Comparison of bioavailable vanadium in alfalfa rhizosphere soil extracted by an improved BCR procedure and EDTA, HCl, and NaNO3 single extractions in a pot experiment with V–Cd treatments

Yang, Jie; Teng, Yanguo; Zuo, Rui; Song, Liuting

Comparison of bioavailable vanadium in alfalfa rhizosphere soil extracted by an improved BCR procedure and EDTA, HCl, and NaNO3 single extractions in a pot experiment with V–Cd treatments

2015

Yang, Jie | Teng, Yanguo | Zuo, Rui | Song, Liuting

The BCR sequential extraction procedure was compared with EDTA, HCl, and NaNO₃ single extractions for evaluating vanadium bioavailability in alfalfa rhizosphere soil. The amounts of vanadium extracted by these methods were in the following order: BCR (bioavailable V) > EDTA ≈ HCl > NaNO₃. Both correlation analysis and stepwise regression were adopted to illustrate the extractable vanadium between different reagents. The correlation coefficients between extracted vanadium and the vanadium contents in alfalfa roots were R NₐNO₃ = 0.948, R HCₗ = 0.902, R EDTA = 0.816, and R bᵢₒₐᵥₐᵢₗₐbₗₑ V = 0.819. The stepwise multiple regression equation of the NaNO₃ extraction was the most significant at a 95 % confidence interval. The influence of pH, total organic carbon, and cadmium content of soil to vanadium bioavailability were not definite. In summary, both the BCR sequential extraction and the single extraction methods were valid approaches for predicting vanadium bioavailability in alfalfa rhizosphere soil, especially the single extractions.

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