took place under mild reaction conditions. The extent of acetylation was measured by the weight percent gain (WPG) that varied from 24.71 to 71.83%. Cotton cellulose acetates, with the degree of substitution (DS) that ranged from 0.89 to 2.84, were prepared in one step. The cellulose triacetate, with a degree of substitution (DS) 2.84, was obtained. The WPG and DS were easily controlled by changing the reaction duration (1–5h), and the concentration of the catalyst (0.05g, 0.075g and 0.10g for 1g of cellulose) in 25ml of acetic anhydride. NIS was recognized as a novel and more successful catalyst for the acetylation of hydroxyl groups in cotton cellulose. Formation of the acetates and the calculation of the degree of substitution were performed by FT-IR, Raman, and 1H NMR.
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