Evaluating CO2 flux and recharge source in geothermal springs, Garhwal Himalaya, India: stable isotope systematics and geochemical proxies

Evaluation of geogenic carbon fluxes between solid Earth and its atmosphere is essential to understand the global geological carbon cycle. Some of the key geogenic CO₂ suppliers are the magmatic mantle and metamorphic degassing from active and quiescent volcanoes, fault zones, geothermal systems and CO₂ rich groundwater. Indian Himalayan geothermal field hosts about 340 geothermal springs in natural as well as artesian condition that eject hot waters and volatiles with varied temperature and chemical composition. These sites provide an opportunity to analyse tectonically driven gas emissions and their impact on regional and global climate. Here we adopt a method for direct measurement of Dissolved Inorganic Carbon (DIC ≈ HCO₃) concentration in the geothermal springs to estimate geogenic CO₂ flux from an active region based on water discharge and area of geothermal system between the tectonic boundaries of the Main Central Thrust (MCT) and Main Boundary Thrust (MBT) of the Garhwal (Northwest) Himalaya. In the study area, geothermal spring water contain high δ¹³CDIC ratio (− 8.5‰ to + 4.0‰ VPDB), and among the major ions, bicarbonate (HCO₃⁻) varies by an order of magnitude from 1697 to 21,553 μEq/L; chloride and sodium vary from 90 to 19,171 μEq/L and 436 to 23181 μEq/L. The elevated concentration of Cl⁻ and Na⁺ in geothermal spring waters suggests affinity towards their deeper origin. These geothermal springs cover a large area of nearly 10,000 km² of the Garhwal region showing a significant discharge of CO₂ rich water with an estimated carbon dioxide degassing flux of ~7.2 × 10⁶ mol/year to the atmosphere. Considering widespread occurrences of geothermal springs in tectonically active areas worldwide, the proposed direct measurement of DIC may be used as a reliable tool to estimate CO₂ fluxes in different active orogenic settings within the Earth system. Results of stable isotopes of δ¹⁸O ₍VSMOW₎ and δD ₍VSMOW₎ in these geothermal spring waters follow the Global Meteoric Water Line (GMWL), suggesting affinity of their recharge through the meteoric origin.